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Furoic acid was synthesied by catalytic oxidation in the mimic enzyme microreactor, which was constructed by strong stirring a non homogeneous phase system of organic reagent and water using β cyclodextrin derivative as an imitating enzyme. This method is easy to handle and more effective than the corresponding reaction in homogeneous phase.

在水与有机试剂组成的非均相体系中,用β环糊精(β cyclodextrin ,缩写:β CD)衍生物模拟生物酶,以强力搅拌下分散在有机溶剂中的小水珠作为微型反应器进行糠醛催化氧化为糠酸的反应,停止搅拌后体系立即分层,产物在有机相,残留的原料和模拟酶在水相。

Furoic acid was synthesied by catalytic oxidation in the mimic enzyme microreactor, which was constructed by strong stirring a non homogeneous phase system of organic reagent and water using β cyclodextrin derivative as an imitating enzyme.

在水与有机试剂组成的非均相体系中,用β环糊精(β cyclodextrin ,缩写:β CD)衍生物模拟生物酶,以强力搅拌下分散在有机溶剂中的小水珠作为微型反应器进行糠醛催化氧化为糠酸的反应,停止搅拌后体系立即分层,产物在有机相,残留的原料和模拟酶在水相。

The one is assigned to transient absorption of the inhomogeneously broadened ground state absorption spectrum, while the other is the response of the solvent to the change of the electron configuration in the excited state due to solvation dynamics of the polar solvent molecules.

认为一个来源于基态吸收谱的非均匀展宽,而另一个则来源于溶剂对于激发态分子结构变化的响应。

Under normal temp., PVF2 has a fine corrosion resistance to many organic solvents like halogen, halogenated hydrocarbon, strong oxidant, boiling acid and alkali; UHMWPE has a fine corrosion resistance to inoxidable acid (dilute sulfuric acid, nitric acid and large concen-tration hydrochloric acid, phosphorus acid, hydrofluoric acid, formic acid and acetic acid), ammonia, amine and various alkali and salty solutions. Both materials can't resist the corrosion of strong oxidable acid.

在常温下,PVF2对卤素、卤代烃、强氧化剂、沸酸、碱等多种有机溶剂都有良好耐蚀性;UHMWPE对非氧化性酸(稀硫酸、硝酸及浓度较大的盐酸、磷酸、氢氟酸、甲酸、乙酸)、氨和胺及各种碱、盐溶液都有良好的耐蚀性,两种材料都不耐强氧化性酸的腐蚀。

Under normal temp., PVF2 has a fine corrosion resistance to many organic solvents like halogen, halogenated hydrocarbon, strong oxidant, boiling acid and alkali UHMWPE has a fine corrosion resistance to inoxidable acid (dilute sulfuric acid, nitric acid and large concen-tration hydrochloric acid, phosphorus acid, hydrofluoric acid, formic acid and acetic acid), ammonia, amine and various alkali and salty solutions. Both materials cant resist the corrosion of strong oxidable acid.

在常温下,PVF2对卤素、卤代烃、强氧化剂、沸酸、碱等多种有机溶剂都有良好耐蚀性;UHMWPE对非氧化性酸(稀硫酸、硝酸及浓度较大的盐酸、磷酸、氢氟酸、甲酸、乙酸)、氨和胺及各种碱、盐溶液都有良好的耐蚀性,两种材料都不耐强氧化性酸的腐蚀。

Under normal temp., PVF2 has a fine corrosion resistance to many organic solvents like halogen, halogenated hydrocarbon, strong oxidant, boiling acidalkali; UHMWPE has a fine corrosion resistance to inoxidable acid (dilute sulfuric acid, nitric acidlarge concen-tration hydrochloric acid, phosphorus acid, hydrofluoric acid, formic acidacetic acid), ammonia, aminevarious alkalisalty solutions. Both materials can't resist the corrosion of strong oxidable acid.

在常温下,PVF2对卤素、卤代烃、强氧化剂、沸酸、碱等多种有机溶剂都有良好耐蚀性;UHMWPE对非氧化性酸(稀硫酸、硝酸及浓度较大的盐酸、磷酸、氢氟酸、甲酸、乙酸)、氨和胺及各种碱、盐溶液都有良好的耐蚀性,两种材料都不耐强氧化性酸的腐蚀。

Under normal temp., PVF2 has a fine corrosion resistance to many organic solvents like halogen, halogenated hydrocarbon, strong oxidant, boiling acid and alkali; UHMWPE has a fine corrosion resistance to inoxidable acid dilute sulfuric acid, nitric acid and large concentration hydrochloric acid, phosphorus acid, hydrofluoric acid, and salty solutions.

在常温下,PVF2对卤代烃、强氧化剂、沸酸、碱等多种有机溶剂都有良好耐蚀性;UHMWPE对非氧化性酸

The effects of several important factors, such as nonaqueous solvents, running buffer system and its concentration and pH, separation voltage, temperature and detection wavelength, were investigated to acquire the optimum conditions.

分别考察了非水溶剂、缓冲液体系及其浓度和pH、运行电压、运行温度和检测波长等条件对实验结果的影响。

By use of organic solvents as separation media, nonaqueous capillary electrophoresis, which expands the application of CE, has some merits that can't be found in conventional CE.

非水毛细管电泳由于使用了有机溶剂作为分离介质,具有一些常规毛细管电泳所不具备的优势,拓宽了毛细管电泳的应用范围,在分析水不溶性物质方面具有独到的优势。

In the hydroxylation of phenol with H〓O〓 in the presence of Ti-ZSM-5, water is best solvent. It produces catechol and hydroquinone simultaneously, and catechol/hydroquinone ratio is approximately 0.85. The results show H〓O〓 utilization ratio increase 14%, when nonoxidizable weak acid HAc is added into the reaction system. Under the conditions of Ti-ZSM-5 as catalyst, phenol/H〓O〓 ratio being 10, a little HAc, temperature 75℃, reaction time 6h, H〓O〓 utilization ratio reaches 74. 6mo1% in the reaction.

对Ti-ZSM-5催化苯酚羟基化的研究结果表明,水是最好的溶剂,羟基化有邻、对苯二酚两种产物,并且邻苯二酚/对苯二酚摩尔比可维持在~0.85左右;向反应体系中加入非氧化性弱酸性助剂HAc时,H〓O〓有效利用率较未加入助剂时可提高14mol%;当催化剂用量为8g/100g苯酚、苯酚/H〓O〓比为10、反应温度75℃、添加少量HAc的条件下,反应6h后,H〓O〓有效利用率可达74.6mol%。

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