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When the reaction is carried out at 22 ℃, a cage complex with an encapsulated diethyl ether, 2 is prepared.

发现温度对自组装反应有着重要的影响:当组装在37-40℃进行时,可以得到包容一个NEt〓的阳离子型超分子笼1,其对阴离子为BF〓,处在超分子笼的外面;当组装在22℃进行时,可以得到包容一个乙醚客体分子的中性超分子笼2。

The mechanism of dioxygen oxidation of 4-nitrotoluene-2-sulfonic acid to 4,4'-dinitrostilbene-2,2'-disulfonic acid in alkali solution under mild condition was investigated.

探讨了在温和条件下在碱的水溶液中氧气液相氧化 4-硝基甲苯- 2 -磺酸制取 4,4'-二硝基二苯乙烯- 2 ,2 '-二磺酸的反应机理,发现 4-硝基甲苯- 2 -磺酸在碱作用下发生离子化生成 4-硝基- 2 -磺酸基苄基阴离子,然后被活化的分子氧氧化成 4-硝基- 2 -磺酸基苄基自由基是反应的关键步骤。

The chelating ability of its enolate anion (TTF-ph-tfac) has been investigated with [MIICl_2·xH_2O] (M = Zn and Co) leading to complexes Zn(TTF-ph-tfac)_2(CH_3OH)_2 (7) and Co(TTF-ph-tfac)_2(CH_3OH)_2 (8), where the metal center is coordinated by two TTF-ph-tfac ligands. This redox active ligand shows promising features for the elaboration of hybrid organic-inorganic building blocks.

具有反铁磁行为的化合物5在110-120K观察到了相转变的发生,是目前已报道的该类化合物中最高的相变温度。3、TTF-ph-tfac烯醇阴离子具有很强的配位能力,与金属氯化物螯合配位分别生成了配合物Zn(TTF-ph-tfac)_2(CH_3OH)_2 (7)和Co(TTF-ph-tfac)_2(CH_3OH)_2 (8),每个中心金属都桥连两个TTF-ph-tfac配体。

The effect of hydrophobic additive on the seed precipitation from sodium aluminate solution was studied by adding fatty acid and heneicosane at different proportions.

研究了疏水性添加剂脂肪酸类阴离子表面活性剂与21-碳烷不同配比对铝酸钠溶液分解产生氢氧化铝和氧化铝的粒度、强度及分解率的影响,考察了产物Al3和Al2O3的强度和粒度之间的关系,探讨了添加剂影响铝酸钠溶液晶种分解的相关机理。

The effect of hydrophobic additive on the seed precipitation from sodium aluminate solution was studied by adding fatty acid and heneicosane at different proportions. The results show that when the mass fraction of fatty acid is in the range of 32%-49% and the additive concentration in sodium aluminate solution is 150×10-6 g/L, the rate of precipitation increases, but the particle size of Al3 and Al2O3 reduces.

摘 要:研究了疏水性添加剂脂肪酸类阴离子表面活性剂与21-碳烷不同配比对铝酸钠溶液分解产生氢氧化铝和氧化铝的粒度、强度及分解率的影响,考察了产物Al3和Al2O3的强度和粒度之间的关系,探讨了添加剂影响铝酸钠溶液晶种分解的相关机理。

The structure consists of discrete adamantylammonium cations lying on crystallographic mirror planes and hexa- fluoridogermanate anions disordered about sites of 2/m point symmetry.

它的结构中包含位于晶体学对称面上的离散的金刚烷胺阳离子,而无序的六氟锗酸盐阴离子位于2/m对称点。

The effects of reaction time, mole ratio of reactants and amount of catalyst on yield of ketal were investigated by using the [SO3H-bPy] [H2PO4] ionic liquid as catalyst. Results show that the ionic liquid was an efficient catalyst for the ketalization with high conversion and selectivity in mild conditions.

以磺酸基功能化的吡啶磷酸类离子液体[SO3H-bPy][H2PO4]为催化剂,系统考察了反应时间、酮与醇的配比、催化剂的用量及催化剂重复使用、不同阴离子、阳离子等因素对反应的影响,优化了反应条件。

SDS could dissolve the protein envelop as well as the lipide membrane of pathogen and cell. SDS is applied in light industry widely and safely, SDS is also made as microbicides in topical vaginal formulations to prevent the transmission of herpes and possibly other pathogens that cause sexually transmitted diseases,including HSV.

十二烷基硫酸钠(Sodium dodecyl sulfate,SDS)是一种阴离子型表面活性剂,为生物膜的最有效的溶解剂,它可以同病菌和各种高等动物的细胞膜的磷脂等脂质体结合而溶解,与蛋白质结合而变性。

The total flavone in antioxidant substance extracted from leaves of tartary buckwheat and its scaveninging function to OH and O(superscript - subscript 2) were determined by photometry and the inhibitory action to Lipin peroxidation and its synergy with other substances were studied by iodimetry in the experiment.

从苦荞叶中提取抗氧化性物质,用光度法测定提取物中总黄酮的含量及对羟自由基和超氧阴离子O(上标-下标 2的清除作用,并采用碘量法研究了苦荞叶提取物对脂质过氧化的抑制作用及与其他物质的协同作用。

The determination demonstrated that the anionic polymerization of ε-caprolactam under 230℃ leaded to a mesomorphous form of PA6; the EPDM had heterogeneous nucleation effect on the crystallization of dispersed PA6 phase; in situ polymerization could further reduce crystallization enthalpy of PA6 component on the level of reactive compatibilization.

研究表明,230℃下进行阴离子聚合得到的PA6为β-介晶型;EPDM对这种分散在橡胶相中的PA6的结晶具有异相成核作用;原位聚合可在反应增容的基础上使得共混物中PA6的结晶焓进一步降低。

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Lugalbanda 是神和被崇拜了一千年多 Uruk古埃及喜克索王朝国王。

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