阴离子的
- 与 阴离子的 相关的网络例句 [注:此内容来源于网络,仅供参考]
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Src l was an acidic cytolysin, which was reported forthe first time. The cDNA encoding the mature Src l was cloned into non-fusion expression vectorpBV220 and expressed successfully in E.coli DH5α in inclusion body. After washing anddenaturing-renaturing, the recombinant Src l protein was purified by Q Sepharose FastFlow ion exchange chromatograph and Phenyl Sepharose hydrophobic interactionchromatograph.
首先构建了Src I基因的非融合蛋白表达质粒pBV220-Src I,并成功地在原核细胞E.coli进行了重组表达,筛选出稳定表达的工程菌株DH5α,摸索了稳定表达的条件,摸索了包涵体的洗涤、变性和复性条件,摸索出了复性蛋白Src I的纯化工艺,纯化过程简单,经QSepharose Fast Flow阴离子交换层析和Phenyl Sepharose疏水层析两步纯化,就可获得了高纯度的重组蛋白样品(纯度达99%以上),该纯化方法适合重组蛋白的大量纯化,为Src I的性质、结构和功能研究奠定了良好的基础。
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Since the dismutation of superoxide radicals by SOD is a reaction that is rate-limited by diffusion and enhanced by electrostatic guidance, all these structural features may be related to GP-MnSOD's high catalytic activity: first, Lys38 may increase the effective enzyme-substrate association rate by enhancing the electrostatic gradient at its substrate channel; second, an excess of acidic over basic residues makes the negative surface potential of GP-MnSOD more larger than those of other known MnSODs. This may enhance the reaction rate by reducing futile collisions of superoxide radicals with GP-MnSOD's surface.
因此,GP-MnSOD的上述结构特征可能与GP-MnSOD的较高酶活有关:首先,Lys38增加了底物通道口的正静电势梯度,从而可能促进了GP-MnSOD的活性中心与底物的有效结合速率;其次,GP-MnSOD表面覆盖的过量酸性残基使得它比其它MnSOD在底物通道以外的蛋白表面更多地被负静电势所覆盖,这可能有效地减少了超氧阴离子与GP-MnSOD表面的无效碰撞,从而提高了反应速率。
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Water-rock interaction demonstrates that, a gold-boring formation , i. e., a set of light metamorphic clastic gritstone, sandy slate, and tuffaceous slate in Wuqiang Runnel Formation, Ban Stream Group, act as the source of gold deposits in South-West Hunan. The gold is originally derived from volcanic eruption materials in Wuling-Xuefeng period; for the typical single gold deposit such as Mobin, which is short of sulphide, chlorine is very important in the metallogenic process; sulphur and chlorine perform as the major negative ions to form complex ions with Au throughout the gold activation and migration movement. The complex ion of chlorine and gold may keep stable in a wide range of temperature; the physical-chemical conditions in typical geothermal fluid system are of deciding significance for gold activation, migration and precipitation.
特定体系的水岩实验证实了漠滨及整个湘西南金矿的成矿元素Au和伴生元素主要源于赋矿围岩-板溪群五强溪组的一套浅变质碎屑砂岩、砂质板岩和凝灰质板岩;首次突破传统认识,证明氯在中低温热液体系中能与Au形成稳定络合物的形式进行运移,因此氯在本区Au成矿过程中起着相当重要的作用;成矿热液流体中Au主要以金硫、金氯络合物形式在溶液中迁移,阴离子∑S、Cl〓对金的活化、迁移及沉淀起主导作用,Au的伴生元素As、Sb在热液体系中与Au形成金锑、金砷络合物有利于金的进一步活化、迁移及沉淀;中低温热液流体成矿过程中,体系的物理化学参数对Au的活化、迁移及沉淀富集起决定性作用。
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In one embodiment, the invention is a system for initiating free radical polymerization comprising: a in one part, one or more amido-borate compounds containing one or more anionic amido-borate moieties comprising an organoborate wherein the boron atom is bonded to a nitrogen atom of ammonia or an organic compound containing one or more nitrogen atoms, such as a hydrocarbyl amine, a hydrocarbyl polyamine, or an aromatic heterocycle containing one or more nitrogen atoms and optionally containing one or more heteroatoms or heteroatom containing functional moieties, and one or more cationic counter ions and b in a second part, a liberating compound which reacts with the nitrogen atom bound to the boron atom upon contact with the amido-borate to form an organoborane radical.
