非溶剂

The research progress on the formation of ordered molecular assembly in imidazolium ILs, such as liquid crystal, micelle, vesicle, microemulsion was reviewed. ILs can act as solvents, co-solvents, or surfactants to form liquid crystals. They also can be substituted for polar, apolar, or surfactant components in microemulsion to prepare various microemulsion systems ILs-in-oil, oil-in-ILs and bicontinuous B.

咪唑类离子液体可以作为溶剂、助溶剂和表面活性剂形成液晶；离子液体可以分别取代微乳液体系中的极性组分、非极性组分或表面活性剂，形成油包离子液体、离子液体包油和双连续的新型微乳液体系。

The invention discloses an InP quantum point preparing method, comprising the steps of:(1) mixing InCl3 with trioctylphosphine oxide, and preserving heat at 90-110DEG C to prepare a solution whose In content is 0.1-0.3mol/L;(2) raising temperature to 130-180DEG C, and charging argon gas;(3) injecting PSi(CH333 into InCl3-TOPO compound in the molar ratio of 1 to 1-1 to 2;(4) when the solution color turns into transparent red or orange, raising temperature to 260-270DEG C and preserving heat;(5) lowering temperature to 90-110DEG C and injecting dodecyl amine, decyl amine or mercaptan;(6) dissolving reacting mixture in nonpolar solvent to form transparent colloidal solution, then adding in polar solution until the colloidal solution is muddy, and centrifugally separating and obtaining deposits and supernatant; and (7) centrifugally separating the supernatant, where the above steps (1)-(5) are performed.

本发明公开了一种InP量子点的制备方法，其步骤为：①将InCl 3 与三辛基氧膦混合，在90～110℃保温制得In含量为0.1～0.3mol/L的溶液；②升温到130～180℃，通入氩气；③将PSi(CH 3 3 3 注射入InCl 3 -TOPO复合物中，其摩尔比为1∶1～1∶2；④待溶液颜色变为透明的红色或橙红色，将升温260～270℃保温；⑤降温到90～110℃，注入十二胺、癸胺或硫醇；⑥将反应混合物溶于非极性溶剂，形成透明的胶体溶液，然后加入极性溶剂，直至胶体溶液出现混浊状，然后离心分离获得沉积物和上层清液；⑦取上层清液进行离心分离。上述步骤①～⑤在保护气氛下进行。

In cyclohexanone/acetone mixed solvent, the initial SPS concentration is high.

在非良溶剂体系，可乳化的最大初始浓度比良溶剂体系的高。

Electropolar solvent such as THF may destroy the polyetherimide layer,while non-electropolar solvent such as petroleum ether cannot solve vinyl acetic acid cobalt.

极性溶剂如四氢呋喃会溶解PEI层，而非极性溶剂如石油醚又不能溶解丁烯酸钴。

The results showed that polar acetone was beneficial to the desorption of methanol, however the effect of nonpolar heptane on the extraction of methanol was more evident.

研究表明，极性溶剂丙酮能够促进甲醇脱附，而非极性溶剂正庚烷对孔道中甲醇有更强的萃取能力。

The conclusions were as follows: theνO-H andνC=O IR absorption maxima shifted towards higher wave numbers after imprinting 17β-estradiol on TFMAA-co-TRIM copolymer with the red shift of theνO-H groups being apparent after precipitation polymerization for 16h while that forνC=O groups being observed after polymerization for 24h. A strong interaction between TFMAA and 17β-estradiol was confirmed by the high selectivity for 17β-estradiol, as indicted by the values of the separation factor of isomers of 17β-estradiol/17α-estradiol (2.28) and the imprinted factor (3.01). Particle diameter of TFMAA-co-TRIM polymer was between 300 nm and 1.5μm, which suited well for solid phase sorbent throughout at low column pressure. The recognition of imprinting TFMAA-co-TRIM polymer for sterol molecules was driven by enthalpy eluted with acetronitile, and low temperature was in favor of the separation of sterol structure analogues on imprinting column. TFMAA-co-TRIM polymer possessed of determinate anti-heat stability, with melting point beginning at 255.84℃, Tp=257.40℃, control TFMAA-co-TRIM polymer and imprinting TFMAA-co-TRIM polymer were respectively decompounded at 267.79℃and 343.11℃, and solid micro-extraction noddle prepared by the special polymerization also showed definite recognition for 17β-estradiol by GC/MS detecting at 270℃. By selection of various washing and elution solvents, elution reagents of close polymerization system were of more advantage in template molecules retention and recognition on molecularly imprinted solid phase extraction column. At a certain extent, progesterone, 17α-estradiol, 17β-estradiol and 4-androstene-3, 17-dione could be intercepted on the MISPE column. Especially, MISPE had high selectivity for progesterone, and imprinting TFMAA-co-TRIM polymer could achieve adsorption balance within 50 min by absorption kinetics test for 17β-estradiol. However, MISPE column showed better selectivity and enrichment property for 17β-estradiol than C18 and CSPE columns according to the data from HPLC and GC/MS analyses. Recovery of 17β-estradiol on MISPE column was up to 85.5% while when prime extracting solution of milk powder was sampled, the recovery of CSPE and C18 columns were 43.7% and 30.7%, respectively.

