香豆素

A few overseas scholars have alreadyconducted some studies to determine the chemical constituents in the leaves, stem, roots,skin, and seeds of the genus Calophyllum of the Guttiferae family, and thus havesuccessfully extracted chemical compounds such as coumarins, xanthonoids, flavonoids,and terpe...

国外学者对红厚壳属植物的叶、茎、根、皮、种子等部位的化学成份进行了大量的研究，得到了呫吨酮类、香豆素类、黄酮类、萜类等多种类型化合物。

The results were as follows:ethanol volume fraction 70%,solid liquid ratio 1∶10,extraction time 10 min,temperature 50℃,ultrasonic power(160 W). Capsella bursa-pastoris ; alkaloids ; ultrasonic ; extraction

近年来，人们用超声波技术提取植物中的生物碱、黄酮、多糖、皂甙、蒽醌、香豆素等生物活性物质[3，4]，结果都表明超声波提取比常规提取法费时少

Some coumarin derivatives are synthesized through Pechmann reaction with catalytical amount of sulfuric acid.

在催化量硫酸的存在下，用微波辐射进行Pechmann反应，制备香豆素衍生物，获得中等至良好的产率。

Aqua, Sorbitol, PPG-1 PEG-9 Lauryl glycol ether, Hydrolyzed elastin, Hydrolyzed wheat gluten, Hydrolyzed collagen, Hydrolyzed glycosamino-glycans, Humulus lupulus, Propylene glycol, Triethanolamine, Sodium hydroxide, Carbomer, Maris limus extract, Ostrea extract, Imidazolidinyl urea, Parfum, Benzyl salicylate, Coumarin, Alpha isomethyl ionone, Hexyl cinnamal, Buthylphenylmethylpropionate, Linalol, Methylisothiazolinone, Methylchloroisothiazolinone.

水，山梨醇， PPG 公司- 1聚乙二醇- 9十二烷基醇醚，水解弹性蛋白，水解小麦面筋蛋白，水解胶原蛋白水解粘多糖，多聚糖，啤酒花提取物花，丙二醇，三乙醇胺，氢氧化钠，卡波姆，马里斯提取物，牡蛎提取物，咪唑烷基脲，香水，水杨酸苄酯，香豆素，阿尔法 l 紫罗兰酮，己基肉桂醛，丁苯基甲基丙醛，芳樟醇，甲基异噻唑啉酮，甲基氯异塞唑晽酮。

Condensation of resorcinol or phloroglucinol with sodium hydrogen malate in the presence of catalytic sulfuric acid leads to the synthesis of natural bioactive umbelliferone and daphnetin under microwave irradiation.

在适量硫酸的存在下，用微波辐射合成了天然活性香豆素伞形花内酯和瑞香内酯。

Ingredients Aloe vera gel*, nettle extract*, alcohol denat.

芦荟胶，荨麻萃取精华，酒精，水，苯氧乙醇，黄胞胶，薰衣草精油，香豆素，香叶醇，柠檬油精，芳樟醇。

The UV and IR spectroscopic studies of the monomer films showed that the photoreaction ratio of monomer (about 50%) was higher than the corresponding photosensitive polymer (about 10%, PVCi). The polarized IR spectra proved that obvious anisotropic absorption was displayed in the irradiated photosensitive film. With polarizing microscopy method, we found that these kinds of photoalignment films exhibited good alignment ability, and the stability of the photoalignment film could reach about 100℃. 2 A photosensitive self-assembled monolayer was fabricated that contained photo-cycloadditable groups, such as, coumarin and cinnamate. The reaction process were detected by contact angle method because the IR absorption of monolayer was very weak. The photosensitive self-assembled monolayer promote uniform alignment of nematic liquid crystals by LPUV, and it thermal stability could reach about 130℃. 3 A cationic bolaform amphiphiles was synthesized that had two photosensitive double bonds, and can be polymerized by ultraviolet. A layer-by-layer self-assembled deposition film was prepared in aqueous solution by using this material and poly (sodium 4-styrenesulfonate). The UV-Vis. spectra proved that the multilayers film was uniform and layer-by-layer. When LPUV irradiated the film, the photopolymerizable double bond underwent [2+2] cycloaddition, and the production of the reaction distributed along the polarized direction of incident LPUV. Polarized UV-Vis. spectra indicated that the irradiated self-assembled multiplayer film was anisotropic, and the dichromic ration is about 0.09, it is higher than the spin-coating method of photosensitive polymer or monomer. We used this anisotropic film as alignment layer of nematic liquid crystals, and obtained a uniform and stability alignment result, the static contrast ratio is about 100, which is very close to application of liquid crystal device. This thesis is an instance that the photochemical material was used in the physics region of liquid crystals, the route that was from photosensitive monomer, self-assembled monolayer film to self-assembled multiplayer film was undergone, by this logical research method photoailgnment of liquid crystal was extended and consummated.