在一个实施方案中,本发明是引发自由基聚合的体系,包括:a在一个部分中,一种或多种含有一个或多个包含有机硼酸根的阴离子酰氨基-硼酸盐部分和一个或多个阳离子抗衡离子的酰氨基-硼酸盐化合物,其中的硼原子键合到氨的氮原子或含一个或多个氮原子的有机化合物,例如烃基胺、烃基聚胺或含一个或多个氮原子和任选含一个或多个杂原子或含杂原子的官能部分的芳族杂环的氮原子上,和b在第二部分中,在与酰氨基-硼酸盐接触时与键合到硼原子上的氮原子反应形成有机硼烷基团的释放化合物。
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The surface activity of Hibiscus syriacus has been studied and shows thatHibiscus syriacus has good surface activity.The influence of temperature,saltness,water hardness and pH on the surface activity of its aqueous solutionsis also studied and shows little influnce.Also the mixture systems of Hibiscussyriacus with some anioic surfactants have been studied and the results show thatthe mixture systems can produce remarkable synergism.
天然表面活性植物木槿叶的应用研究本课题对天然植物原料木槿叶提取物中的表面活性物的性质(临界胶束浓度、表面张力和起泡性能)及其影响因素(温度、pH、水硬度和盐度等)进行了系统的研究,结果表明木槿叶表面活性物具有较好的表面活性,且它的cmc和〓在一定范围内受一些因素的影响也不大,是一种理想的香波原料;同时也研究了木槿叶活性物与其它温和型的阴离子表面活性剂的复配体系,表明具有明显的协同增效效果。
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The joint toxicity was evaluated by different methods, including toxicity unit,additive index, similarity parameter and mixtures toxicity index. The results show that the binary joint effects of phenol and toluol mixed with SDS are synergistic, while the binary joint effect of SDS and nitrobenzene is antagonistic. The environment risk of some compounds will be enhanced because of the joint of SDS.
研究结果表明: 4种不同的评价方法对SDS与取代芳烃苯酚、甲苯和硝基苯的联合效应评价结果具有较好的一致性,即SDS与苯酚、甲苯的二元混合体系的毒性表现为不同程度的协同作用,而与硝基苯则表现为弱拮抗作用;对环境存在风险性的阴离子表面活性剂SDS,当与一些有毒有害物质共存时会增加该类物质的环境风险性。
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The composition comprises: 35 to 65 wt % of an anionic detergent or surfactant selected from alkyl benzene sulphonic acids, alpha olefine sulfonates, long chain fatty acid sulphates, higher fatty acids, as well as the alkali metal and alkaline earth metal salts thereof, and natural detersive agents, and mixtures of any of these; 3 to 15 wt % of a non-ionic detergent or surfactant selected from alkoxylated alkyl phenols and alkoxylated fatty alcohols; 5 to 10 wt % of a water-swellable cellulose derivative or a salt thereof, wherein the cellulose derivative exhibits a viscosity of at least about 1500 cps, measured in a 1 % aqueous solution at 25 DEG C with a Brookfield viscometer having spindle 3, speed 30rpm, factor 40 for viscosities of 2500-3500 cps; 6 to 20 wt % of a solubility regulator selected from alkali metal and alkaline earth metal chlorides, carbonates and sulphates, aluminosilicates and starch; and 0 to 20 wt % of a fragrance or perfume in solid, liquid or microencapsulated form.
该组合物包含:a35―65%重量的阴离子洗涤剂,其选自烷基苯磺酸、α-链烯烃磺酸盐、长链脂肪酸硫酸盐、高级脂肪酸以及其碱金属和碱土金属盐和天然的去污剂,和任何这些组分的混合物;b)3―15%重量的非离子洗涤剂,选自烷氧基化烷基酚和烷氧基化脂肪醇;c)5~10%重量的水可溶涨的纤维素衍生物或它们的盐,其中纤维素衍生物按1%水溶液在25℃下用Brookfield粘度计(3号转轴,转速30rpm,2500―3500cps粘度的因子是40测定;具有粘度至少约1500cps;d)6―20%重量的溶解性调节剂,选自碱金属和碱土金属氯化物、碳酸盐和硫酸盐、硅铝酸盐和淀粉;和e)0~20%重量的为固体、液体或微囊包封形式的香精。
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Both star copolymer precursors are hydrolyzed in the acidic conditions, then the corresponding recovered star copolymers of EO and glycidol with multi pending hydroxylmethyls are esterified with 2-bromoisobutyryl bromide to produce the ATRP macroinitiators with multi pending bromoisobutyryl groups . Then the latters initiate the polymerization of styrene to form the corresponding amphiphilic three- and four-arm star PEO-g-PS.
