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In Ni-Al alloys the first peak position of Ni-Al pair correlation function is smaller than the sum of Ni and Al atomic radii, meaning a strong interaction between Ni and Al atoms and a chemical bonding with weak covalence.

计算表明,Ni-Al非晶态合金可以用猝冷法制备,它们的结构与液态Ni-Al合金类似但与液态合金相比更加有序且有部分晶化趋向。

This invention discloses a preparation method for anti-corrosion rare earth magnet material characterizing that it takes the optimized grain-boundary phase design as the starting point on the basis of a dual alloy method to select Nd base alloy with high crystal forming ability as the assist alloy and reduces the temperature of the press mold blank in a quartz container to room temperature from over grain-boundary phase melting point with the water extraction way to get enough cooling rate and guarantee the non-grain-boundary phase, compared with the material of the same composition prepared by ordinary method, the weightlessness of this invented material reduces over 30% after testing the weightlessness of the material by laying it for 96 hours under 121deg.C, 2 atmosphere and 100% humid environment to show the advanced performance of anti-corrosion.

本发明公开了一种耐腐蚀稀土永磁材料的制备方法,其特征是它在双合金法制备工艺的基础上,以优化晶界相设计为出发点,选取具有较高非晶形成能力的Nd基合金为辅合金,并在烧结回火时将置于耐高温石英容器中的压型坯件,从晶界相熔点以上以水淬冷却的方式降温至室温,以达到足够的冷却速率,确保得到非晶晶界相,根据本发明制得的耐腐蚀稀土永磁材料,通过测量在121℃、2个大气压以及100%湿度环境下放置96小时后材料的失重情况,结果显示本发明得到的材料与常规方法制备的相同成分的稀土永磁材料相比失重减少了30%以上,充分证明其具备了更优越的耐腐蚀性能。可广泛应用于电子、汽车、计算机、电力、机械、能源、环保、国防、医疗器械等领域。

Connecting with the new properties of NiP amorphous alloys which are prepared by method using nickel hypophosphite as reac-tant,applications of el ectroless nickel in high technological field are described in brief.

本文阐述了化学镀镍在国内外的应用及前景;结合以次磷酸镍为原料的新方法制备的高质量NiP非晶态合金的新性能,介绍了化学镀镍在高科技领域中的应用。

Some amorphous binary alloy films have been successfully grown by ion beam assisted deposition .

本文阐述了用离子束辅助沉积技术制备非晶合金薄膜的基本思路,介绍了本研究组在二元合金系统里制备非晶和亚稳晶相的研究结果。

In order to reach the purpose of using pre-laser cladding method preparation of Ni-based amorphous alloy coatings on 45 steel substrate surface by the method was carried out. The principles of the three clusters and the amorphous line of the law of composition rules were used. The Ni59.35Nb34.45Sn6.2 alloying powder which has a great glass-forming ability in conventional preparation methods of amorphous alloys was chosen. In the protection of atmosphere, the amorphous surface coating was prepared. The microstructure, micro-hardness and performance of the different output power of the laser cladding were analyzed.

中文摘要:为了达到研究预置激光熔覆可以在45钢上制备Ni基非晶合金涂层的目的,采用非晶形成能力三判据原则及非晶成分团簇线定律法则,选择了采用常规非晶合金制备方法中具有极大玻璃形成能力的Ni59.35Nb34.45Sn6.2合金粉末,在保护气氛下,制备非晶涂层,并对不同输出功率下得到的涂层进行微观组织和结构表征及性能测试。

By adding minor amount of cheap element Fe into metallic glass based on Zr65Cu17.5Al7.5Ni10 composite, bulk metallic glass in diameter of 3 mm was successfully synthesized by copper mold suction casting method at different voltages.

对以Zr65Cu17.5Al7.5Ni10为基体的非晶合金中添加微量廉价的Fe元素,采用铜模吸铸法在不同电压下制备出直径3 mm大块非晶合金。

Through designing of composition and structure of the bioactive graded coating,innerstress and its distribution in the coating were analyzed and calculated, the resultsshowed that when composition distribution coefficient n was 1.5, a reasonable stressdistribution could be got, that was at the beginning of deposition the suspension containingrichly BG granules was used so that a rich BG granules layer, a good transitional layerbetween BG layer at the bottom and the coating could be obtained at the titanium alloy side,the bottom of the coating; the stress value near the interface and surface and its character,pressure stress or tensile stress, were decided by the character of its composition itself.Changing composition distribution coefficient n could only change the variation tendency ofstress in the coating, but did not change the stress distribution rule in the coating. Thethinner the coating is, the sharper stress variation in the coating is, which does not mean thatthicker coating is better because the thicker the coating is, the little the permitteddeformation of coating is, so the coating thickness should be thinner, for example, about50μm for bending applications, but for applications only bearing pure shear stress, such asroot of tooth implant, the coating can be thicker little, for instance, about 80~100μm. The study on electrification characteristic and electrophoresis deposition of HAand BG granules in aqueous and non-aqueous solution system found that EPD almost didn'toccur in aqueous solution system. However, because HA granules take position charges inabsolute alcohol, a homogeneous EPD be carried out on the cathode titanium alloy slice, but taking negative charge in absolute alcohol the BG granules not be deposited on the cathode. A guided HA crystallizing, 100~300nm, on surface of the BG granules be realized by metathetical reaction, which cover BG granules with HA microcrystals and make the covered BG granules taking position charges in absolute alcohol, sequentially realize the EPCD of the BG and HA granules on the cathode, so it is feasible to make a titanium alloy/BG/HA bioactive graded coating by making use of EPCD technology. The corrosion experiment of rich boron bioglass coating and plasma spray coating showed that split phase, rich boron and rich silicon phase, occurred during its preparation. In basic medium the corrosion behavior of 〓 BG coating showed uniformity corrosion, the corrosion mostly occurred at rich boron phase area, therefore batch formula design of BGshould avoid the occurring of split phase. The corrosion appearance of plasma spray coatingappeared a non-uniform corrosion, mostly occurred at the edge of the laminated HA moltendrops, and emerged an accelerated corrosion tendency, which will easyly lead to corrosioncrackles extending to the interface and the happening of osmotic interfacial corrosion, thatmay be one of the major reasons leading to the coating cracking-off in the later period. Thetesting results of thermal expansion coefficient of 〓 and 〓BG showed the thermalexpansion coefficient of 〓 BG matched with that of titanium alloy better, and 〓 BG couldsinter with titanium alloy into densification enamel layer at low temperature (720℃).

