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In molten ZnCl2 at high temperature, microporous organic framework based on phthalocyanine skeleton has been obtained from tetracyanopyrazine,and the dynamic trimerization reaction of 1,3,5-tricyano-benzene can lead to triazine-based material with high porosities.

在高温熔融的氯化锌存在下,四氰基吡嗪可以构建形成具有酞菁骨架的微孔材料, 1,3,5-三氰基苯可以发生三聚反应形成具有三嗪结构的微孔材料,均具有较好的多孔性能。

The characteristic of BMS silica mesostructure and the effect of various synthesis factor (including ammonia/silica molar ratio, composition concentration variation, surfactant alkyl chain length, auxiliary organic molecules such as trimethylbenzene, catalyst structure and properties, solvent and cosolvent volume and its polarity, aging and drying conditions and postsynthesis hydrothermal treatment and so on) on the resultant BMS silica structure and properties were assessed using a series of analytical techniques such as XRD, SEM, TEM,〓Si MAS NMR, TG-DTA and N〓 adsorption measurements.

结果显示BMS二氧化硅分子筛是由大量封装胶束的纳米二氧化硅颗粒(约为20-40nm)堆积形成的聚集体,其双介孔分布中较小的介孔起因于颗粒内部表面活性剂模板形成的介孔,我们称之为骨架介孔。它类似于我们在MCM-41中看到的介孔,可通过改变表面活性剂胶束的尺寸而在2.56-3.65nm的范围内进行调节。

Triphenylamine and their derivatives are excellent optical materials,and TPA is chosen as the basic framework for the design and synthesis of a series of TPA-based dyes.

三苯胺(Triphenylamine,TPA)及其衍生物是一类性能优良的光电材料,本论文即是选用三苯胺为基本骨架,通过简单的有机反应,设计和合成一系列三苯胺类有机敏化剂。

Methods:Dehydration of D-mannitol,followed by a reaction sequence of selective protection,benzylation,deprotection,tritylation,benzylation and removal of the trityl group,afforded the title compound.

以D-甘露醇为原料构建2,5-脱水-3,4,6-O-三苄基-D-葡萄糖醇的手性分子骨架,通过选择性地对多羟基的保护和脱保护达到对产物分离的目的。

Since the founding of the PRC,wo xian the cause of the rapid development of traffic, from scratch, from weak to strong, and made great progress, especially the "15" sincewo xian highway in accordance with provincial and municipal development planning, and built a road Tsubo , Gallery Park Road-based framework, the road network connectivity throughout the county, and in 2006, the realization of the "Every Village Oil."

建国以来,我县的交通事业飞速发展,从无到有,从弱到强,取得了巨大的进步,特别是&十五&以来,我县根据省市的公路发展规划,建成了津保公路、廊泊公路为主骨架,连通全县的公路网,并于2006年,实现了&村村通油路&。

In this thesis, we find that dlg is indispensible in the establishment of anterior-posterior and dorsal-ventral polarity of drosophila oocyte. Removal of Dlg function from the posterior follicle cells using the FLP/FRT system leads to disruption of oocyte skeleton reconstruction that is elicited by the failure of those posterior cells to differentiate normally in mid-oogenesis. We demonstrate that abnormity of Notch, JAK-STAT and EGFR signal pathway in dlg mutants contributes to this aberrant differentiation. dlg null mutant also blocks the normal differentiation of two groups of anterior follicle cell-stretched cell and centripetal cell, but not border cell, with a lower penetrance. However unlike the result in posterior follicle cells, Notch and JAK-STAT signaling are both undisrupted in all mutant anterior follicle cells, implying other fate determinants may be involved.

我们的研究发现,后端滤泡细胞中的Dlg在果蝇卵子发生中期卵母细胞前后轴和背腹轴建立过程中也是必须的,PFC中dlg完全缺失型突变引起PFC的分化异常,导致卵子发生中期卵母细胞骨架重组异常,Stau、Grk等极性决定蛋白定位错误。dlg突变阻碍了Notch、JAK-STAT、EGFR等调节PFC分化的信号通路的激活。dlg突变的PFC也没有获得前端滤泡细胞命运。dlg突变不影响前端滤泡细胞群中边界细胞的分化,但是在一定程度上影响伸展细胞和向心细胞的分化,并且这种影响不依赖于前端滤泡细胞Notch或JAK-STAT信号激活的异常。

Based on the crystal complex structure of ligand and receptor proteins, we have developed several strategies for grafting the binding site of the native ligand protein to unhomologous scaffold proteins.

把蛋白-蛋白相互作用区嫁接到另外一个非同源的骨架蛋白上,有助于了解蛋白质结构和功能之间的关系,并且在医学上具有潜在的价值。

By comparing with known compound A2'P 5'A,it was shown that two ribose rings of a and b adopt predominantly S conformation at 18℃, but with elevation of temperature, the N conformation of some ribose ring increaed: the torsional angles e' and β of the phosphate backbone were estimated to have a change of +2° and ±12°respectively; two ribose rings of both A2'P(CH3)5'A and were partially overlapped and the degree of overlapping of was smaller than that of the : with increasing of temperature, the adenine moiety of A2'P(CH3)5'A showed a stronger tendency to unstack than A2'P(CH3)5'A .

它们与A2′P5′A相比发现:(1)在18℃时两个核糖环是S型构象占主要成分,但随温度升高有的核糖环趋向于转化成N型构象;(2)磷酸骨架的扭角ε′和β分别改变±2°及±12°;(3)A2′P(CH_3)5′A和的两个核糖环均属部分重叠,并且前者的重叠程度小于后者;(4)随着温度升高,A2′P(CH_3)5′A比A2′P(CH_3)5′A有着更强的去堆积效应。

Particularly, the neutral anion fluorescence chemical sensor uses cholic acid molecules as the molecule frame, and introduces a neutral thiourea or ureido to the positions of a 3 bit carbon atom and a 24 bit carbon atom to be used as a bonding unit; a fluorescence chemical functional group is introduced to the positions of the 3 bit carbon atom and the 24 bit carbon atom or to other positions and used as a signal unit, and then a neutral anion fluorescence chemical sensor is synthesized.

具体而言是以胆酸分子为分子骨架,在其3位碳原子和24位碳原子上引入中性硫脲或脲基,作为键合单元;在3位碳原子和24位碳原子上或其他位置引入具有荧光化学官能团,作为信号单元,合成中性阴离子荧光化学传感器。

Causes to the lubricating oil leakage in the frame-work of the speed variator in the expansion turbine EGT240NS are analyzed and a new type of magnetic mechanic oil seal is introduced in the present paper.

分析了EGT240NS膨胀机变速器骨架油封漏油原因,介绍了一种新型油封———磁力机械油封的应用。

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With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务,乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐,因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。

Closes the eye, the deep breathing, all no longer are the dreams as if......

关闭眼睛,深呼吸,一切不再是梦想,犹如。。。。。。