围绕上述思路开展了如下工作：1合成了三种可进行光二聚反应的光敏小分子单体，LPUV 辐照制作了光控取向膜；用紫外-可见光谱法和红外光谱法分析了薄膜中的光化学反应，发现小分子的光反应程度可达到50%以上，至少比光敏高分子高出5倍；薄膜的偏振红外光谱证实，经过LPUV 辐照后薄膜出现了明显的各向异性；将小分子光控取向膜制成液晶器件，在偏光显微镜下观察看到均匀一致的液晶取向；并且热稳定性达到100℃左右，接近实用化要求。2制备了含肉桂酸、香豆素基团的自组装单层膜；采用接触角的方法监测自组装反应的动力学过程；紫外-可见光谱证实了自组装单层膜在石英基板表面形成；自组装单层膜经LPUV 辐照后能诱导液晶均匀取向，而且热稳定性可达130℃，热稳定性进一步提高。3合成了含有光敏双键的双季铵盐，在水溶液状态下将它和聚乙烯基苯磺酸钠沉积生成layer-by-layer 自组装多层膜，紫外-可见光谱证实这是一个逐层均匀的沉积；在LPUV 照射下，自组装膜中的光敏双键按照偏振方向发生[2+2]环加成反应，形成取向膜，用二向色性值评价的分子取向度高于高分子及小分子光控取向膜的水平；实验证明用自组装多层膜制成的液晶器件亮暗态均匀，静态对比度约为100，达到实用化器件的水平。

Twenty compounds have been isolated and structure-elucidated, ten of which were new compounds including one new skeleton diterpene malloapeltin A, 5 cembrene-type diterpenes, two dolabradane-type diterpenoids, one triterpene ester malloapeltin B and one coumarinolignoid compound 5'-demethyl aquillochin.

其中有10个是新化合物，包括一个新骨架的二萜，五个枯烯类的二萜，两个罗柏烷型的二萜，一个三萜的对苯二甲酸酯和一个香豆素木脂体类化合物。

This protocol could also be used for the selective reduction of the endocyclic double bond of the 3-electron withdrawing group substituted coumarins. This method is clean, mild, and efficient.2 ZrCl_4 / HEH was found to be a selective and efficient reagent combination for the direct reductive amination of electron rich aldehydes and ketones with weakly basic amines after scanning various catalysts such as InCl_3, BiCl_3, CF_3COOH and so on.

图一 1。我们用汉斯酯作为有机还原剂，乙醇为溶剂，实现了4-甲叉基噁嗯唑酮和吡唑酮环外双键的高选择性还原；此外，我们还将这一还原体系用于3-吸电子集团取代-3，4-二氢香豆素环内双键的选择性还原。

Esculetin had the highest affinity toward the binding site of XO, and this was due to hydrogen bonding interactions. The hydroxyl group at C-6 formed hydrogen bonds with the carboxyl group Glu802 that played critical role on XO binding.

在8种香豆素衍生物中发现esculetin与黄嘌呤氧化酶的亲和力最高，因为在esculetin的结构上，C-6的OH基团可与麸胺酸802的COOH基团形成氢键，此键结对於抑制黄嘌伶氧化酶活性是很重要的，因而增加了两者结合的稳定性。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失