在阴离子共聚EPEE单体和环氧乙烷单体的过程中,通过变换引发剂体系中的醇的结构(由原来的二元醇变成多元醇,如三羟甲基丙烷和季戊四醇),合成了星形结构的共聚物,通过水解反应脱去保护基团后,再与2-溴异丁酰溴反应,得到链的侧端挂有很多2-溴异丁酸酯基的星形大分子引发剂,通过ATRP聚合机理引发苯乙烯聚合得到PEO为主链,PS为侧链的星形一接枝共聚物。
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These compounds are of substantial interest both inviewpoints of theory and practical applications, mainlyunder the stimulus to achieve synthetic models either foractive sites of iron-sulfur proteins or for transitionmetal catalysts. This thesis describes the synthesis, structures andconformations of 51 new iron-sulfur cluster complexes,which have been characterized by elemental analysis andstandard spectroscopic methods. In addition, single-crystalX-ray diffraction analyses were performed for 4 representa-tive new compounds. Reactivities of μ-〓 with mono- and di- Grig-nard reagents derived intermediates toward various organicelectrophilic substrates were studied, along with complexa-tion of arynyl-containing iron-sulfur clusters by 〓Thus, several bridged, non-bridged, monomeric, dimeric,homonuclear, heteronuclear iron-sullfur and iron-sulfur co-balt-carbon cluster complexes were synthesized. A novelreaction and convenient route for the synthesis in highyield of tetranuclear iron complexes 〓 containing atetracoordinated sulfur atom was discovered, whereas aplausible mechanism based on experimental results was propo-sed for the formation of the new cluster type.
鉴于有机铁硫原子簇化学在基础理论发展和应用方面的重要意义,因此我们开展了这一课题的研究,并取得以下主要成果: 1、本文共合成了51个新有机铁硫及含钴碳簇基的有机铁硫原子簇配合物,除用元素分析,NMR,IR,MS法表征其结构和构象外,还用X-光衍射技术测得四个代表性配合物的单晶结构和构象; 2、我们业已发现炔基Grignard试剂同〓可形成一种&开环&与&闭环&中间物的平衡混合物,研究该平衡混合物同各种亲电试剂的反应; 3、研究发现了一种可高产率地形成〓含〓四配位硫挛合簇的新化学反应并对此反应提出了—种有趣的反应机理; 4、首次由1,4-二溴丁烷双Grignard试剂与〓制得一种新型铁硫簇双硫阴离子活性中间体,并进而研究了它的亲核反应性能; 5、找到了通过〓的光化学反应来合成簇合物〓-〓的一条有实用价值的新路线。
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The results show that myristic acid radical anion of precursor Zn0.78 Al0.2220.22c13h27COO0.81H2O can be almost completely replaced by complex anion [La(TiW11 O39)2]^3- under special controlled reaction conditions.
结果表明,该产物中[La(TiW11O39)2](上标 13-)配阴离子沿其长轴垂直于层板的方向分布于水滑石层板间,产物有规整的层状结构、大的层间距(d003=3.29nm)、良好的结晶度和热稳定性,产物对二甘醇与苯甲酸的酯化反应、二甘醇的脱水环化反应和苯甲醛的氧化反应具有良好的催化性能。
- 推荐网络例句
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Lugalbanda was a god and shepherd king of Uruk where he was worshipped for over a thousand years.
Lugalbanda 是神和被崇拜了一千年多 Uruk古埃及喜克索王朝国王。
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I am coming just now,' and went on perfuming himself with Hunut, then he came and sat.
我来只是现在,'歼灭战perfuming自己与胡努特,那麼,他来到和SAT 。
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The shamrock is the symbol of Ireland and of St.
三叶草是爱尔兰和圣特里克节的标志同时它的寓意是带来幸运。3片心形叶子围绕着一根断茎,深绿色。