高氯酸

This technique pro-duced not only N-phosphonomethyliminodiacetic acid with high quality but also a great deal of chloromethane by the hydrolyzation of dimethyl phosphite and methylal .

提供了一种利用亚磷酸二甲酯残液(亚磷酸二甲酯生产过程中的副产)和甲缩醛(甘氨酸法生产草甘膦过程中的副产)为原料来合成双甘膦的方法，采用该工艺可以合成高含量的双甘膦，而且利用亚磷酸二甲酯残液和甲缩醛的充分水解可生成大量的氯甲烷，从而大大提高上述副产物的综合利用价值，具有很好的发展前景。

Because of specificity and high efficiency, the catalytic efficiency of cellulase is high(more 103~1013 times than general catalysts), the condition of catalytic reaction is mild and the catalytic activation can be adjusted and controlled, which can improve remarkably semblance and handle of fabrics during finishing fabrics by biological catalyzing, moreover cellulase can replace some chemical materials such as acid, cocain, chlorine and phosphorus etc, so as to decrease pollution, make no waste-water and protect environment.

由于酶具有专一性和高效性，采用生物催化，其催化效率高比一般催化剂高10~3～10~(13倍，催化反应条件温和，催化活性可调节控制，应用在纺织品处理上，能显著改善织物的外观和手感，并能取代一部分酸、碱、氯、磷化合物等化工原料，从而减少污染，不产生污水，有利于环保和生态。而且酶本身又无毒，容易生物降解，不会引起环境污染，所以酶处理已被公认为是一种符合环保要求的绿色印染加工方法。本文选用了市场上常用的纤维素酶R-10和纤维素酶ECS2610两种生物酶。

Results: The proportion of Gram-negative bacilli rose obviously, so did the opportunistic pathogen's and Yeasts detected rate. Most drug sensitive tests showed the drug-fast rate turned to be high. Escherichia coli, Salmonella and Citrobacter resistant and so on to fluoroquinolones was 57%~97%. These bacteria to imipenem showed excellent activity. Meticillin-resistant-staphylococcus resistant to ciprofloxacin, norfloxacin, clindamycin, tetracycline, erythromycin, cefazolin and ampicillin were 40.9%, 42.4%, 63.6%, 72.2%, 85.9%, 100.0% and 100.0%, respectively Streptococcus and Enterococcus resistant to major β-lactams-penicillin, aminoglycosides, macrolides, tetracyclines and sulfonamides were between 36.0% to 100.0%.

结果：革兰阴性杆菌比例显著升高，条件致病菌和酵母样真菌检出机会显著增多；药敏结果显示多数临床细菌对常用抗生素的耐药趋势在不断上升；大肠埃希菌、沙门菌和枸橼酸杆菌等革兰阴性杆菌对喹诺酮类药物的耐药率达57%~97%，亚胺培南则对阴性杆菌有较高的敏感覆盖率；耐甲氧西林葡萄球菌对环丙沙星、诺氟沙星、氯洁霉素、四环素、红霉素、头孢唑啉和氨苄西林的耐药率分别为40.9%、42.4%、63.6%、70.2%、85.9%、100.0%和100.0%；链球菌和肠球菌对多数β内酰胺类青霉素、氨基糖苷类、大环内酯类、四环素类以及磺胺类药物均呈高度耐药，耐药率在36%~100%。

Second, among the seven yeast strains investigated, Rhodotorula gracilis AS 2.499 exhibited the highest activity and stereo-selectivity to tert-butyl-6-chloro-5-hydroxy-3-oxohexanoate.

其次，从实验室保藏的七株酵母菌株中筛选出对-6-氯-5-羟基-3-羰基己酸叔丁酯具有较高还原能力的菌株——Rhodotorula gracilis AS 2.499。

Medium to high conversion and selectivity were achieved with easy separation of the products from the ionic liquids due to their immiscibility.

反应具有适中至高的转化率和选择性，依据底物的不同，反应结束后可以和离子液体系分层，便于产物分离。氯铝酸离子液体具有一定的重复使用性

Uranium in the ore is separated and converted into U in HCl andcomplexed with TPC and a new type thoron reagent,2(phosphino-chloro-benzenediazo)-7 (disulfo-naphthyl-diazo)-naphthalene-1, 8 diol-3, 6 disulfonic acid.

