非合金的

Based on the non-isothermal transformation theory and non-steady state nucleation theory, a new method for calculating the continuous cooling transformation curve and the critical cooling rate of bulk metallic glass alloys is put forward in this paper.

在非等温转变理论以及非稳态形核理论基础上提出了计算大块非晶合金连续冷却转变曲线和临界冷却速率的新模型，以用于评估合金的非晶形成能力。

The Fe57-xCo18Nb4Al2Si4B15Smx(x=0-3) amorphous alloy ribbons were prepared byvacuum arc melting and melt spinning. The influences of Sm addition on the glass forming ability, thermal stability, crystallization behavior and magnetic properties of Fe57-xCo18Nb4Al2Si4B15Smx amorphous alloys were studied by X-ray diffraction, differential thermal analyzer and vibration sample magnetometer survey.

摘 要：采用真空电弧熔炼和真空熔融甩带法制备Fe57-xCo18Nb4Al2Si4B15Smx(x=0~3)非晶合金，借助X射线衍射、差热分析以及振动样品磁强计等手段研究稀土元素Sm对制备合金的非晶形成能力、非晶热稳定性、非晶晶化行为以及磁性能的影响。

The structure and thermodynamics of liquid Au and AuCu alloys have been simulated using molecular dynamics method based upon the EAM interatomic potential to reveal the influence of the mismatch in atomic size on the glass forming ability.

近年来，非晶合金由于有较好的延展性和抗腐蚀性，得到了广泛的应用犤1犦。Duwez犤2犦首次制成金属非晶，Inoue犤3-4犦将非晶的获得归纳为三条基本规律，这为选择合金元素提供了有益的指导。

Consequently, the improvement of cycle life is described as the partial substitution of Zr for Mg in the alloy.

XRD结构分析表明：主相仍为Mg↓2Ni； Zr替代Mg使合金的微晶结构发生了改变，趋于非晶化；添加Zr的合金的容量比由扩散法合成的合金的容量有所提高；合金中添加Zr，提高了电极的放电容量，增大了放电平台；特别是Zr 对六方晶系Mg2Ni合金结构中Mg的部分取代大幅度提高了电极的循环寿命，未经任何处理的 Mg1.4Zr0.6Ni合金电极经25个循环后，放电容量仅衰减4.11%，表明添加Zr对提高合金的循环寿命具有重要的作用。

ABSTRACT Amorphization of Cu-Zr system by mechanical alloying of elemental Cu and Zr powder mixtures (30-65at% Cu) and mechanical grinding of the alloys with Cu concentration ranging from 59 to 75at% have been extensively investigated. The structural changes, crystallization behavior as well as atomic short range ordering were followed by differential scanning calorimetry , X-ray diffractometry and nuclear magnetic resonance spectroscopy .

本文采用多种技术系统地研究了球磨Cu和Zr混合粉末制备的Cu〓Zr〓（x=30，33，40，50，55，59，65）非晶合金的形成过程和球磨金属间化合物得到的Cu〓Zr〓（x=59，65，70，75）非晶合金的形成过程，比较了它们形成过程的异同，同时研究了球磨形成的非晶合金的晶化行为以及原子短程有序结构，并与急冷非晶合金作了详细的比较。

The DTA result shows that the Ni-Ce-B nano-amorphous alloy has four exothermal peaks located at 275, 330, 423 and 528℃, and the Ni-Ce-P nanoamorphous alloy has three exothermal peaks (278, 410 and 528℃). The temperature of the highest exothermal peak increases by 150 and 170℃ respectively, compared with Ni-B and Ni-P nano-amorphous alloys.

DTA结果表明，Ni-Ce-B纳米非晶态合金有275、330、423和528℃四个晶化峰，Ni-Ce-P纳米非晶态合金有3个晶化峰（其晶化峰分别在278、410和528℃），其最高晶化峰温度较相应Ni-B和Ni-P纳米非晶态合金的分别升高150℃，170℃。

The catalytic performance of all the amorphous alloy catalysts mentioned above was measured during liquid phase hydrogenation of furfural to furfuryl alcohol, together with the kinetic studies. The relationship between the catalyst performance and the structure of catalyst, surface electronic state of the amorphous alloy has been systematically studied based on a series of characterization of catalysts . Meanwhile, the promoting effects of the support on the thermal stability and catalytic activity of the amorphous alloy catalysts have been discussed.

本文采用一系列的表征方法(XRD、XPS、TEM、BET、氢吸附、TPD等)进一步研究非晶态合金催化剂的表面结构、表面电子态和催化性能之间的关系，探索电子效应和几何效应对催化剂活性中心结构的影响，探索非晶态合金的晶化失活和载体对非晶态结构的稳定化作用，以及修饰剂对催化性能的改善作用等。

In this paper,the forming mechanism and affecting favtor of bulk metallic glasses is systematically discussed from the aspects of thermodynamic, kinetic and microstructure . Thermodynamic factors which favor the amorphization of alloys analyzed, the glass forming range of ternary alloys system was proposed by using Miedema theory, Toop model and considering the influence of free energy of pure metals at different temperature. The approach was applied to predict the composition range of amorphous Mg-Cu-La alloys. Several methods(such as three empirical criterions ,binary alloys phase diagram , Miedema theory and Toop mode) were used to design a series of Mg65Cu25La10 、Mg68Cu17La15 and Mg57Cu23La20 alloys, These bulk amorphous alloys with maximum diameter thickness reaching to 1mm were prepared by means of graphite-molding casting though the raw materials are of a low purity by conventional casting processes at a low cooling rate.

本文从合金的热力学、动力学及结构形成条件方面系统的讨论了Mg 基大块非晶的形成机制及影响因素，并从非晶形成的热力学观点出发，综合应用Miedema理论和Toop 模型，并考虑纯金属在不同温度下的自由能，在此基础上提出了一种定量预测三元非晶合金形成范围的方法，用该方法计算Mg-Cu-La 三元合金系的非晶形成范围，应用多项技术(三经验原则、二元合金相图及Miedema 理论和Toop模型)设计了Mg65Cu25La10 、Mg68Cu17La15 和Mg57Cu23La20非晶合金。

The results show that the alloy undergoes obvious plastic elongation, the specimen fractures into four sections and the diameter changes from 16 mm to 12 mm. The fracture surfaces distribute randomly well developed and partially developed veinal patterns. The deformation behavior of alloy is non-Newtonian flow behavior. About 3% amorphous matrix of extruded specimen transforms crystal, the crystal particles with size of 10-20 mm are precipitated in the amorphous matrix, the thermostability of the extruded specimen was lowered. The failure of the alloy is mainly attributed to non-uniform viscous flow under high strain rate resulting from the hydrostatic extrusion process.

结果表明：非晶合金在高应变速率下产生了明显的塑性变形，直径从16 mm变为12 mm，断裂为4段，且样品断口上随机分布着充分发展与未充分发展的脉纹式切变带，由此可看出非晶合金的变形为非牛顿体变形行为；挤压后的样品约有3％的非晶相发生晶化，在非晶基体上析出10～20 nm的纳米晶粒，导致挤压后非晶合金的热稳定性降低；静液挤压高应变速率变形条件使非晶合金产生非均匀流变，是造成非晶合金断裂的主要原因。

In the investigation, non-equilibrium Al-based materials were prepared using rapid solidification techniques, including melt spinning and close-coupled inert gas atomization.

从原子拓扑结构角度对Al基合金所特有的极弱非晶形成能力进行了解释，并提出通过小原子的微合金化改善Al基合金的非晶形成能力的思路。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。