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However, in actual practice, the relative quantity of ethyl orthosilicate to hydroxysiloxane used is always many times larger than the stoichiometric ratio.

将硅橡皮分别在空气及氮气中进行高温处理,并测定其溶胀度的变化的结果,证明这现象是由于硅橡皮在高温下发生降解及氧化所致。

We found out one kind of new orange-red long afterglow material La2O2S: Eu3+, Mg, Zr.2 In the phosphor Gd2O2S, Mg, Ti which was prepared by high-temperature solid-state method, the orange afterglow phenomenon can be seen after illuminated with UV light.3 Using the high-temperature solid-state method, Gadolinium oxysulfide phosphors doped with rare earth ions were synthesized. We can observe the red or orange phosphorescence in Gd2O2S doped with Eu3+, Sm3+, Tm3+, Yb3+, Dy3+, Er3+, Nd3+or Ho3+. This is a new result of the long afterglow phosphors research.4 Using the microwave radiation method, the new Sm3+ doped gadolinium oxysulfide phosphor, which has the orange-red long afterglow emission after illuminated with UV light or visible light, was synthesized for the first time.5 In fluorescent materials YOX doped with europium ions, the long afterglow phenomenon wasnt observed but the blue luminescence of Eu2+ and red luminescence of Eu3+ are simultaneously examined. This is a new result of the valence stability and change of Eu2+ in yttrium oxyhalide .We systematically studied the effects of the host, addition agents and reaction atmosphere on the valence change and fluorescence property of europium ions.

经过系统的研究总结得到以下的结论与成果: 1采用高温固相反应法合成了一系列稀土离子掺杂的硫氧化镧发光粉,发现了该体系中Eu~(3+)的长余辉发光,从而得到一种迄今未见文献报道的红色长余辉发光材料:La_2O_2S:Eu~(3+),Mg,Zr; 2在Gd_2O_2S,Mg,Ti磷光粉中观察到橙色的长余辉发光现象; 3采用高温固相反应法合成了一系列稀土离子掺杂的硫氧化钆磷光粉,在掺杂Eu~(3+)、Sm~(3+)、Tm~(3+)、Yb~(3+)、Dy~(3+)、Er~(3+)、Nd~(3+)、Ho~(3+)的Gd_2O_2S中观察到红色和橙色长余辉发光; 4首次采用微波法合成了Gd_2O_2S:Sm~(3+),Mg,Ti磷光粉,该磷光粉经紫外或可见光激发后呈现明显的橙红色长余辉发光; 5在YOX中同时观察到Eu~(2+)和Eu~(3+)的发射,系统研究了基质、添加剂及反应气氛对Eu价态和发光的影响。

Cr1MoV and Cr5Mo are three common types of pearlitic heat resistant steel and widely used for high temperature tubes in petro-chemical industry, so it is necessary to develop a set of computer aided decision-making system for safety evaluation of tubes.

20钢、12Cr1MoV和Cr5Mo是 3种常用作石化企业高温炉管材料的珠光体耐热钢,开发和应用计算机决策支持系统对高温管线进行安全评估是非常必要的。

The melting point of the pure periclase magnesia is 2,800℃, some impurities may reduce the melting point of the magnesia , borides influence is extremely remarkable.

纯净的方镁石型氧化镁的熔点为2800℃,一些杂质可使氧化镁的熔点降低,其中硼化物的影响极为显著,即使是少量的硼化物(0.01%-0.02%)的存在就将导致氧化镁的抗蠕变性能明显降低,而B2O3在高温时的气化能够造成氧化镁材料的气孔率增大,严重影响其高温强度,故镁砂降硼是非常重要的。

Results show that protons are liberated by dehydration or dehydroxylation after calcination at 500℃. These protons disrupt the silicon-oxygen-aluminium bridges where there are Al substitutions in the tetrahedral sheet of the montmorillonite. Some of silicon-oxygen and aluminum-oxygen tetrahedral invert to react with the pillaring agents and yield covalent bonds which firmly fix the pillars to the host clay. The Al-MMT are thermally and hydrothermally stable up to 700℃.

经过500℃高温焙烧后,交联剂经脱水或脱羟基释放出质子攻击蒙脱土四面体层中Si-O-Al四键,硅氧四面体和铝氧四面体发生翻转,与交联剂发生反应生成共价键,形成稳定的层柱黏土材料,在700℃高温下,Al-MMT材料不仅具有较好的热稳定性,而且具有较好的水热稳定性。

The present development of high temperature proton conductors with high chemical stability as electrolyte materials for protonic ceramic membrane fuel cells is reviewed, as well as the influence of novel element doping strategies on the chemical stability, ionic conductivity and sinterability for BaCeO3-based materials.

重点评述了近期化学稳定性好的高温质子导体电解质材料的发展以及新的掺杂体系对于经典BaCeO3基质子导体在化学稳定性、电导率和烧结活性等方面的作用,分析了高温质子导体作为电解质材料在质子陶瓷膜燃料电池发展中存在的问题和发展的方向。

The rheologies of two types of high-density water-based drilling fluids including the fresh water-based drilling fluid and salt water-based drilling fluid were tested at high temperatures of 50℃, 80℃, 120℃, 150℃, 180℃, 200℃ and 220℃ respectively, and at high pressure of 5MPa using Fann50SL Reometer.

以室内研制的抗高温高密度淡水基和盐水基钻井液为基础,采用Fann50SL高温高压流变仪对钻井液在不同温度下的流变性进行了测试。

It is well known that the large lattice mismatch (16%) and thermal expansion coefficient mismatch between GaN and sapphire substrate are the main origins of TDs. By new growing technique of LEO, we acquired high quality GaN films almost free of TDs. The stress characteristics in GaN films with MLTB growing technique is dependent on growing systems and conditions, and the changes of stress and dislocation density are rightabout; Combining buffer layers of high temperature and low temperature is first developed to growing GaN films with low dislocation density, and the mechanism of lowering TDs density is that the first buffer layer of high temperature can make nuclear in second buffer layer of low temperature bigger. This technique also can restrain yellow luminescence effectively.

众所周知,晶格失配和热应力失配是GaN异质外延中位错产生的主要原因;为此,我们对几种降低缺陷的MOCVD外延生长方法进行了新的尝试,其中尝试了侧向外延生长技术,得到了低位错密度(小于10〓/cm〓)、高质量的GaN外延层;尝试多低温缓冲层法,发现材料中的应力特性与生长系统和生长条件有关,材料中的应力与位错密度按相反方向变化;首次尝试高低温联合缓冲层法,材料中高温缓冲层可以使随后的低温缓冲层中成核颗粒增大,从而导致随后高温GaN外延膜中位错密度降低,并且能够有效地抑制黄光峰。

CRC was found to be prone to spalling when subjected to high temperature, which usually occurs in the 300℃~400℃temperature range.

2由CRC的高温性能试验结果可知,CRC在高温过程中,可能会发生不同程度的爆裂现象,发生爆裂的温度区间集中在300℃~420℃间。

Experimental investigation on the effects of moisture content and fibers on both explosive spalling and residual mechanics of high performance concrete after exposure to high temperatures was presented in this paper.

本文研究了含湿量和纤维对高性能混凝土高温爆裂和高温后残余力学性能的影响。

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