阴离子的

The results of the present research are as follows, The correlation between physico-chemical properties of organic compounds and their competitive power was studied, and it was indicated that organic compounds preferable to form H-bonding with organic matter of sorbents have stronger competitive power; Sorption behaviors of ionizable organic compounds in different species and their competitive power were examined, and the results showed that phenols and carbonxylic acids with benzyl circle have much stronger competitive power in molecular species than in ionized species, because negative charges of anionic forms can depressed their adsorption on the surface of the sediment; in contrast, organic bases such as aniline and p-chloroaniline show weaker competitive power in molecular species than in ionized species, and this is because both species of the organic bases could adsorb strongly onto the sediment; there is a correlation between competitive power of organic pollutants in multi-solute systems and their sorption isotherm nonlinearity in single-solute systems, and organic compounds whose sorption isotherms is linear in single-solute systems hardly have competitive power in multi-solute systems; Competitive sorption effects in more than two-solutes systems was studied, and it was exhibited that mixture of two cosolutes each of which could suppress sorption of nominal solute onto the sediment had synergistically competitive sorption effect on the nominal solute; A method about incorporating sorption/desorption of organic pollutants into river water quality model was developed, and discussion about degree of sorption/desorption effect on model prediction for different organic compounds was made, which will provide theoretical basis and practical processes for setting up more accurate water quality model.

论文主要取得了以下研究成果。(1)有机化合物的吸附竞争能力与其物化性质具有相关性，易与沉积物有机质形成氢键的化合物其竞争能力也比较强；(2)可离子化有机化合物的吸附竞争能力与其存在形态有关。酚类、含苯环的羧酸类化合物，其离子态的吸附竞争能力远小于分子态，其机理为有机酸阴离子所带的负电荷抑制了表面吸附能力，主要发生分配作用；而苯胺类化合物，其离子态和分子态都表现出显著的竞争能力，而且离子态的竞争能力略强于分子态，原因在于有机碱阳离子所带的正电荷促进了其表面吸附能力；有机化合物竞争能力的强弱与其单组分吸附等温线的非线性程度具有一定的相关性，吸附等温线近似为线性的化合物没有或只具有微弱的竞争能力；(3)对目标有机化合物的吸附具有竞争效应的有机化合物混合后，将对目标有机化合物的吸附产生协同竞争效应；(4)以京杭运河为例，率先提出了将有机污染物的吸附／脱附作用及水文水力参数耦合到水质模型中的方法，并讨论了吸附／脱附作用对不同有机污染物预测模型的影响，为建立更准确的水质模型及进行更客观的风险和生态评估提供了参考依据。

Four main parts were included in this dissertation:(1) Precise measurement of Gvalues of hydrogen peroxide in the reactions of flavonoids with superoxide anion andα-hydroxy ethyl peroxyl radicals;(2) Kinetic studies of the reactions of typicalflavonoids with α-hydroxy ethyl peroxyl radicals;(3) HPLC-MS analysis of theproducts after γ-irradiating rutin ethanol solution saturated with air, a reactionmechanism was proposed;(4) Preliminary investigation on the reaction between rutinand peroxynitrite.

本论文的内容主要包括四部分：(1)黄酮类化合物在与超氧阴离子自由基以及α-羟乙基过氧自由基反应的过程中生成的过氧化氢G值的准确测定；(2)几种典型的黄酮类化合物与α-羟乙基过氧自由基的反应动力学研究：(3)空气饱和芦丁乙醇溶液经γ-辐照后产物的HPLC-MS分析及反应机理推测；(4)对芦丁与过氧亚硝酸盐的反应做了初步的探索。

The Ca2+ salt solution as a new regenerant was presented in this paper. The influences of the calcium salt proportioning, temperature, dosage and flow rate on anion exchange fiber regeneration were studied. High regeneration can be obtained with 0.5 mol/L CaCl2+8 g/L CaO+6.5 °Bx sucrose solution at 70～80 ℃, the dosage of the Ca2+ salt solution was about half of the raw decoloring syrup, the regenerant flow rate should be lower than that of the raw decoloring syrup. It was shown that stable decolorization rate and lower decline in exchange capacity could be achieved with the new regenerant. It performed more effectively than the traditional sodium salt regenerant with less discharge of waste water.

