阴极的

Preparation of the cathode includes:shaping under the press of 40Mpa, sintering at 550℃for 1 hour and at 900℃for 8 hours and threading with molybdenum bar; Considering the literatures we choose CaCl2 as salt for preparation titanium. Pretreatment of salt is for 1 hour at 100℃and for 2 hours at 300℃. Partial pressure of oxygen which need lower than 5.11×10-7Pa to reduct titanium oxides and hygroscopic property of salt need a sealed equipment to electrolyse. And finally successfully designed a satisfied one and the results show that the equipment can be satisfied the requirment of the experiment. Flow of the inert gas is 1.5L/min, the voltage is 2.8 V, temperature is 850℃and time is 2 hours during pre-electrolysis. Flow of the inert gas is 0.2L/min, the voltage is 3.1 V, temperature is 900℃and time changes with the mass of TiO2 during electrolysis, namely the greater need the longer time; To eliminate influence of salt and other impurities, the products need to wash with distilled water and dilute chlorhydric acid , then wash with dilute hydrochloric acid under supersonic wave assistant. Finally, electrometical properties of the electrolysis of TiO2 is researched by cyclic voltammetry and chronoamperometry, and results show that there are two main reodox steps, namely from TiO2 to TiO and from TiO to Ti.

阴极制备主要包括40MPa压力下模压成型、两段式烧结(1小时内升至550℃保温1小时，再1小时升温至900℃保温8小时)及烧结后TiO2块打孔用钼棒串接三个主要环节；实验中选用CaCl2作为电解熔盐，并对其进行预处理(100℃，保温1小时； 300℃，保温2小时)；经热力学计算，还原钛氧化物的氧分压至少要低于5.11×10-7Pa，结合电解过程中所用熔盐CaCl2有极强的吸水性的特点，电解装置应有较高的密封性，自行设计了一套密封性可靠的电解装置，便于实验过程中熔盐预处理和氧分压的控制；通过干燥处理预电解过程中Ar流量大约为1.5L/min、电压为2.8 V、温度为850℃、时间为2小时，电解过程中Ar流量大约为0.2L/min、电压为3.1V、温度为900℃，实验结果表明电解时间与TiO2质量密切相关，质量越大需要电解的时间越长；通过自来水冲洗—稀盐酸浸泡、洗涤—在超声波辅助作用下稀盐酸洗涤，可减少熔盐及其它杂质对电解产物检测结果的影响；最后，通过循环伏安法、计时电流法对电解机理的研究，确定电解还原TiO2制备金属钛主要经历了TiO2-TiO-Ti的过程。

Associated minerals are primary glauberite, halite and terrigenous mud; while calcite is absent or rare. The X-ray diffraction analysis shows that the mud-sized crystalline dolostone has an average CaCO3 mole content of 57.30% and an average degree of order of 0.40, revealing the characteristics of higher calcium content and lower degree of order. It is closely intergrown with glauberite, indicating that the aqueous medium in the depositional environment of mud-sized crystallinedolostone was hypersaline water or dilute brine. The temperature of water in the depositional environment calculated according to the oxygen isotope data averaged 30.5℃ and the minimum homogenization temperature of inclusions in primary glauberite crystals associated with mud-sized crystalline dolomite was 44℃. The two groups of temperature data are close, indicating that the temperature of the water in the paleolake environment during the deposition of mud-sized crystalline dolostone ranged from 30.5℃ to 44℃.

泥晶白云石在阴极发光下呈红色、橙红色，与其伴生的矿物除原生钙芒硝、石盐、陆源泥质外，方解石没有或极少；X衍射分析结果表明，泥晶白云石的CaCO3摩尔含量平均为57.30%，有序度平均为0.40，具高富钙、低有序的特征；与钙芒硝岩的紧密共生，说明泥晶白云岩沉积环境的水介质为高盐度的咸水或淡卤水；根据氧同位素数据计算的沉积环境的水体温度平均为30.5℃，与泥晶白云石伴生的原生钙芒硝晶体中的包裹体均－温度最低值为44℃，这两组温度数据基本接近，表明泥晶白云石沉淀时环境水体的温度大致在30.5-44℃之间。

First, a full three-dimensional numerical model is developed, which considering not only the rib resistance to the species, but both the single- and two-phase flow and transport in the gas channels and diffusers at both the anode and cathode sides of PEM fuel cell. Two sets of boundary conditions, one for a conventional flow field and the other for an interdigitated one, are presented. A detailed discussion of the numerical techniques for the PEM fuel cell model is given with a flow diagram to provide an overview of the solution procedure using FORTRAN language.

