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The thermodynamic parameters in the separation of enantiomers of amino acid derivatives and diastereomers of cinchona alkaloids were calculated and the dissociation constants of cinchonine and cinchonidine on the cinchonine imprinted monolithic disk were determined by frontal analysis.

计算了氨基酸衍生物对映体以及辛可纳非对映异构体分离过程的热力学参数并利用前沿色谱法测定了辛可宁和辛可尼丁在盘状分子印迹整体柱上的离解平衡常数。

Diastereomers of cinchonine and cinchonidine were separated in pressure-assisted capillary electrochromatography mode, and the resulted separation efficiency was much higher than that obtained in high performance liquid chromatography.

采用压力辅助电色谱模式拆分了非对映异构体辛可宁和辛可尼丁,其柱效远高于其在HPLC中拆分的结果。

Several non-isolated-pentagon structures of low symmetries are found to have low energies close to the most stable isomer.

并且一些较低对称性的非IPR异构体也拥有与最低能量接近的较低能量。

The technique has isomerization of 1,2,4-trimethylbenzen and precise distillation as a union, which is unique and feasible.

该工艺采用偏三甲苯非临氢催化异构化技术与精密精馏的分离手段有机结合的方法,工艺独特可行。

Firstly, we discuss the technology corresponding on XML, the basic theory of structured and unstructured isomerous data resource and the concept of Service-Oriented Architecture and Enterprise Service Bus in this paper.

论文首先对XML相关技术、结构化和非结构化的异构数据源理论以及面向服务的体系架构与企业服务总线等相关理论基础进行了论述。

A new technology for synthesis of mesitylene from pseudocumene by liquid non-hydroisomerization on M-2 catalyst was studied.

在M-2型复合丝光沸石催化剂上,研究了偏三甲苯液相非临氢异构化合成均三甲苯的工艺。

Separation of organic-organic mixtures by pervaporation is discussed with emphasis on the following aspects: pola...

其中,又重点报道了有机混合液分离的最新研究成果,将其分为:极性/非极性化合物、芳香烃/脂肪烃体系、芳香烃/脂环烃体系、同分异构体、多元体系和汽油脱硫等六部分进行了详细叙述。

The difference in solvent polarity environment between excited state intramolecular charge transfer and proton transfer states leads to a remarkable ESICT/ ESIPT coupled reaction. In polar, aprotic solvents, in contrast to a unique PT tautomer emission observed in 3-hydroxyflavone (3HF), dual emissions are resolved, consisting of ESICT and ESIPT bands.

不同於化合物3-hydroxyflavone只观察到异构物的质子转移萤光放射峰的结果,在极性、非质子酸溶剂里,我们会观察到3-hydroxyflavone衍合物有两个萤光放射峰,是分别经由ESICT与ESIPT两种不同路径个别的贡献。

This Sm-catalyzed reaction firstly efficiently realized the catalytic cycle in the tandem rearrangement/reduction reaction of α-hydroxy epoxides, and moreover the diastereoselective amplification could be distinctly observed when two C1 epimers in substrate were subjected to this catalytic tandem reaction.

该催化的多功能串联反应,高度非对映选择性地一步控制了含有季碳的三个相邻立体中心,有效地构建了&2-季碳1,3-二醇&结构单元,首次实现了此类重排—还原过程的催化循环,其中对于两个C1位的差向异构体底物,此反应具有明显的非对映选择性放大特点。

Synthesis of such compounds from nonchiral materials results in equal numbers of the enantiomers, racemates.

使用非手性物料合成此类化合物导致等量的对映异构体和外消旋物。

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This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。

There is no differences of cell proliferation vitality between labeled and unlabeled NSCs.

双标记神经干细胞的增殖、分化活力与未标记神经干细胞相比无改变。