顺式的

B3LYP/6-311++G** calculations were carried out to study the trimethylamine catalyzed Baylis-Hillman reaction between acraldehyde and formaldehyde.

采用密度泛函DFT-B3LYP方法在6-311++G**基组下计算研究了三甲胺催化的丙烯醛和甲醛的Baylis-Hillman反应的微观过程，获得了两种反应通道(分别对应于顺式-丙烯醛和反式-丙烯醛)的势能面。

The optimized structures and energies of the reactants, intermediates, transition states and products of two reaction channels (corresponding to syn-acraldehyde and anti-acraldehyde) in gas or in methanol solvent were obtained. The potential energy profiles reveal the processes of the trimethylamine-catalyzed Baylis-Hillman reaction between acraldehyde and formaldehyde in gas or in methanol solvent at the microscope level.

通过研究，获得了三种情况下两种反应通道(分别对应于顺式-和反式-丙烯醛)中涉及的反应物、产物、中间体、过渡态的优化结构及其能量，并由此得到了反应的势能面图，在电子微观层次上揭示了三甲胺催化的丙烯醛和甲醛的Baylis-Hillman反应的微观过程。

In this paper a tube wall reactor has been studied for the catalytic oxidation of benzene to maleic anhydride.

以苯催化氧化制顺酐的反应为研究对象，对管壁式催化反应器进行了研究。

This enhancer is regulated by a composite cis-acting element, the FOX:ETS motif, which is bound and synergistically activated by Forkhead and Ets transcription factors.

这个增强子受到一种复合顺式作用元件的调控——FOX：ETS，它能够被Forkhead和Ets转录因子约束或激活。

The results show that the complexes 4a, 5a, 6a from reactions of pyrazine, 4,4\'-bipyridine, bpe and Cp~*Co[S_2C_2B_(10H_(10)] have similar transform structure.

反应表明，由同一类型的二齿配体pyrazine，4，4\'-bipyridine，bpe所得到的化合物4a，5a，6a是具有类似反式结构的化合物，而用bpo作配体得到的化合物7a是一个顺式结构的化合物。

Work was also carried out. From numerous facts of ourprevious work, it might be seen that the stereoselectivity of aziridination viasulfonium ylides depends upon the sulfonium salts and C=X compounds. The moreactive the sulfonium ylide and C=X compound are, the more cis product is generated.Whereas, trans product will be major if the activity of the sulfonium ylide and C=Xcompound is low.

通过对以往工作的总结，我们发现，在经由硫叶立德途径的小环化反应中有一个经验规律：产物的立体选择性与所用的锍盐和C=X化合物有关，即锍盐和C=X化合物的活性增强，有利于形成顺式产物，反之，锍盐和C=X化合物的活性降低，有利于反式产物的形成。

Particular attention will bepaid in the field of gene expression regulation to high-throughput screening andidentification of cis-acting elements within the genome and to investigation ofinteraction manners of these regulatory sequences with regulatory proteins in theconditions of in vivo chromatin contexts.

如何在体内的染色质环境下，高通量、大规模地筛选与检测基因组内的顺式作用元件并研究其与反式作用因子间的相互作用，是当前和今后一个时期内基因表达调控领域内的研究重点之一。

The influence of microwave radiation on Ullmann reaction has been investigated by three Ullmann reactions, including triphenylamine formed by treating the diphenylamine with bromobenzene or Chlorobenzene which substitutes Iodobenzene; 4,4\'-dimethyltriphenylamine formed by treating 4,4\'-dimethyldiphenylamine with bromobenzene which substitutes Iodobenzene; 4,4\',4-trinitrotriphenylamine formed by treating 4-chloronitrobenzene with p-nitroaniline in this paper.

实验表明，在微波辐射条件下，顺式比反式迈克尔反应活性高；若在丁烯二酸的双键上引入甲基后，降低了进行迈克尔加成反应的活性；引入酯基对双键的影响比腈基有利于进行迈克尔反应，丙烯酸甲酯较丙烯腈的迈克尔反应活性高。

Optical control of the primary step of photoisomerization of the retinal molecule in bacteriorhodopsin from the all-trans to the 13-cis state was demonstrated under weak field conditions (where only 1 of 300 retinal molecules absorbs a photon during the excitation cycle) that are relevant to understanding biological processes.

在弱场条件下（整个兴奋周期中，300个视黄醛分子中只有一个吸收光子），细菌视紫红质中视黄醛分子的从全反式到13－顺式状态的光致异构化的最初阶段的光学控制被阐明，这与生物学过程的理解有关。

The estimated tunneling probability of the H13 proton from one well to another well shows that the life time of the proton staying in one of these wells is about 6×10^2 a. It is too long to let tautomers of cytosine be in thermodynamical equilibrium in a room temperature gas phase experiment.

估算出的H13质子从一个势阱到另一个势阱的穿透几率表明质子呆在其中一个势阱中的寿命大约是6×10^2 a，这使胞嘧啶和它的顺式亚胺式互变异构体在室温气相实验中远不能达到热平衡。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。