高分子

This paper reviews the recent progress in molecular recognition of artificial receptors derived from steroid cholic acid as one of the structural components.

简要评述了胆甾基功能高分子的分子设计与合成研究进展，着重对侧基型高分子胆甾进行论

This in vivo study was to examine the historical changes of implanted novel chitosan/collagen composite barrier for confirming the clinical feasibility. Four other commercial GTR membranes were chosen for comparison. Among the resorbable GTR membranes, BioMend Extend and Peri-Aid are collagen base, and GORE-TEX OSSEOQUEST is synthesized membrane, while GORE-TEX e-PTFE (Expanded polytetrafluoroethylene) is synthesized but non-resorbable. Beagle dogs were used as animal model. Buccal mucoperiosteal flaps were reflected in the bilateral mandibular premolar and molar areas. Buccal alveolar bone was reduced on 1st、2nd premolar and molar to a level 5 mm apical to the cemento-enemel junction. Root surface was denuded of periodontal ligament and cementum, and notches were placed at the bone level of each root. The tested GTR barriers were implanted in critical bone defect areas. Flaps were coronally positioned and sutured. Two beagle dogs were sacrificed each time as the designed time period after surgery. Histological and histometirc evaluation at 7 days、14 days、28 days、3 months were performed post-operatively to determine the healing response of each treatment modality.

本研究之目的在评估与工研院生医中心合作发展出可吸收性去乙醯几丁聚醣/胶原蛋白复合之组织导引再生膜片，并选择与可吸收性之BioMend Extend 及Peri-Aid 胶原蛋白膜片，和GORE-TEX OSSEOQUEST 合成高分子膜片，及不可吸收之GORE-TEX e-PTFE合成高分子膜片，等其他四种市售商品材料共同对照评估，应用8只年龄为12个月的雄性小猎犬，均分4组(分别为7天、14天、28天、3个月)，为动物活体评估模式，在实验犬之左、右下颚第一、二小臼齿及大臼齿的颊侧区制造骨缺损后，分别植入组织导引再生膜片，依实验设定时间将小猎犬牺牲，取下缺损区骨头，以光学显微镜观察量测其牙垩质再生高度与齿槽骨再生高度之变化，以探讨其组织再生模式及评估新膜片在临床应用之适用性。

The enterprise survey :Changzhou Danli Material Of Macromolecule CO. LTD,Shanghai Danli Paper Industry CO. LTD, Changzhou New Danli Import And ExportCO. LTD, Changzhou Jinfu Compound Material CO. LTD.,lies in the south ofChangzhou ,Jiangsu province , down of the Yangtze River , built at 1993.Itsthe Association Of China Paper Lives. And this is a compound company which isengaged in the production, management and trade, import and export .We have more than 150 workers now, besides 8 senior engineers, 15

常州市丹利高分子材料有限公司常州丹利高分子材料有限公司，上海丹利纸业有限公司，常州新丹利进出口有限公司，常州金富复合材料有限公司，位于长江中下游地区，江苏省常州市南郊，公司创建于1993年，（原常州市唯爽卫生用品有限公司），是中国生活用纸协会会员单位，为集生产，经贸，进出口为一体的复合型企业。

Chitosan is a biopolymer, which contains high contents of amino and hydroxyl active functional groups, can be conjugated with heavy metal ions. And because of its advantages such as nontoxic, no second contamination, easy to depolymerize, it is paid more and more attention by scientific researchers.

壳聚糖作为一种天然高分子化合物，高分子段链中含有-OH、-NH2活性基团，可与重金属离子形成配合物，而且由于其无毒，不产生二次污染，生物降解性好的优点，在废水处理中的应用越来越受到科研工作者的关注。

