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After the carboxymethylation,the solubility of pachyman in the water was significantly increased,its β-D-glucan characteristic absorption peak at 890 cm-1 became weak obviously,and its methylene vibration absorption peak and CO antisymmetrical stretch vibration absorption peak appeared at 1 333 and 1 606 cm-1 respectively,which indicated that the carboxymethylation succeeded.The analysis of AFM results showed that CMP molecules existed in different morphology under different solution conditions,and that the concentration,ionic strength and solvent physical chemistry characteristics of polysaccharide solution had effects on the CMP chains conformation and the action mode between different molecular chains.The phenomena were considered to be related to hydrogen bond association and intramolecular and intermolecular electrostatic interactions of CMP.

结果表明:经过羧甲基修饰,茯苓多糖在水中的溶解性显著增加,890 cm-1 处的β-D-葡聚糖特征吸收峰明显减弱,1 333 cm-1 处出现次甲基振动吸收峰,1 606 cm-1 处出现〖JG(〗C〖ZJLX,Y〗O〖JG)〗非对称伸缩振动吸收峰,表明羧甲基化成功;原子力显微镜分析表明:在不同溶液条件下,CMP分子以不同形态存在,多糖溶液的浓度、离子强度及溶剂的物化特性均能对CMP的分子链构象及链间相互作用形式产生影响,推测可能与CMP分子内、分子间的氢键缔合及静电作用有关,CMP分子与云母基底间的吸附及静电作用也会对CMP的分子链构象及图像质量产生影响。

Cellulose acetate butyrate with high or low degree of butyryl substitution was synthesized in heterogeneous system(butyric acid/ acetic acid/ butyric anhydride/ sulfuric acid) using the "free solvent" method. The effect of activation time, esterification time, the molecular weight of cellulose and the content of the organic acid or anhydride on the degree of acetyl and butyryl substitution of cellulose was discussed.

在非均相体系中进行酯化反应,采用&反应性溶剂&,以硫酸作为催化剂合成出从高丁酯含量到低丁酯含量的纤维素醋酸丁酸酯,研究有机酸以及酸酐的添加量、活化时间、酯化反应时间以及原料纤维素的分子量对酯化产物纤维素醋酸丁酸酯的影响。

Effects of vapour of organic solvents on the poly- was studied by the differential scanning calorimetry.

用差示扫描量热研究了几种有机溶剂蒸气对聚对苯二甲酸乙二酯的作用,表明可分为反应性的和非反应性的两种。

In this whole, SPES and free vitriol in mixtures were simultanuously analysed by conductometric nonaqueous titration, by using the distinguishing effect of nonaqueous solvent and its predominate solubilization property for the mixtures.

为此本文提出利用非水溶剂的区分效应和对SPES的良好溶解性能,通过电导滴定分析SPES和自由硫酸的混合产物。

Non-fluoride ionic number of Nd-F in dilute LiF-NdF3 melts and Nd-O-F species in dilute LiF-NdF3-Li2CO3 melts was researched by cryoscopic method,respectively.

采用冰点降低法分别研究了以LiF为溶剂的稀LiF-NdF3熔盐中Nd-F离子团及LiF-NdF3-Li2CO3熔盐中Nd-O-F离子团的非氟离子的个数。

Although the conformation of DNA will be changed in organic solvents,it will not denaturate or dehelix,because the absorption of DNA will not increase greatly with the increasing concentration of ethanol.

为此 ,研究有机溶剂环境中DNA分子的构象变化及其与各种非水溶性药物特别是抗癌药物之间的相互作用

The homogeneous batch distillation and hetegeneous azeotropic batch distillation were studied for separating dimethylbenzene and butylacetate from the industrial waste solvents in this article.

研究了以均相间歇精馏和非均相共沸间歇精馏从工业废溶剂油中分离二甲苯和醋酸丁酯。

Its electroosmotic flow properties are investigated in a variety of nonaqueous media (methanol and mixtures of methanol and acetonitrile).

利用溶胶凝胶技术改进了二氧化锆涂层毛细管的制备方法,并系统的研究了非水体系中(甲醇以及甲醇和乙腈的混合溶剂)二氧化锆涂层毛细管在不同条件下的电渗流行为。

In order to cutting down the cost, flocculation of recombined Erwinia carotovora-Eccl3B cell from broth, influence of temperature, pH and oxidants on the separation of PHB were studied; and the method which measure the molecular weight of PHB by intrinsic viscosity was also studied; furthermore, a phenomenon was found that insolubility of PHB in chloroform can be changed by pretreated at over 120℃ for the fist time, and the mechanism of this phenomenon was explored.

为了降低成本,提高生产效率,本文针对发酵法生产PHB过程中存在的,发酵液难以分离沉淀,非有机溶剂提取PHB时分子量严重降低等问题,进行了发酵液的絮凝,及温度、pH、氧化剂对提取PHB影响的研究。并对粘度法测定PHB分子量的方法进行了研究,同时,对于研究过程中发现的,加热后PHB在三氯甲烷中的溶解性变化及其原因进行了探索。

This article reports a new kind of copolymer, non polar polar terpolymer : poly(styrene-butadiene-methyl methacrylate ) P(S-b-B-b-MMA prepared by anionic polymerization with n BuLi as initiator, 1,1 diphenylethylene as capping agent and lithium 2-(-methoxyethoxy) ethoxide as complex agent.

以正丁基锂为引发剂, 1 ,1-二苯基乙烯为戴帽剂, 2-(2-甲氧基乙氧基)乙氧基锂为络合剂,在环己烷、四氢呋喃混合溶剂中,采用阴离子聚合法,于-70℃~-40℃合成了非极性-极性的三嵌段共聚物聚苯乙烯-聚丁二烯-聚甲基丙烯酸甲酯,并借用GPC、1H-NMR、DSC、TEM、IR等仪器对共聚物进行了表征。

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