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The structure analysis indicates that the reverse symmetry ligand H4LB molecules are linked into a 2D supermolecular network by two types of hydrogen bonds. One type occurs between the oxalamide oxygen group and the phenol hydroxyl qroup of the nearest molecule with d=2.906(2) and ∠O-H…O=151.8°. The other type is between the oxalamide nitrogen group and the oxalamide oxygen group of anther molecule with d=2.849(2),∠N-H…O=158.7°.

晶体结构研究表明配体H4L为顺式桥联分子,晶体中存在两种氢键,一种是草酰胺基团的O原子与苯环上的酚羟基形成O-H…O氢键[d=2.906(2),∠O-H…O=151.8°];另一种是草酰胺基团的氨基与相邻草酰胺基上的O原子形成N-H…O氢键[d=2.849(2),∠N-H…O=158.7°],通过上述两种氢键将化合物H4LB连接成二维网络结构。

Erve growth factor combined with its receptor, activated Ras - MAP kinase , mitogen - activated protein kinase kinase is the important regulating factor that make IkB kinase, IKK, phosphated, IkB kinase make the IκBα:(the subunit of NF -κB ) phosphated, the phosphated IkBα degraded, and p65 - p50 heterodimer can be formed, then the heterodimer translocated to nucleus and combined with the promoter domain or other consensus sequence.

GF与其受体相结合,最后可以激活Ras-有丝分裂激活的蛋白激酶途径,有丝分裂激活的蛋白酶激酶(MEKK1)是IγB激酶发生磷酸化的重要调节因子,IKK使NF-κB的亚单位IKBα发生磷酸化,磷酸化的IKBα发生降解,而最后留下p65-p50二聚体,该二聚体然后转位到细胞核内与κB基因的增强子区域或与他的顺式作用序列结合。

From the starting material: propargyl alcohol, the building block was prepared easily by Jones oxidation, esterfication, bromination and selective trifluoromethylation.

第一部分:从丙炔醇出发,经过Jones氧化,甲酯化,顺式二溴化,再选择性地在酯基的β位实现三氟甲基化,合成了目标含氟砌块。

The chiralMn complexes, especially Jacobsenscatalyst, display high enantioselectivity for asymmetric epoxidation of conjugated cis-di-, tri-and some tetrasubstituted prochiral alkenes in the NaClO biphasic system, but the epoxidationreaction generally requires a long reaction time even in the presence of an axial ligand.

在NaClO两相体系中,手性Mn配合物,尤其是Jacobsen催化剂,对共轭顺式二取代、三取代和部分四取代烯烃的不对称环氧化具有高的对映选择性,然而即使存在轴向配体,环氧化反应也通常需要长的反应时间。

The chiralMn complexes, especially Jacobsen\'scatalyst, display high enantioselectivity for asymmetric epoxidation of conjugated cis-di-, tri-and some tetrasubstituted prochiral alkenes in the NaClO biphasic system, but the epoxidationreaction generally requires a long reaction time even in the presence of an axial ligand.

在NaClO两相体系中,手性Mn配合物,尤其是Jacobsen催化剂,对共轭顺式二取代、三取代和部分四取代烯烃的不对称环氧化具有高的对映选择性,然而即使存在轴向配体,环氧化反应也通常需要长的反应时间。

MOTIVATION: In order to facilitate a systematic study of the promoters and transcriptionally regulatory cis-elements of the yeast Saccharomyces cerevisiae on a genomic scale, we have developed a comprehensive yeast-specific promoter database, SCPD.

动机:为了促进在基因组范围上对酵母中启动子和转录调控顺式调控元件的系统性研究,我们开发了一个全面的酵母特异的启动子数据库----SCPD。

However, this contradicts other experiments that have demonstrated that treated tumor cells do not contain bare platinum, but rather undegraded cisplatin—accumulated in certain organelles.

其中就含有一些完整的顺式铂氨。小泡接着进入胞内,并且和包括细胞核在内的细胞器发生接触。

Among them, p-coumaric acid, cis-aconitic acid, vanillic acid, citric acid were well known antiinflammation active components.

已知对羟基桂皮酸、顺式乌头酸、对羟基苯甲酸、香草酸、柠檬酸具有抗炎活性。

Treatment of polystyrene-supported selenium ,bromide with lithium acetylides afforded polystyrene-supported selenoacetylene, which reacted with dicyclohexylborane giving a way for stereoselective synthesis of polymer-supported- vinylic selenides .

聚苯乙烯负载硒溴与炔基锂反应合成聚苯乙烯负载炔基硒醚,再与二环己基硼烷反应制得聚苯乙烯负载顺式烯基硒醚;此负载型烯基硒醚在NiCl2(PPh3)2存在下与格氏试剂发生偶联反应,提供了一种有效的-1,2-二取代乙烯的固相有机合成方法

This requirement may be satisfied by the submission of information such as the following: name (generic name, chemical name, code number ); Chemical Abstracts Service number if available; description (e.g., appearance, color, physical state ); molecular formula and molecular weight; structural formula (including ionic state if applicable ); stereochemistry identifying chiral centers, cis-trans isomerism, etc.

有的话、描述(如:外观、颜色、物理状态)、分子式和分子重量、结构式、立体化学(找出手性中心、顺式贯穿异性等)、对映结构体或固态形式比率(如:外消旋物、规定的异构体、对映异构物和固态形式的混合物)、溶解性档案、分隔系数、溶液pH值、解离常数、熔点和沸点、拆射率、精确重力。

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I didn't watch TV last night, because it .

昨晚我没有看电视,因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来,在北京的很多小区里,电梯液晶电视被撤了下来。

I'm running my simile to an extreme.

我比喻得过头了。