降解产物

The discussion of the degradation mechanism: Chitosan is not hydrolyze in neutral soak in vitro. The mechanism of degradation of the PDLLA membrane in vivo and in vitro is similar, both represent the simple hydrolyze. The degradation of he composite membrane mainly represent the PDLLA hydrolyze of, chitosan can hydrolyze when there are acid product which is PDLLA's catabolite in vitro.

降解机理探讨：壳聚糖膜体外中性条件下不水解；聚乳酸膜体内外降解机理相似，都表现为简单水解机理；复合膜体外降解主要表现为聚乳酸的水解，壳聚糖在聚乳酸降解后产生酸性产物的条件下存在酸水解机理。

The gasification efficiency increased and the molar fraction of H2 decreased with an increase in the reaction temperature. The decomposition of PVA was more complete at higher temperatures. At 24 MPa, 500℃ and 120 s, the TOC remove rate, the carbon gasification rate and the hydrogen gasification rate were up to 71.46%, 67.97% and 157.24% respectively. A change in the residence time had no significant effect on the molar fraction of gas production but an increase in the residence time could enhance the gasification efficiency of PVA. It was found that the intermediates were mainly alkane, cycloparaffin, aromatic hydrocarbons, and low-molecular weight acids. It was supposed that PVA was degraded into small molecules through breaking of C-C bonds. Parts of the molecules were converted into H2, CO, CH4 and CO2 while some was converted into aromatic hydrocarbons.

过程探索发现：反应温度的升高能提高PVA气化效率，但气体产物中H2的含量随反应温度的升高有所下降；随着反应温度的升高，PVA分解趋于彻底，在压力24MPa、温度500℃、停留时间120s的条件下，TOC去除率、有机碳气化率和氢气化率分别达到71.46%，67.97%和157.24%；停留时间的变化对气体产物含量没有明显的影响，但延长停留时间能提高PVA的气化效率；PVA气化反应中间产物主要为链状烷烃、环烷烃、芳香烃及小分子酸，根据中间产物出现的顺序推测PVA的降解为由C-C键断裂形成小分子物质，这些小分子物质一部分转化为H2，CO，CH4和CO2，一部分形成难降解的芳香族化合物。

Therefore, it is necessary to determine the intermediates and mineralization products and obtain photocatalytic degradation mechanism finally.

因此，有必要研究光催化降解反应的矿化产物、中间产物进而得到其光催化降解机理。

There are different methyl branch structures correlated with isomerous nonyl of NP in the alkyls. The primary metabolites from the dominant bacteria experiment have alkyl phenols and benzene acetic.

研究结果表明，活性污泥降解壬基酚的初级代谢产物主要为C4～C6烷基取代苯酚，烷基链的结构差异与其母体壬基的异构方式有关，烷基上的支链主要为甲基；优势降解菌群代谢壬基酚的初级产物除烷基苯酚外，还有苯乙酸等。

Thus, the photosensitizers are expected to degrade more rapidly in the environment.5. Na2Fl shows no obvious algaecidal activity with or without illumination, however, the other five xanthene derivatives shows approximately similar inherent toxicity and phototoxicity.

实验证实，呫吨类化合物在自然条件下能在发挥光敏生物活性的同时迅速降解为小分子化合物，残留量少，同时，其降解中间产物和终产物的光敏生物活性也迅速降低，对环境的潜在风险很小。5。

The possible pathway of ABAS degraded by Zoogloea HP3 was that ABAS was first cleaved to produce o-phthalic acid and products. The former was further degraded and the composites of the latter were 2-amino-3-hydroxyl-5bromobenzenic sulfonic sodium and 2, 3-dihydroxyl-5-bromobenzenic sulfonic sodium.

动胶菌HP3作用下溴胺酸可能的降解途径为蒽醌环开裂生成中间产物邻苯二甲酸，邻苯二甲酸被进一步降解；溴胺酸降解后的最终产物为2-氨基-3-羟基-5-溴苯磺酸钠和2，3-二羟基-5-溴苯磺酸钠。

The results of batch experiments showed that the anaerobic biodegradation kinetics of 2-CNB and 4-CNB by granular sludge were follwed by first-order reaction. The nitro groups of 2-CNB and 4-CNB were more easily attacked by electron than chlorines and they were reductively biotransformed to amino groups under anaerobic conditions. The acclimated anaerobic granular sludge, which could dechlorinate 4-chloroanline to aniline, showed that it had the ability of para-dechlorinating. The anaerobic biodegradating on pathway of 2-CNB and 4-CNB were suggested as follows:AbstractIn ZVI(zero-valent iron, Fe0)-reduction system, the nitro groups of 2-CNB and 4-CNB were reductively transformed to amino groups.