选用二价钙离子蔗糖溶液为再生剂，再生蔗糖脱色后的强碱性阴离子交换纤维，研究了再生液的配比、再生温度、再生液用量、再生液流速等因素对再生效果的影响，结果表明配比为0.5 mol/L CaCl2+8 g/L CaO+6.5 °Bx蔗糖的再生液在70～80℃温度下，再生剂的用量约为脱色糖汁的一半，流速应低于脱色时的流速时，再生效果优于传统的钠盐再生剂的再生效果，重复再生后的纤维脱色率能保持稳定，交换容量下降少，且再生液能回收利用，废水排放量小，是一种环保型再生液。

The Ca(superscript 2+) salt solution as a new regenerant was presented in this paper. The influences of the calcium salt proportioning, temperature, dosage and flow rate on anion exchange fiber regeneration were studied. High regeneration can be obtained with 0.5mol/L CaCl2+8g/L CaO+6.5 °Bx sucrose solution at 70~80℃, the dosage of the Ca(superscript 2+) salt solution was about half of the raw decoloring syrup, the regenerant flow rate should be lower than that of the raw decoloring syrup. It was shown that stable decolorization rate and lower decline in exchange capacity could be achieved with the new regenerant. It performed more effectively than the traditional sodium salt regenerant with less discharge of waste water.

选用二价钙离子蔗糖溶液为再生剂，再生蔗糖脱色后的强碱性阴离子交换纤维，研究了再生液的配比、再生温度、再生液用量、再生液流速等因素对再生效果的影响，结果表明配比为0.5mol/L CaCl2+8g/L CaO+6.5 °Bx蔗糖的再生液在70~80℃温度下，再生剂的用量约为脱色糖汁的一半，流速应低于脱色时的流速时，再生效果优于传统的钠盐再生剂的再生效果，重复再生后的纤维脱色率能保持稳定，交换容量下降少，且再生液能回收利用，废水排放量小，是一种环保型再生液。

The two-photon absorption cross-sections of these styryl derivatives were determined by Z-scan technique, and the benzothiazolium derivatives exhibited the largest TPA cross-sections (10〓s·cm〓/photon) and the best power limiting ability at high operable incident intensity. The results show that the benzothiazolium derivatives are promising organic compounds as two-photon absorption optical limiting materials. 2. Several organic dyes active to 800nm femtosecond laser with D-π-A structure were designed and synthesized.

研究了它们的上转换荧光、上转换激射和光限幅行为，通过改变染料分子共轭体系的大小，首次实现了在576nm-635nm范围内的双光子上转换激光波长的调节，其中噻唑啉碘盐类二苯乙烯化合物的双光子上转换激射峰（576nm）是迄今在1064nm皮秒激光作用下能够得到的最短波长的激光；阴离子显著改变上转换激射效率，但对上转换荧光峰和激射峰的位置影响很小；增加溶液的浓度，上转换荧光光谱和激射光谱红移，并在一定的浓度范围内，能够有效的提高上转换激射效率；利用Z-扫描技术测定了染料分子的双光子吸收截面，发现苯并噻唑类染料分子的双光子吸收截面高达10〓s·cm〓／photon，而且在较大的入射光强范围内，这类染料分子具有较大的光限幅能力，是一类作为双光子吸收光限幅材料很有潜力的染料分子。

Emulsification is the mainly reason to influence on the reaction, the influences of emulsifiers such as the concentration of emulsifies, the ratio of anionic to nonionic emulsifier on the polymerization stability were researched;The influences of concentration and feeding method of initiators on the reaction stability and the mechanical properties of coating film of acrylate polymerization stability were researched;The influences of reaction temperature, stirring speed and pH buffer agent on the polymerization stability and pH regulator on the storage stability of Acrylate emulsions were also researched.

乳化剂是影响乳液稳定性的主要因素，因此对乳化剂进行了全面的探讨，包括乳化剂的种类和用量、阴离子型与非离子型乳化剂的比例对乳液稳定性的影响；文中还研究了引发剂的用量、加入方式对聚合稳定性的影响，以及引发剂用量对聚丙烯酸酯涂膜力学性能的影响；此外，讨论了反应温度、搅拌速率、pH值缓冲剂对乳液聚合过程稳定性的影响及pH调节剂对乳液贮存稳定性的影响。

A method of dyeing a polyamide fiber structure characterized by using a polyamide fiber structure which has structural differences along the fiber length direction and dyeing the structure with an anionic reactive dye in a dye bath having a pH of 3 to 8; and a dyed polyamide fiber structure obtained by the above method.

