高分子

Abstract］ Objective To Treating the nano-SiO2 particle by silicon coupling reagent, functionalize the SiO2 by making double bond on its surface. Polymerizing on the surface of nano-SiO2 surface by the method called emulsion polymerization, the nano-SiO2 is covered by polymer to get the PMMA-KH-570-nano-SiO2 complex material. Test the surface structure of the surface of nano-SiO2 by FTIR, and test sort of its mechanical performances.Comparing the treated nano-SiO2 which is directly dispended in the PMMA emulsion with the SiO2 without any treatment, we are trying to find an effective method which can not only increase the dispersion of SiO2, but also improve the mechanical performance of the artificial teeth.

目的 通过硅烷偶联剂KH-570处理SiO2纳米粒子，向其表面引入双键使其功能化，采用乳液聚合的方法在SiO2纳米粒子表面进行接枝聚合，实现高分子对SiO2纳米粒子的表面包覆处理，制得PMMA－KH-570－SiO2纳米复合材料，采用FTIR对SiO2纳米粒子表面结构进行了表征研究，并且测定了它的多种机械性能，与表面处理过的SiO2纳米粒子直接分散至PMMA乳液中制得的复合材料、未添加任何增强物质的空白组进行比较，探索一种能够提高SiO2在基体中的分散性，为义齿复合材料的研究和开发提供理论依据和参考。

In this study, we first synthesize a conducting polymer, P3HT, via Grignard metathesis method. And we functionalize the polymer chain end of P3HT into vinyl group. After characterize from 1H NMR spectroscopy, we use the end functionalized P3HT to proceed coupling reaction with P2VP anion.

为了达到这个研究目的，我们先利用格林纳置换法合成导电高分子P3HT，并将其尾端乙烯化，在经核磁共振仪确定结构后，利用此尾端乙烯化之P3HT与P2VP阴离子反应进行接合。

Nanosized CPF(Conjugated Polymer of Furfuryl alcohol)/ZnO composite catalyst was prepared through in-situ polymerization and heat conversion. The thermal stability, morphologies, size, structure and optical absorption properties of the CPF/ZnO material were characterized by TG-DTA, TEM, XRD, XPS, IR and UV-Vis techniques.

通过原位聚合-热转化两步法，利用ZnO纳米微粒和糠醇制备出了具有大共轭结构的高分子和ZnO的纳米复合催化材料；用TG-DTA、TEM、XRD、XPS、IR和UV-Vis等技术对其热稳定性、形貌、尺寸、结构及吸光特性等进行了表征，以亚甲基蓝溶液的催化降解研究了该材料在自然光条件下的催化性能。

YTY paper reinforcement of the recently developed a new water soluble polymer material, it is a high molecular weight polymer compound ionictype, mechanim, numberrepresentationof exesting non－ionic, and numberrepresentationof anions and cations, so this in paper-making process, you can and pulp fiber molecules multi-spots adsorption, which increases the fine celluiose filler and retention; at the same time it can also promote hydrogen between cellulose, and gives the paper jiantiao dry strength significantly increase, because the reinforcement of the unique structure, so it can be used with other paper cocatalyst compouding, a broad pH range as a reinforcement of the paper is available at wood pulp and wood pulp-straw gamasid mixed pulp and paper pulp etc.

YTY纸张补强剂系近期研制成功的新型水溶性高分子材料，它是一种高分子量复合离子型的高聚物，在其分子结构中，既有非离子基团，还有阴离子、阳离子基团，因此这在造纸过程中，可以与纸浆中的纤维分子形成多点吸附，从而提高填料与细纤维素的留着率；同时它还可促进纤维素分子之间的氢健作用，使纸张干强度明显提高，由于该补强剂分子的独特结构，因此它可与其它造纸助剂复配使用，能在较宽广的pH范围内，作为纸张补强剂，可以在木浆、木浆——草浆混合浆、革浆等多种纸浆中使用。

This article introduces the research progress in the improvement of the tradition wet strength agent and the development of new environment-friendly wet strength agents such as the polyacetal, the glutaric dialdehyde, the high polymer latex and so on.

介绍了国内外改进传统湿强树脂和聚缩醛类、戊二醛、高分子胶乳类等新型环境有好型湿强剂的研究现状及其作用机理，并且指出环境友好型湿强剂是今后研究发展的方向。

Lactide, glycolide or caprolactone, biodegradable polyester and diisocyanate as materials are first bulk melt polymerized to prepare the degradable polymer with thermal deformation transforming temperature of about 37 deg.c. The obtained material is processed at temperature over melting temperature so as to shape into spiral rack, applied with stress at temperature higher than Ttrans to form shape easily operational handling and frozen to eliminate stress into the product.

本发明以丙交酯、乙交酯或己内酯，生物可降解聚酯及二异氰酸酯为原料，通过本体熔融聚合制备得到热致形变温度转化点在37℃左右的可降解高分子材料，将得到的材料在熔融温度以上进行加工、赋形制作成用于不同管腔内的螺旋管状支架；在T＞T trans 条件下施加应力，加工为便于手术操作的形状；冷冻定型消除应力，即得产品。

The pre-polymer of latic acid and glycerine was reacted with hexamethylene diisocyanate and degradable cross-linking polyucethane network material was prepared.

提出了开发可降解高分子材料这一热门课题是从根本上解决白色污染的主要途径。

Homodyne correlation spectroscopy studies of polymer ultrafineparticles in good and θ solvents revealed that translational diffusioncoefficients D of the polymers changed linearly with scattering wave vector.

高分子超微粒在良溶剂与θ溶剂中的光子相关光谱的研究表明聚合物的平动扩散系数D随散射矢量q线性变化。

High hydroscopicity resin ; high molecular compound ; absorbent ; petroleum industry ; application

高吸水能力树脂；高分子化合物；吸收剂；石油工业；应用

Objective: Acrylonitrileis a hypertoxic nitrile of colorless and bitter apricot seed. It is an important material used for synthetic resin, synthetic fiber, synthetic rubber, et al, and its manufactures is widely used in daily life and production process. Because of computers, television, automobiles and other related industries on the demand for ACN, the production and demands of ACN is increasing year by year, and the occupational exposure is also a rapidly expanding population.

目的：丙烯腈(acrylonitrile，ACN)，是一种无色、具苦杏仁味的高毒类腈化物，是合成树脂、合成纤维、合成橡胶等高分子材料生产中的重要原料，其制成品在日常生活和生产过程中使用广泛；电脑、电视、汽车等相关行业对ACN的需求量不断增加，近年来的生产量和需求量逐年上升，职业接触人群也迅速扩大。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。