2分批试验结果证明，颗粒污泥降解2-CNB和4-CNB遵循一级动力学，在厌氧条件下，CNB发生序列的硝基还原与脱氯作用，苯环上的硝基比氯原子更容易受到亲电子攻击，发生还原反应生成氨基；所获得的颗粒污泥具有对位脱氯活性，可使4-CA进一步脱氯形成苯胺。2-CNB和4-CNB厌氧降解的建议性途径为： ZVI(Zero-valentiron)对2-CNB和4-CNB的作用主要是将苯环上的硝基还原为氨基；在ZVI与污泥共还原转化体系中，ZVI对氯代硝基苯的硝基转化具有一定的促进作用，但因ZVI对中间产物的吸附特性，终产物形成速率趋慢。

The experimental results indicates that the optimum pH range was 1.60~2.20, and the optimum H2O2 concentration was 10.0 mmol/L. The degradation ratio increased with the increasing concentration of ammonium ferric oxalate in the range from 0.1 to 1.0 mmol/L, but no significant increase in degradation ratio was observed when the concentration was above 1.0 mmol/L. When the concentration of fuchsin basic increased, the degradation ratio dropped, while the concentration of degraded fuchsin basic rised. When the concentration of fuchsin basic was low, the degradation followed first-order kinetics, but when it was high, the degradation could be fitted by zero-order kinetics. The absorbtion of fuchsin basic at 543 nm disappeared quickly, while the absorbtion of intermediates formed during the course of fuchsin basic dagradation at 298 nm vanished slowly.

试验结果表明：碱性品红降解的最佳初始pH为1.60~2.20，最佳初始H2O2浓度为10.0mmol/L；草酸高铁铵的浓度在0.1~1.0mmol/L时，碱性品红的降解率随浓度的增大而增大；高于1.0mmol/L时，则降解率相差不大；碱性品红的初始浓度增大，降解率减小，而实际降解的浓度则增加；碱性品红的浓度在低和高时，降解动力学过程不一致；随降解的进行，碱性品红在可见光区的吸收峰迅速消失，而降解过程中形成的中间产物吸收峰却消失很慢。

Four main radiolysis products of chlorpyrifos and two main radiolysis products of cypermethrin were determined by using gas chromatography tandem mass spectrometry analysis method.

4 kGy剂量辐射，毒死蜱的降解率在98%；12 kGy剂量辐射，氯氰菊酯的降解率在84%；通过GC/Ms分析得出4种毒死蜱主要辐解产物和2种氯氰菊酯主要辐解产物。

The following main results are obtained: The TiO_2 photocatalyst with small crystallite size, high surface area, narrow and uniform pore size distribution, and microporous frameworks could be prepared out by applying MW radiation in the preparation process. The microwave-induced fluorescence technique verified for the first time that microwave enhanced the formation rate of hydroxyl radical, leading to the increase in the photocatalytic efficiency. Compared with the conventional catalyst, TiO_2 prepared by MW dielectric heating owns a higher UV absorption ability, and its optical absorption edge and photovoltaic response are shifted toward the short wavelength region, resulting in increase of photooxidation efficiency. The photocatalytic conversion and the mineralization ratio of acetaldehyde are increased respectively by 30% and 40% over the TiO2 prepared by MW radiation when compared to the TiO2 prepared by the conventional heating. For the MW-assisted photocatalytic reaction over the MW-prepared TiO2, production of hydroxyl radicals is enhanced by 22.5%, and the photocatalytic conversion is accordingly increased by 20%. Similarlly, applying MW also increased the photocatalytic conversion and the mineralization ratio of acetaldehyde over TiO2/Al2O3 sample.

论文得到如下主要结果和结论：(1)微波介电加热TiO_2 溶胶可得到晶粒度小、光催化活性高、比表面积大和孔径分布窄而均一，且微孔发达的TiO_2光催化剂；在溶胶干燥处理过程中微波可使催化剂表面缺陷增加，进而导致光催化反应过程有更多的活性羟基自由基产生；(2)微波制备能显著增强TiO_2 样品的紫外光吸收率，并使其光吸收和光伏响应阈值发生蓝移，从而提高TiO_2的氧化还原能力；(3)与常规加热法所制TiO_2比较，微波法制备的TiO_2对乙醛的光催化降解转化率提高30%，CO_2生成率提高40%以上；(4)与未加微波辐射时相比，发现在光催化反应过程中施加微波，TiO_2 的羟基自由基生成速率提高了22.5%，相应CH_3CHO 光催化降解转化率提高了20%；对Al_2O_3/TiO_2催化剂，CH_3CHO 光催化降解转化率甚至提高了33%，同时CO_2 的生成率也都大幅度提高；(5)微波辐射可改变光催化降解乙醛的产物分布，推断施加微波时乙醛光催化降解按照羟基自由基引发的链式反应机理进行，微波&非热效应&起主要作用。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新