该模型考虑了双极板上流道间的筋部对于反应气体传递阻力以及电流密度分布的影响，从而使模型具有三维特性；建模过程中进一步考虑了流道和扩散层中可能存在的液态水，从而将现有的单相流动模型拓展成为两相流动模型，因此，该模型可以同时模拟电池内部阴极、阳极侧流道和扩散层中两相流动的发生和分布情况；分别给出了平行流场燃料电池和交指型燃料电池的边界条件；详细讨论的三维模型的耦合求解算法和技巧；用实验数据验证的该模型的准确性。

According to the experimental results, both the conducting area and material of current collector slices have great influence on the performance of micro PEMFC, especially the former one. The increment of cell's performance is finite by increasing the gas reheats temperature. The performance is better for open ratio 75% compared with 50% and 67%. The concentration polarization is improved by increasing the air flow rate at high current density and if the GDL diffusive capability in the latter cell could be promoted, the differences between these two cells' performances would be reduced.

由实验结果可知，集电片的导电面积与材料对於电池性能有显著的影响，尤其是前者；对於增加反应气体的再热温度，微型燃料电池增加的性能有限；双极板开孔率75%相较於开孔率为50%与67%有最佳的性能曲线；增加阴极气体空气的流量，可以改善高电流情况下的浓度极化现象，所以若我们能增加气体扩散层的扩散能力，则可以减少两者的性能差距。

The main research work of this dissertation is as follows: Based on the chemical reaction engineering theory and the nitrobenzene electroreduction mechanism, the plate and frame electrolyzer was designed and applied to the process of electroreduction nitrobenzene to p-aminophenol. This dissertation measured the residence time distribution data of the electrolyzer by means of the pulse response method and studied the rule of flow pattern along with the current capacity change. Under different conditions ,this dissertation studied the cyclic voltammetry properties of nitrobenzene on different electrodes by means of the dynamic cyclic voltammetry method and the electrode materials applied to the NB electroreduction have been selected primarily.Baseed on the results of cyclic voltammetry tests, this dissertation used p-electrode systems to measure the steady-state- polarization curves of nitrobenzene on different electrodes in H-type diaphragm cell, and obtained each primary factor s influence rule and the exchange current density value of each electrode.And then on the basis of the conclusions of fundamental researchs upword, the effects of influence factors on the the yield of p-aminophenol and the current efficiency,such as electrode material, current density, quantity of electricity circulated, nitrobenzene concentration . sulpuric acid concentration and so on, have been studied in detail in the systems of hign temperature , strong acidity and oxygen-poorthrough a series of electrolysis experiments in this paper.After all using Pb as anode Monel metal as cathode Dupont Nafion 417 cation-exchange membrane as membrane, this dissertation obtained the optimum technological condition: reaction temperature about 85C, current density 500A m-2, sulphuric acid concentration 20%wt.

论文的主要研究工作为：运用化学反应工程理论，结合硝基苯的电还原机理，设计出用于硝基苯直接电还原合成对氨基苯酚实验的板框式电解槽，并利用脉冲响应法测定了该板框式电解槽的停留时间分布数据，研究了流型随流量变化的规律；通过动态循环伏安法研究了硝基苯在不同电极上、不同条件下的循环伏安特性，初步评选出了用于硝基苯电还原的电极材料；结合循环伏安的测定结果，在H型隔膜电解槽中采用三电极体系测定了硝基苯在不同电极上、不同条件下的稳态极化曲线，得到了各主要因素的影响规律及硝基苯在各个电极上电还原的交换电流密度数值；在基础研究结论指导下，采用板框式电解槽，在高温、强酸、贫氧系统中，进行了一系列的电解实验，分别考察了电极材料、电流密度、通电量、硝基苯浓度、硫酸浓度等因素对收率及电流效率的影响，最终选择以蒙乃尔合金电极作为阴极、铅合金为阳极、Dupont Nofion 417阳离子交换膜为隔膜，得到由硝基苯直接电还原制对氨基苯酚的最佳电解工艺条件：反应温度85℃，电流密度500A·m~(-2)，硫酸浓度20％wt。

Finally, according to market conditions and market products this article paper analyzes the trends in the development of camera technology, and designs a color night vision camera.

最后根据市场情况和市面上产品的情况分析了摄像机技术的发展趋势，并设计了一款彩色夜视摄像机。

Only person height weeds and the fierce looks stone idles were there.

只有半人深的荒草和龇牙咧嘴的神像。