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In their structures, polyanions are bridged by Ln ions via the coordination of the bridging oxygen atoms and terminal oxygen atoms, forming a W–Ot′–Ln–Ob–W linkage; and through the W–Ot′–Ln–Ob–W linkage a one-dimension infinite linear chain with alternating cations and anions is formed.

在相似的合成条件下,我们向原有体系内加入顺丁烯二酸作为有机配体,合成了化合物7,其7的基本结构和化合物1-6很相似,但有一个顺丁烯二酸阴离子取代了一个NO3-离子的位置。

The benzene (or 80% of the butene) and the excess air in a fluidized bed or fixed-bed reactor for oxidation reaction of maleic anhydride was absorbed into the cycle of acid maleic acid.

将苯(或80%的丁烯)与过量空气在流化床或固定床反应器中进行氧化反应生成顺丁烯二酸酐,被循环的酸液吸收成顺丁烯二酸。

On the NiO/SiO〓 catalyst prepared by IM, the main hydrogenation product of MA was SA, the activity and selectivity were almost no relation with the nickel content and nickel species 3. Summarizing the characterization and activity evaluation of the catalysts, we concluded: On nickel based catalyst, when NiO was crystallite, and the Ni〓 that was prepared by reducing, hydrogenation of the MA could lead to SA but not to γ-BL; when NiO was cluster and had a properly interaction with the support, the Ni〓 prepared by reducing, could hydrogenate MA to SA then to γ-BL. When NiO cluster and crystallite were both existed on the catalyst, the hydrogenation products were mixture of SA and γ-BL, and the amounts of SA and γ-BL were related with the ratio of cluster and crystallite.

综合催化剂的表征和活性评价得出:当镍基催化剂上氧化镍以结晶态存在,经氢还原后的零价镍可使顺丁烯二酸酐加氢得到丁二酸酐,丁二酸酐难以进一步加氢为γ-丁内酯;当镍基催化剂上氧化镍以簇团形式存在,与载体之间有适当的相互作用时,经氢还原后的零价镍可使顺丁烯二酸酐加氢得到的丁二酸酐进一步加氢为γ-丁内酯;若催化剂上氧化镍既有结晶态又有簇团形式时,随二者含量比例不同而得到丁二酸酐和γ-丁内酯的混合物。

In recent years, as the Maleic anhydride is being produced in larger scale a number the investigation have been reported on the hydrogenation of the MA to SA,γ-butyrolactone , succinic anhydride , tetrahydrofuran and 1, 4-butanediol which are important chemicals in medicine, pesticide and petrochemistry.

近些年来,由于顺丁烯二酸酐生产规模的大型化,以廉价的顺丁烯二酸酐为原料合成高附加值化学品的研究倍受青睐。

Single dibasic acid can be identified by infrared spectroscopy while mixed dibasic acids have to be differentiated by paper chromatography in isopro-pan...

顺丁烯二酸酐固化的环氧树脂经水解与分离后得到的主要是反丁烯二酸和少量顺丁烯二酸,前者的含量随固化温度的提高而增多,因而确证这一顺-反异构化反应是在固化过程中受热,而不是在水解,酸化时受化学试剂的作用产生的。

Niobic acid; catalytic synthesis; di-2-ethylhexyl phthalate; di-n-octyl phthalate; di-2-ethylhexylmaleate; di-n-octyl maleate; cyclohexene; modification of catalyst; dynamics of esterification

工程科技I,化学,有机化学铌酸;催化合成:邻苯二甲酸二辛酷;邻苯二甲酸二异辛酯;顺丁烯二酸二辛酯:顺丁烯二酸二异辛酯:环己烯;改性;动力学

M treatment materials, and also tartaric acid and no maleic acid detected in G. v treatment materials. Inoculation also increased the content of organic acid secretion (increased by 19.80~56.87 mg/kg) of trifoliate root, and the application of AlPO4 greatly increased organic acid content (increased by 20.06~21.84 mg/kg); uninoculated plant root secreted a bit of organic acid; Mycorrhizal poncirus trifoliata seedlings excreted malic acid (42.87%), citric acid (39.22%) and oxalic acid (12.06%).

接种AM真菌的根系分泌的有机酸种类与对照有所不同,未接种处理枳分泌的有机酸有草酸、苹果酸、乳酸、乙酸、顺丁烯二酸和柠檬酸等6种,而接种G.m的则检测到草酸、酒石酸、苹果酸、乳酸、乙酸、柠檬酸、丁二酸等7种,G.v处理的检测到酒石酸,接种处理均未检测到顺丁烯二酸;接种丛枝菌根真菌增加了枳根系分泌有机酸的量比未接种处理增加19.80~56.87 mg/kg,且施用AlPO4后有机酸含量显著增加(增加20.06~21.84 mg/kg;未接种植株根系仅分泌少量有机酸;接种植株根系分泌的有机酸以苹果酸(42.87%)、柠檬酸(39.22%)和草酸(12.06%)为主。

The influence factors such as amount of catalyst,molar ratio of maleic anhydride to n-butanol,and reaction time on the yield of dibutyl maleate were discussed.

以La2(SO4)3/SiO2为催化剂,顺丁烯二酸酐和丁醇为原料,合成内增塑剂顺丁烯二酸二丁酯,探讨了催化剂用量,酐醇物质的量比以及反应时间等对收率的影响。

Effects of microwave power, reaction time, reaction temperature, solvent etc. on reaction were studied by a single factor tests. The results show that maleic acid is more active than fumaric acid; the introduction of methyl group on the double bond can weak the reactivity of the Michael addition reaction; the ester base is more propitious to complete the Michael addition reaction than the nitrile base.

为研究微波下迈克尔反应的规律,本文采用单模聚焦微波有机合成仪,通过对顺丁烯二酸、反丁烯二酸和氨水合成DL-天冬氨酸、顺式3-甲基丁烯二酸和氨水合成3-甲基天冬氨酸、丙烯酸甲酯和氨水合成β-丙氨酸、丙烯腈和氨水合成β-氨基丙腈等五个反应对迈克尔加成反应进行了研究。

Dibutyl maleate was prepared from maleic anhydrideand n- butyl alcohol in the presence of tungstophosphoric acid or molybdophosphoric acid .

顺丁烯二酸酐和正丁醇为原料,分别以磷钨酸和磷钼酸为催化剂,合成了顺丁烯二酸二丁酯。

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