通过研究阐明：紫外聚合产物TFMAA-co-TRIM中的νO-H振动吸收峰在聚合16h后红移，νC=O振动吸收峰在聚合24h后红移；TFMAA-co-TRIM对雌二醇异构体的印迹因子达到了3.01，α为2.28，优于其它功能单体参与得到的聚合物识别特性；TFMAA-co-TRIM聚合物粒径介于300 nm至1.5μm之间，作为色谱固定相具有良好的通量和低的柱压；在乙腈流动相中，TFMAA-co-TRIM分子印迹固定相的分离过程主要被焓驱动，低温有利于分子印迹固定相分离甾醇结构类似物；TFMAA-co-TRIM分子印迹聚合物在255.84℃时开始熔融，Tp=257.40℃，聚合物CP的降解温度在267.79℃，MIP降解温度在343.11℃，制备的固相微萃取头初步经GC/MS 270℃的耐热性测定；不同的洗提溶剂筛选证明了选择接近聚合溶剂的洗脱体系更有利于MISPE发挥识别效应；分子印迹固相萃取柱对孕酮、17α-雌二醇、17β-雌二醇和雄烯二酮都具有不同程度的保留特性，可作为此类化合物的吸附材料，特别对孕酮强保留的富集特性，可作为孕酮的选择性识别吸附剂，其分子印迹聚合物对17β-雌二醇的吸附动力学测定显示在50 min内基本达到吸附平衡，具有作为传感器核心敏感材料的潜力；对比萃取奶粉中17β-雌二醇性能，MISPE柱比非分子印迹固相萃取柱和C18柱具有更高的保留，回收率依次为85.5%，43.7%和30.7%。

In the non-polar solvent, auto-sensitized photooxidation of the aminated hypocrellins is mainly involved with the singlet oxygen mechanism.

三。在非极性溶剂中，胺基衍生物的自敏光氧化主要涉及单重态氧的机制，在极性溶剂中则以超氧负离子自由基的机制为主。

Some approved aneugens Trip terygiuwlIypogaucum (evelHutch, colchicine, thiabendazole, a tropine sulfate,d-ubocurarine was added into the reactive system respectively and the changes of their absorption values were taken down during different periods under the conditions of 37 0C and 350nm .

本研究通过多步聚合和解聚合反应从猪脑中分离纯化微管蛋白，建立微管蛋白的体外聚合和解聚合反应平衡体系，并将已证实的非整倍体诱发剂（昆明山海棠根部水抽提物、2-（4′-噻唑）苯丙咪唑、硫酸阿托品、d-筒箭毒碱）分别加入此反应平衡体系中，于37℃、350nm条件下，记录此体系不同时期的吸光值变化，与阳性对照物和溶剂对照处理平衡体系后的吸光值在相同时间点作比较，以此评估这几类非整倍体诱发剂对离体条件下的微管蛋白聚合的影响，寻求这几类非整倍体诱发剂是否可通过抑制微管蛋白聚合作用途径而诱发非整倍体。

A SPE procedure was suggested for extracting and concentrating fisetin by using different volume fractions of ethanol in aqueous solution as the loading conditions.

分别以中药黄栌的主要成分非瑟酮为印迹分子、丙烯酰胺为功能单体及乙二醇二甲基丙烯酸酯为交联剂，通过封管聚合法合成了分子印迹聚合物；将其装于自制的固相萃取柱中，研究了以不同体积比的乙醇-水溶液为溶剂时非瑟酮在柱上的保留行为；通过优化清洗及洗脱条件，使非瑟酮与它的结构相似物槲皮素在柱上得到了很好的分离。

Moreover, in comparison of birth lengths in eight subgroups defin ed by organic solvent status (nonexposure/exposure) and maternal genotype for MS P1 and GSTM1, in the presence of organic solvents ' exposure , the birt h length was a clear gradient of adverse effects .

3我们将芳香烃溶剂，母亲基因MSP1（野生型、杂合子/突变型）与基因GSTM1分为8组，在芳香烃溶剂暴露组，可见母亲基因型致出生身长呈斜线降低，然而在芳香烃溶剂非暴露组，其母亲基因型对出生身长的影响无明显改变。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了