阻化剂

The research indicated that under the compound use of hydroquinone and methyl quinone or independent use of phenothiazines or nitrogen oxygen free radical made the polymerization retarder, opposite-methyl-phenylsulfon made the esterification catalyst, toluol made the backflow including water condition, the acid mellowly compared to when it was 1.15, the production rate of the synthesis methylacrylic acid polyethylene glycol single methyl ether (400) ester may achieve 98.9%, was extremely similar to the overseas product functional group structure.

研究表明，在氢醌、甲醌复合使用或者单独使用吩噻嗪、氮氧自由基哌啶酮作阻聚剂，对甲苯磺酸作酯化催化剂、甲苯作回流带水的条件下、酸醇比为1.5时，合成的甲基丙烯酸聚乙二醇单甲醚(400)酯产率可以达到98.9%，与国外产品官能团结构十分相似。

The results indicated that at the inhibitor dosage of 0.4%, mole ratio of methacrylic acid to MPEG of 1.5:1 and reaction temperature of 120 ℃, the yield of MPEGMA could reach 92.3%.

结果表明：阻聚剂质量分数为0.4%、酸醇摩尔比为1.5：1、反应温度为120℃时，酯化率可达到92.3%。

However, the esterification rate and yield reach 94 % and 89 % with the oil of vitriol as catalyst, and the best reaction conditions are that the weight ratio of catalyst and inhibitor are 2.5 % and 0.6 %, the volume of toluene is 60 mL, the molar ratio of MAA and TEG is 2.2:1 and reaction time is 3 h, and the content of TEGDMA is 88 % analyzed by GC.

以浓硫酸为催化剂，当阻聚剂的用量分别为原料的2.5 %和0.6 %，甲苯用量为60 mL，n：n=2.2∶1和反应时间为3 h时，酯化率和产率分别为94 %和89 %，气相分析TEGDMA的质量百分数为88 %。

A new technique for selective plugging and acidizing oil wells is presented based on the principle of temporary plugging and acidizing in which selective plugging agent is first injected to block high permeable zones, then acid is injected to acidize low perlmeable and contaminated ones.

针对暂堵酸化技术存在的问题，提出了一种油井选堵酸化的新技术，即在注酸前注入选堵剂封堵高渗透水层，然后注入酸液以酸化低渗透层和污阻部位。研制了符合最终堵水不堵油要求的选堵剂，描述了这一新技术的机理。通过模拟试验，考察了新型选堵剂的选堵效果、封堵强度及酸化转向率等。

The experiment confirmed the kind of catalyst and the best technical condition.The result shows,731 strong acidity ion exchange resin is the best catalyze and high selection,it can be used serval times,esterify rate in 80.2%.

考察了催化剂种类、用量、原料配比、反应时间、阻聚剂用量以及催化剂使用次数等因素对酯化率的影响，确定了催化剂种类和最佳工艺条件。

Three novel hemicyanine derivatives,-N-(4-sulfopropyl)-4-[2-(4- N, N-diethylaminophenyl)-ethenyl]pyridinium,-N-(4-suMbbutyl)- 4-[2-(4-N, N-diethylaminophenyl)ethenyl]pyridinium (EPS4), and-N-(4- su)fobutyl-4-[2-(4-N, N-diethylaminophenyl)ethenyl]quinolinium (EQS4) with different length of alkyl chains between the adsorbing group (RSO3-) and the chromophore group, were synthesized and their photophysical and photoelectrochemical properties were studied.

设计合成了具有不同空间位阻的吡啶盐类和喹啉盐类半菁染料-N-(4—磺酸根丙基)-4-[2-4（4-N，N-二乙基氨基苯基）乙烯基]吡啶鎓盐，-N-4-磺酸根丁基）-4-[2-(4-N，N-二乙氨基苯基）乙烯基]吡啶鎓盐（EPS4）和-N-（4-磺酸根丁基）-4-2-（4-N，N-二乙基氨基苯基）喹啉鎓盐（EQS4），研究了它们的光物理性质，并将它们用作TiO2纳米晶电极的光敏化剂引入光电化学电池中。

Work 工作:(1) feasible process development for high-pure tetraalkyphosphonium salt as catalysts for polymerizations, potential sale 2-4 million us$;(2) simple and feasible preparation process for phosphonium salt as ionic liquids, biocides and phase transfer catalysts;(3) new and industrially feasible processes for highly sterically hindered alkylphosphines as catalyst ligands, these include tricyclohexyl-phosphine, phosphorinanes and dsmphos2,3- bis(9-phosphabicyclononylbutane;(4) sterically hindered dialkylphosphinic acid as new generation of co/ni extractant;(5) alkylphosphonium wittig reagents and the wittig reactions with them;(6) exploration of the application of borane chemistry in the synthesis of highly sterocally hindered organophosphines;(7) customer preparation of samples of a variety of organophosphorus compounds for customers all over the world.

用作高分子聚合反应催化剂的高纯度四烷基瞵盐的实用生产流程。产品销售前景 2-4 百万美元；(2)用作离子化液体，杀菌剂和相转移催化剂的烷基瞵盐的简单实用合成方法；(3)高位阻烷基磷化氢催化剂配体的工业实用合成路线的研究，这包括，三环己烷基磷， phosphorinanes 和 dsmphos 2，3-bis(9-phosphabicyclononylbutane ；(4)高位阻二烷基膦酸金属萃取剂的工业实用合成路线的研究；(5)烷基膦 wittig 反应试剂的研究；(6)硼化学在高位阻烷基磷化氢合成中的应用；(7)为世界各地提供顾客合成服务。

The influence of acrylic acid and tetradecyl alcohol, amount of catalyst and inhibitor, reaction temperature, reaction time were investigated.

探讨了丙烯酸与十四醇摩尔比，催化剂和阻聚剂的用量、反应温度及反应时间对酯化反应的影响。

A photosensitive resin for UV curing acrylic powder coating has been synthesized by esterification of methacrylic acid and GMA-type acrylic resin at the presence of ethyl acetate as solvent, tetramethylammonium chloride as catalyst, YK as inhibitor.

以醋酸丁酯为溶剂，四甲基氯化铵为催化剂，氮氧自由基为阻聚剂，由甲基丙烯酸缩水甘油酯类丙烯酸树脂与甲基丙烯酸酯化反应制得了UV固化粉末涂料用感光性丙烯酸树脂。

The volatile corrosion inhibitor Add the atmospheric steam (waste of paper with the parcel, blowing air through the suppression chamber products, etc.).

将易挥发的腐蚀抑制剂放入蒸汽的大气中（用阻化纸包裹，吹动抑制空气通过制品腔室等等）。

Plunder melds and run with this jewel!

掠夺melds和运行与此宝石！

My dream is to be a crazy growing tree and extend at the edge between the city and the forest.

此刻，也许正是在通往天国的路上，我体验着这白色的晕旋。