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This thesis consists of three main parts of the research work on the syntheses, structures and reactivities of the olefin-coordinated transition metal carbene and carbyne complexes. In chapter 1, on the basis of our previous research works on the reacitivites of the cationic carbyne complexes of transition metals with metalcarbonyl anions, we explored the reactions of the cationic carbyne complexes of manganese (1) and rhenium (2) with polymetalcarbonyl anions, and developed a new method for the preparations of heternuclear trimetal bridging carbyne complexes.

本论文对烯烃配位的过渡金属卡宾和卡拜络合物的合成、结构和反应性能进行了研究,主要进行了如下三方面的工作:第一章在本小组过去的研究基础上,进一步考察锰和铼的阳离子卡拜络合物1和2与羰基金属阴离子化合物的反应,用来合成异核多金属桥卡拜络合物,发展合成多金属桥卡拜络合物的新方法和新路线。

It was discovered that this modified kaolin had ideal capability of removing arsenic from water because of its giant active surface and coordinate action, intensify, for arsenate ions AsO(superscript 3- subscript 4 and Fe(superscript 3+) fixed on the framework, and achieving the aim of removing the minimal content of arsenic from the water.

以高岭土为原料通过碱熔合成得到类似于分子筛的笼状骨架结构,并将Fe(上标 3+)通过离子交换吸附,负载在其骨架上,实现改性;利用改性后的吸附剂具有大的活性表面积,以及砷阴离子AsO(上标 3-下标 4与Fe(上标 3+)的强配位能力,实现了基于配体交换的固液分离的从微量含砷水中去除砷。

Superoxide dismutase (EC 1.15.1.1;SOD) is a metal-containing enzyme that widely exist in organisms. It catalyzes the dismutation of superoxide free radical and produces hydrogen peroxide and oxygen.It plays an important role in protecting the plasmalemma from the reactive oxygen species.A recombinant plasmid pPICZA-sodM18 was constructed and after its linearization was transferred into chromosome of Pichia pastoris GS115 by electroporation.

超氧化物歧化酶(Superoxide dismutase;EC 1.15.1.1;SOD)是广泛存在于生物体内的金属酶,是机体内唯一以超氧阴离子自由基(O_2~-)为底物的酶,它能专一地催化O_2~-的歧化反应,生成过氧化氢和氧气,能有效的抵御氧自由基和其他氧化物自由基对细胞质膜的毒性,对机体防御氧化损伤起着十分重要的作用。

The developing principle of MB gypsum fine foamer which takes compound honey-locust abietic acid anionic surfactant as principal composition,is analyzed in theory.

从理论上分析了以复合型皂角松香酸类阴离子表面活性剂为主要成分的MB石膏微发泡剂的研制原理,详细研究了MB微发泡剂在石膏料浆中的起泡条件、起泡性能及其对硬化后的建筑石膏物理力学性能的影响,MB微发泡剂与现有发泡剂的性能比较,MB微发泡剂在纸面石膏板中的应

In every group, rabbits were subdivided into experimental and control subgroups. 2 Rabbits were bullets injected followed by continuous injected with 13C labeled leucine, glucose, and lactic acid; 3 Blood were drewed before and 150, 160, 170, and 180 min after the initiation of isotopes injection for material analysis; 4 Exhale gas were collected every 5 min in the first 30 min followed by every 30 min there after for material analysis; 5 After centrifuge in low temp the supernatant of the blood samples were collected and went through axon and anon exchange column treatment; 6 Treated blood sample was used for 13C labeled leucine, glucose lactic acid examination through mass spectrograph; 7 The exhale gas was collected for 13CO2 exam through gas-phase mass spectrograph; 8 CO2 total production rate (V13CO2), body various substances production, oxidation speed, and substances metabolic percentage all can be calculated through equations provided by references below; 9 Data was processed through student t test.

分亮氨酸、葡萄糖和乳酸三组各取健康新西兰兔16只,每组再分为高代谢脓毒症组和对照组两部分,建模方法同第一部分;2)三组分别先静脉弹丸式推注再持续灌注13C标记的亮氨酸、葡萄糖和乳酸;3)灌注前抽取动脉血作为背景值,灌注达150,160,170和180min分别抽取动脉血2ml用于质谱分析;4)实验开始后前30min中每5min收集呼出气一次,随后每30min收集呼出气一次,用于气相质谱分析;5)血样经过低温离心取上清液,过阳离子及阴离子交换树脂,再经衍生化处理;6)处理过的血样进入气相色谱-质谱仪,测量其13C标记的亮氨酸、葡萄糖和乳酸丰度;7)实验兔的呼出气通过13CO2气相质谱分析仪测定其中的13CO2丰度(E13CO2);8)利用文献提供的公式算出CO2总生成率(V13CO2)以及机体各物质的通量、氧化速率以及物质代谢百分比等;9)数据分析处理采用t检验。

Vulgaris to magnetic treatment The Superoxide anion in algae cell increased and antioxidant ability was declined by a suitable magnetic treatment. There was different response of the enzymic component-Superoxide dismutase , Catalase , and peroxidase enzyme, and their activities were induced to increase. There was no much response for the nonenzymic component-glutatnione to the magnetic treatment, while content of carotenoid was reduced remarkably with the increasing magnetic intensity and time.