The UV and IR spectroscopic studies of the monomer films showed that the photoreaction ratio of monomer (about 50%) was higher than the corresponding photosensitive polymer (about 10%, PVCi). The polarized IR spectra proved that obvious anisotropic absorption was displayed in the irradiated photosensitive film. With polarizing microscopy method, we found that these kinds of photoalignment films exhibited good alignment ability, and the stability of the photoalignment film could reach about 100℃. 2 A photosensitive self-assembled monolayer was fabricated that contained photo-cycloadditable groups, such as, coumarin and cinnamate. The reaction process were detected by contact angle method because the IR absorption of monolayer was very weak. The photosensitive self-assembled monolayer promote uniform alignment of nematic liquid crystals by LPUV, and it thermal stability could reach about 130℃. 3 A cationic bolaform amphiphiles was synthesized that had two photosensitive double bonds, and can be polymerized by ultraviolet. A layer-by-layer self-assembled deposition film was prepared in aqueous solution by using this material and poly (sodium 4-styrenesulfonate). The UV-Vis. spectra proved that the multilayers film was uniform and layer-by-layer. When LPUV irradiated the film, the photopolymerizable double bond underwent [2+2] cycloaddition, and the production of the reaction distributed along the polarized direction of incident LPUV. Polarized UV-Vis. spectra indicated that the irradiated self-assembled multiplayer film was anisotropic, and the dichromic ration is about 0.09, it is higher than the spin-coating method of photosensitive polymer or monomer. We used this anisotropic film as alignment layer of nematic liquid crystals, and obtained a uniform and stability alignment result, the static contrast ratio is about 100, which is very close to application of liquid crystal device. This thesis is an instance that the photochemical material was used in the physics region of liquid crystals, the route that was from photosensitive monomer, self-assembled monolayer film to self-assembled multiplayer film was undergone, by this logical research method photoailgnment of liquid crystal was extended and consummated.

围绕上述思路开展了如下工作：1合成了三种可进行光二聚反应的光敏小分子单体，LPUV 辐照制作了光控取向膜；用紫外-可见光谱法和红外光谱法分析了薄膜中的光化学反应，发现小分子的光反应程度可达到50%以上，至少比光敏高分子高出5倍；薄膜的偏振红外光谱证实，经过LPUV 辐照后薄膜出现了明显的各向异性；将小分子光控取向膜制成液晶器件，在偏光显微镜下观察看到均匀一致的液晶取向；并且热稳定性达到100℃左右，接近实用化要求。2制备了含肉桂酸、香豆素基团的自组装单层膜；采用接触角的方法监测自组装反应的动力学过程；紫外-可见光谱证实了自组装单层膜在石英基板表面形成；自组装单层膜经LPUV 辐照后能诱导液晶均匀取向，而且热稳定性可达130℃，热稳定性进一步提高。3合成了含有光敏双键的双季铵盐，在水溶液状态下将它和聚乙烯基苯磺酸钠沉积生成layer-by-layer 自组装多层膜，紫外-可见光谱证实这是一个逐层均匀的沉积；在LPUV 照射下，自组装膜中的光敏双键按照偏振方向发生[2+2]环加成反应，形成取向膜，用二向色性值评价的分子取向度高于高分子及小分子光控取向膜的水平；实验证明用自组装多层膜制成的液晶器件亮暗态均匀，静态对比度约为100，达到实用化器件的水平。

Dissertate macromolecular material and expect for its performance,and interface control technology of metal and macromolecular material connect.

论述了电子元器件组装中所采用的高分子材料及对其高性能的期望、金属与高分子材料的连接所应用的界面控制技术。

Cobalt polyamidomine dendrimer was prepared by the reaction of cobalt chloride,glyoxal and polyamidomine dendrimer of 5.0 generation.

通过氯化钴、乙二醛和第五代树状高分子反应合成了金属钴树状高分子配合物。

Fixation of direct dyes with silica gel ;2. Taking advantage of proof salt and high hydrophilic property of the silica gel and the carboxymethyl cellulose inarch polysalt of the super water-absorbent resin recombination,this paper made use of the water-absorbent composite form the inorganic polymer, sequentially advanced water-absorbent velocity and capacity of polymer water-absorbent resin in the brine.

利用具有良好耐盐和高亲水性能的硅凝胶与羧甲基纤维素接枝聚丙烯酸盐的高吸水树脂进行复合，制备出无机高分子的硅凝胶-羧甲基纤维素接枝聚丙烯酸盐耐盐高吸水复合材料，从而提高了高分子吸水树脂在盐水中的吸收能力及吸收速度，研究了复合材料的吸盐水性能，通过扫描电子显微镜观察了复合材料表面的微观结构，初步探讨了硅凝胶-羧甲基纤维素接枝聚丙烯酸盐耐盐高吸水复合材料的吸盐水机理。

Cellulose is a kind of innoxious natural polymer material with abundant natural resources, high polymerization degree, good molecule orientation and chemical stability.

纤维素资源丰富，是一类聚合度高、分子取向好、化学稳定性强的天然高分子材料，且具有许多合成高分子无法比拟的优良的生物相容性和生物降解性能，无毒无害。

It was helpful that the application range and development future of the itaconic epoxy resin could be expanded.

希望能够拓展衣康酸环氧酯树脂的应用范围，为水性高分子涂料和水溶性高分子电解质产品的研究带来一些有益的启发。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。