将Ti6Al4V合金在1000℃下进行真空热处理会降低其力学性能,且合金内的V元素会向表面富集,因此,钛合金真空热处理和表面涂层的烧结温度不能过高,即应低于其相转变点;通过对生物活性梯度涂层的组成和结构的设计,分析和计算了梯度涂层内的应力大小和分布,结果表明:对于本研究,当成分分布系数n=1.5时,可以获得较合理的涂层力学性能,即在沉积开始时,采用富含BG颗粒的悬浮液,以便在钛合金侧获得同底层BG有良好过渡的富BG涂层;梯度涂层界面和表面的应力大小、性质由材料组成本身的性质决定,改变成分分布系数,只能改变涂层内应力变化的趋势;涂层的厚薄不影响涂层内的应力分布规律,但涂层越薄,涂层内的应力变化越快,但这并不意味着涂层越厚越好,因为涂层越厚,涂层允许的变形越小,对于应用于弯曲受力部位的涂层而言,涂层应薄一点为好(50μm);而对于仅纯受剪切应力的部位,如牙根种植体,涂层可适当加厚(80~100μm);通过对HA和BG颗粒在水溶液体系和非水溶液体系中的带电特性和电泳沉积的研究发现,它们在水溶液体系中很难发生电沉积;在无水乙醇溶液中,HA颗粒带正电,可在阴极钛合金片上发生均匀的电泳沉积,而BG颗粒则带负电荷;利用复分解反应法,可以制得100~300nm的HA,通过诱导HA在BG颗粒表面结晶,可对BG颗粒进行表面包覆,获得了被HA包覆的BG颗粒,改变了BG颗粒表面的带电特性,使BG和HA颗粒在无水乙醇中均带上正电荷,从而实现了HA和BG颗粒在阴极上的共沉积。

The unsmoothed characteristics of some living beings in soil have wear reduction and wear resistance function . The research benefits the revelation that a tungsten carbide reinforced Cu-base alloy wear-resistant composite coating was produced on mild steel by spark plasma sintering.Under the condition of two bodies abrasive wear ,the coating with the structure that hight hardness and good wear resistance WC particles embedding in tough fine Cu-base alloy matrix resist the abrasion wear and manifest the good wear reduction and wear resistance properties that the unsmoothed bodysurface of some living beings in soil have.

本研究受到某些土壤动物体表非光滑几何特征具有减磨、耐磨特性的启示,应用放电等离子烧结工艺,选取具有优良塑性的Cu基合金作为复合层基体,硬质点WC颗粒作为增强相,在碳钢表面形成WC\ Cu基合金耐磨复合层,在两体静载荷磨粒磨损条件下,高硬度、耐磨WC颗粒镶嵌在高塑性的Cu基合金基体中,共同抵抗磨粒的磨削,表现出某些土壤动物体表非光滑几何特征所具备的优良减磨、耐磨特性。

It is found that the structure of the ternary electroless Ni-W-P coating is greatly influenced by W content in the deposit. It is also found that the requisite content of phosphorus for amorphous Ni-W-P structure is less than that of Ni-P binary alloy coating, and the more tungsten exists, the less phosphorus is required. The hardness of the deposits will be enhanced as the deposit structures are changed from amorphous to mix-or nanocrystalline structures. The corrosion resistance of Ni-W-P ternary alloy is improved as W content increased, and the passivation of amorphous deposits is formed more easily than that of mix-structure and nanocrystalline deposits.

研究发现,化学镀Ni-W-P三元合金镀层的结构受镀层中钨含量的影响较大,非晶态Ni-W-P三元合金镀层所需磷含量较非晶态Ni-P二元镀层所需磷含量要低,并且钨含量越高,所需磷含量越少;镀层硬度随镀层结构从非晶态→混晶态→纳米晶态转变而增加;镀层的耐蚀性随镀层中钨含量增加而变好,且非晶态镀层较混晶态和纳米晶态镀层更易形成钝化区。

NF 99 contains chlorinated additives, fatty oil and sp ecial lubricity fortifiers to impart quick release of chip from tool even under extreme high cutting pressure.

NF 99 是一款专为非铁金属而配制的切削油,适用於铜金属、铝金属及其合金的重负荷切削,含有氯化物、脂肪及特殊润滑添加剂,增进其极压及润滑性能,就算在高切削压力下,也能使屑片容易与刀具分离,低的黏度确保了足够的冷却及冲屑性能,都是高速切削所必需。当使用在钢铁金属,此高性能油品同样能达到良好的效果。

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