铀在 0.5—1.4 mol/l盐酸中，用氯化十四烷基吡啶作增溶剂，铀与偶氮氯膦6，8-萘二磺酸-TPC形成的三元络合物具有极高的灵敏度ε_(705nm=1.6×10~5l·mol~(-1)·cm~(-1)和较好的选择性。

In this thesis, drug distribution in local tissues after topical administration of the ATPs was investigated with HPLC technique, concentration of ACF in skin and muscle remained high during 12hours. Pharmacodynamic of ATPs was evaluated with diclofenac gel as a control, and it was found that ATPs had stronger anti-inflammatory activity than diclofenac gel.The results of rabbit skin irritation test and Guinea pig skin allergia test make it certain that ATPs is safe for topical administration.

本文利用局部组织活检法考查了大鼠局部应用ATPs后的局部组织分布情况，结果表明药物能在皮肤和肌肉组织中12h维持较高的药物浓度；将所制ATPs与市售双氯芬酸钾凝胶进行了药效学比较，结果表明ATPs的抗炎效果优于英太青；家兔皮肤刺激性试验结果表明，ATPs对完好皮肤无刺激性，对破损皮肤具有轻度刺激；豚鼠过敏性试验结果显示ATPs无致敏性。

The preparation method is characterized in that:(1) at minus 10 DEG C to 10 DEG C, a chloroauric acid solution with a certain concentration is added into a nano-Pt/C catalyst by ultrasonic or stirring mixture and the atomic ratio of Pt to Au is controlled between 18:1 and 5:1;(2) a small amount of monohydric alcohol or dihydric alcohol or trihydric alcohol of C1-C3 is added and is stirred at minus 10 DEG C to 10 DEG C for 10 min to 5h, so as to prepare the carbon-loading Pt-Au bimetallic nano electro-catalyst;(3) if necessary, the catalyst obtained by the step (2) is treated for 0.5 to 4h at high temperature ranging from 100 DEG C to 700 DEG C in the inert or reducing atmosphere, so as to adjust and control the grain size of the Pt-Au bimetallic nano electro-catalyst.

本发明涉及了一种高稳定性碳载Pt-Au双金属纳米电催化剂的制备方法，其特征在于：(1)在-10～10℃中，将一定浓度氯金酸溶液加入到纳米Pt/C催化剂中经超声或搅拌混合，控制Pt∶Au的原子比为18∶1-5∶1；(2)添加少量C 1 -C 3 的一元、二元或三元醇类，在-10～10℃下搅拌10min-5h，制备了碳载铂金双金属纳米电催化剂；(3)视需要，可将步骤(2)得到的催化剂在惰性气氛或还原气氛中经100～700℃高温处理0.5-4h，可调控Pt-Au/C双金属纳米催化剂的粒径。

In order to find biologically active urea compounds,seven new N-[5-(3-pyridyl)-1,3,4-thiadiazol-2-yl]-N'- urea derivatives were synthesized by the reaction of 2-amino-5-(3-pyridyl)-1,3,4-thiadiazole with aroylazides,which were prepared starting from carboxylic acids,ethyl chloroformate and sodium azide by one-pot procedure.

为了寻找高生物活性的脲类化合物，通过2-氨基-5-(3-吡啶基)-1，3，4-噻二唑与酰基叠氮化物反应，设计合成了7个新的N-[5-(3-吡啶基)-1，3，4-噻二唑-2-基]-N'-取代苯基脲，其中芳酰基叠氮化物是以芳酸、氯甲酸乙酯、叠氮化钠为起始原料采用&一锅法&所制得。

ABSTRACT Chemical corrosion mechanism of concrete in Qinghai salt lake is briefly reviewed, and bittern resisting behavior of high alumina cement concrete, magnesium oxychloride cement concrete, alkali-activated slag concrete, ferrialuminate cement concrete and polymer impregnated concrete are also reported in the paper.

摘 要 简述了普通水泥混凝土在盐湖环境中的受腐蚀机理﹔报道了高铝水泥、氯氧镁水泥、铁铝酸盐水泥、碱矿渣和聚合物浸渍混凝土的抗盐卤腐蚀行为﹔对硅灰高密实混凝土的抗盐卤腐蚀机理进行了详细讨论，认为改善孔结构是获取混凝土高抗腐蚀性的有效途径。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。