本发明的聚酰胺类纤维构成物的染色方法，是以用纤维纵向上有结构差别的聚酰胺类纤维构成物，经将pH调至3～8的含阴离子性反应性染料的染液染色为特征的，本发明的染色物是由该染色方法制得的聚酰胺类纤维的染色物。

Wheares under buffer pH5.2, there is no strong static electricity and instead being a longer wavelength movement; SDS\'s participation just restricts the relative movement of heme\'s ethylene; a new fluorescent peak forms and the reduction of enzymatic activity is due to the packing of micella\'s formation.

强变性的阴离子表活剂SDS与带净正电荷和弱负电荷的SBP(处于pH2.6和4.2缓冲液中)有强烈的静电力作用，酶活力丧失，二级结构变化，荧光强度增加，特征Soret发生蓝移，卟啉环的π-π*共轭的分裂能增大；而当SBP带净负电荷(pH5.2)时，没有静电吸引力，Soret带发生红移；SDS的引入只是限制了血红素上乙烯取代基的运动，使其与卟啉环共轭：极性环境的变化导致产生新的荧光峰；酶活力因胶团包裹作用而有下降。

As shown in the experimental results: as the conductor of petroleum biological degradation, the quantity of microorganism is the important factor of petroleum degradation efficiency, the huge natural capacity of microorganism in soil is its foundation of bioremediation; petroleum density in certain scope do not affect for the degradation efficiency of petroleum, and in the density of 5%, its initial degradation efficiency is higher, however after training 40 days, this kind of advantage change weak gradually, the reason may be the petroleum of high density probably having certain poison role for microorganism; the best ecological condition of petroleum contaminated soil bioremediation is that nutrition material C: N = 60, electron receives body HiOi joining quantity amount to 12 mg/g, water content is 50%, surface activator is anion surface activator of 12 Wan base benzene sulphur sour sodium; the relation of primary and secondary of factor is water content, surface activator, nutrition material and electron receiver.

试验研究结果表明：作为石油生物降解的执行者，微生物的数量是影响石油降解效率的重要因素，土壤中微生物的巨大的自然容量是其生物修复的基础；石油浓度在一定范围内对石油的降解效率并没有影响，并且在5％浓度时，其起始降解效率较高，但是到了培养40天以后，这种优势渐渐变弱，可能还是高浓度的石油对微生物有一定的毒害作用；石油污染土壤生物修复的最佳生态条件为：营养物质C：N为60，电子受体H_2O_2的累计加入量为12mg/g，含水量为50％，表面活性剂为阴离子表面活性剂十二烷基苯磺酸钠；因素的主次关系为：含水量、表面活性剂、营养物质和电子受体。

Oxalic acid loading substantially stimulated soil P release from A1 horizon, showing a linear relationship; but its effect on B horizon soil was relatively negligible, especially at low oxalic acid concentrations mmol L^(-1. Oxalate solutions 0.5~20.0 mmol L^(-1 oxalic acid adjusted to pH 5.16 with 10.0 mmol L^(-1) NaOH had a much higher (1.51~2.98 times) soil-P-release effect than oxalic acid solution the same in oxalate concentration. Therefore, the mechanism of oxalic acid/oxalate triggering release of soil phosphorus is assumed to be dominated by ligand-exchange or complexing reactions of oxalate anionC2O(superscript 2- subscript 4 but not simply acid-dissolving effect. The effect of oxalate anion on soil phosphorus release was found to be somewhat cumulative, i.e. the amount of P released was primarily controlled by the cumulative oxalate loading rate, relatively independent of the manner of oxalate addition (one-time or sequential).

结果表明，草酸能显著促进暗棕壤A层磷的释放，土壤磷溶出量随草酸溶液浓度升高而线性增加；但对B层土壤磷的释放效应相对较弱，草酸浓度低於5mmolL^(-1)时B层磷的释放不明显。pH5.16草酸钠溶液比相同浓度的草酸溶液具有更高的解磷效率，在设置二者浓度为0.5~20.0mmolL^(-1)时，前者的解磷量是后者的1.51~2.98倍，推断草酸盐溶液或凋落物淋洗液中草酸类物质促进暗棕壤磷释放的主要机理在於草酸阴离子C2O(上标 2-下标 4配位反应。

It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发，分析对称连杆曲线上鲍尔点的产生条件，提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品，年生产总值3000万美元，产品价廉物美、选料上乘、质量保证，深受国内外客户的青睐