小球藻抗氧化系统对磁处理的响应一定强度的磁处理使小球藻中超氧阴离子·O〓升高,抗氧化能力降低,抗氧化酶系统的关键酶SOD,CAT,POD酶应激性升高;非酶体系的GSH对磁处理响应不明显,Caro含量普遍有较为明显的降低,随处理时间的增加Caro的量下降显著。

To investigate the pitting and metastable pitting rules of type 304 stainless steel, potentiodynamic polarization method was employed to study the behavior of metastable pitting and stable pitting on 304 stainless steel in sodium bromide solution and borate/phosphate buffered bromide solutions. The influence of the concentration of Br-、the pH value、the buffer capacity and general environmental factor to pitting potential and metastable pitting was studied as well.

为了更深入地了解304不锈钢的稳态及亚稳态孔蚀规律,本文采用动电位慢扫描法测得了304不锈钢的阳极极化曲线,研究了不锈钢在纯溴化钠溶液及含溴化钠的硼酸盐或磷酸盐缓冲溶液中的亚稳态孔蚀以及稳态孔蚀行为,分析了溴离子浓度、pH值、缓蚀性阴离子、以及缓冲容量和综合环境因子对孔蚀电位以及亚稳态孔蚀特征参数中的形核数目、峰值电流、生长寿命的影响。

From the results of IR and XPS spectrocopy. The cationic sol components H〓SiO〓 and 〓 of the solution trend to adsorp on the surface of electronegative aegirine because of electrostatic acctraction each other, and interrupted the collector's reaction with Fe〓 on the surface. Hence the flotation of aegirine was decreased, on the other hand, there is electrostatic repulsion between the surface of hematite and the cationic sol H〓SiO〓.〓, Which has advantage to dispersion of hematite particles, therefore, the hematite flotation is achieved sucessfully with anionic collector.

根据红外光谱和XPS测试结果可知,在弱酸性介质中,活性硅酸胶体抑制剂中荷正电的胶团H〓SiO〓及〓由于电性吸引而选择性地覆盖在荷负电的钠辉石表面,从而阻碍了阴离子捕收剂与表面Fe〓的配位作用,导致钠辉石的浮游被抑制;而赤铁矿表面由于荷正电,与矿浆中的H〓SiO〓、〓等硅酸胶团存在着电性排斥作用,有利于赤铁矿颗粒的稳定分散,所以赤铁矿能够被脂肪酸捕收剂吸附而选择性上浮。

First,the content of surfactant should be more than 18 percent and the content of anion surfactant should be kept in proper proportion to the content of nonionic surfactant. Second,the content of zinc naphthenate should be kept in directly proportional to the content of other surfactant. Third,the content of rosin shouldnt too higher and the content of oleic acid should be kept in directly proportional to the content of rosin. Fourth,the content of water should be kept in a low level (less than 8%);otherwise emulsifier oil will delaminate. In addition,the requisite content of sodium heavy alkyl benzene sulfonate is higher than petroleum sulfonate.

试验表明在以松香、重烷磺酸钠、石油磺酸钠为主要乳化剂时,要获得优良的乳化液,需满足以下几个条件:(1)需在乳化油配方中加入适量的乳化剂,且其中阴离子乳化剂总量与非离子乳化剂总量的应保持适当的比例;(2)乳化油中环烷酸锌的量与其它乳化剂总量要保持正比关系;(3)乳化油中松香的量不易过大,且油酸的加入量应与松香量成正比;(4)乳化油中水分含量不易过高(一般不能大于8%),过高时稳定性不好,易分层。

Single-component samarium diiodide catalyst system was first used with polymerization of acrylonitrile. Adding of hexamethylphosphoramide could greatly improve reaction activity of the catalyst system. AN/Sm12 and l{IVIPA1 Sm12 molar ratios, reaction time and temperature were mainly investigated with yields and molecular weights of resultant PAN.

研究发现HMPA的加入可以极大地提高催化活性;考察了单体与催化剂(SmI2)的摩尔比例、第二组分与催化剂(SmI2)的摩尔比例、反应温度、反应时间等因素对相应聚合物的产率和分子量的影响,通过对聚合物的红外和核磁的分析,提出了&单电子转移-双阴离子引发&机理。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。