阳离子的

Selective doping has been proved to be a semiconductor oxide improve the photocatalytic activity of the most effective ways The introduction of certain metal ions can greatly improve the photocatalytic oxidation efficiency, Recently, a lot on the adoption of the doping to improve the photocatalytic oxidation performance reports, doped semiconductor photocatalysis material because of its physical and optical properties change, thereby improving the photocatalytic properties.

有选择性的进行掺杂已被证明是一种提高半导体氧化物光催化活性的极其有效的方法，掺入一定的金属阳离子能极大的提高TiO2的光催化效率，最近有大量的关于通过掺杂来提高TiO2的光催化性能的报道，掺杂的半导体光催化材料由于其物理和光学性质的改变，通过扩展光响应范围和提高光生电荷的分，从而提高了光催化性能。

In one embodiment, the invention is a system for initiating free radical polymerization comprising: a in one part, one or more amido-borate compounds containing one or more anionic amido-borate moieties comprising an organoborate wherein the boron atom is bonded to a nitrogen atom of ammonia or an organic compound containing one or more nitrogen atoms, such as a hydrocarbyl amine, a hydrocarbyl polyamine, or an aromatic heterocycle containing one or more nitrogen atoms and optionally containing one or more heteroatoms or heteroatom containing functional moieties, and one or more cationic counter ions and b in a second part, a liberating compound which reacts with the nitrogen atom bound to the boron atom upon contact with the amido-borate to form an organoborane radical.

在一个实施方案中，本发明是引发自由基聚合的体系，包括：a在一个部分中，一种或多种含有一个或多个包含有机硼酸根的阴离子酰氨基-硼酸盐部分和一个或多个阳离子抗衡离子的酰氨基-硼酸盐化合物，其中的硼原子键合到氨的氮原子或含一个或多个氮原子的有机化合物，例如烃基胺、烃基聚胺或含一个或多个氮原子和任选含一个或多个杂原子或含杂原子的官能部分的芳族杂环的氮原子上，和b在第二部分中，在与酰氨基-硼酸盐接触时与键合到硼原子上的氮原子反应形成有机硼烷基团的释放化合物。

The bulky ortho-brominated aryl groups are implanted to create nonplanarity around amino center. Thus, the effective conjugation length to the protonation site is shortened and the energy gap between neutral and protonated forms is narrowed. The protonation can only occur at the nitrogen atom of the benzothiazole and the temperature variation disturbs the equilibrium between the neutral and monocation and the reverible thermochromic effect can thus be achieved.

在邻位的位置引入立体阻碍大的溴原子，进而控制质子化过程的酸碱平衡只发生在 benzothiazole 上的氮原子上，企图达到只有中性分子，与单阳离子两种稳定的形式存在，经由外界的刺激下，例如温度或酸的量的改变，促使逆反应的发生，而达到热致变色的效果。

The function mechanism among the minerals and floatation drugs had been studied with the way of IR and academic calculation, which pointed out that absorption of G-4 on the surface of phosphorite belonged to physical and chemical types, but the chemical one was in the highest flight. Absorption of amine collector named GE-609 on the surface of quartz belonged to electrostatic and physical type. Distilled water could hardly wash the GE-609 down from the surface of quartz. Leading component of S-721 was the concentrated compound of naphthol sulfonic acid and formaldehyde. The compound had a stronger affinity to the Mg~(2+) on surface of dolomite than the Ca2+ on surface of phosphorite, which is the essential reason in the separation of phosphorite and dolomite. The leading components of soluble glass in function were HSiO3 hydronium and F^SiC^ colloid granule.

通过红外光谱测定以及理论计算的方法研究了选矿药剂与矿物间的作用机理，研究表明：脂肪酸捕收剂G-4对胶磷矿的捕收作用是以化学吸附为主、化学吸附与物理吸附共同作用的结果；胺类阳离子捕收剂GE-609在石英表面的吸附属于静电物理吸附，但很难用水洗的方法使GE-609从石英表面脱附；S-721主要成分为萘酚磺酸与甲醛的缩合物，萘酚磺酸与甲醛的缩合物对白云石表面Mg~(2+)的吸附明显强于对胶磷矿表面Ca~(2+)的吸附，这是胶磷矿与白云石分离的根本原因；水玻璃溶液中对石英起抑制作用的主要组分是HSiO_3~-和H_2SiO_3胶粒，水玻璃除对石英起抑制作用外，对矿浆还具有一定的分散作用。

The new opinion and mechanism that the simultaneously adsorption of complex pollution of both organic and heavy metals will be achieved on soil modified with amphoteric surface modifying agent, which have both charged group and organophilic group on one ASMA molecule, were proposed at first time, and its rationality was testified at the same time; The 50% was the critical CTMAB modifying ratio of soil CEC at which the organophilic bond modifying mechanism was emerged; The thermodynamic characteristics of adsorption of OPT and HMP on OMS were discovered ; The study revealed the surface peculiarity of OMS that the modifying agent were distributed at uneven scatter mode and multi-characters surface were coexisted on surface of OMS, revealed the adsorption peculiarity of OMS that multi-mechanisms were coexisted, confirmed the unequal charge amount modifying mode of OMS in which dual-modifying mechanism of both ion exchange and OPB were processed at the same time, and confirmed that the adsorption hobby to CTMAB was higher than that to Ca2+ on Lou soil.

首次提出了用两性表面修饰剂对土壤进行修饰改性，利用两性表面修饰剂所具有的荷电基团和疏水基团达到对土壤中有机、重金属污染物同时吸附的思路和机理，并通过实验证实了所提设想的合理性；发现了土壤CEC值的50%修饰比例是CTMAB开始显现以疏水键机制对土土样表面进行修饰的临界点；揭示了有机修饰改性土对有机物、重金属吸附过程的热力学特征，填补了该项研究工作的空白；阐明了修饰剂在改性土表面呈分散态的非均匀分布，改性土表面具有不同性质表面共存的表面特征和对污染物多机制共存的吸附特征，确定了阳离子表面修饰剂在土表面的修饰是一种离子交换和疏水键结合两种机制相伴并行且为非等电荷量交换的修饰反应模式，以及土具有对CTMAB的吸附偏好性远大于对钙离子吸附偏好性的特征。

After the cell growth curves was recorded, RPE cells of the 3-5th passages were utilized. 2、Three different siRNA (siRNAl,siRNA2,siRNA3) targeting against human cx43 gene and one negative control siRNA were designed and transfected into cultured human RPE cells via liposome reagent. The most effective siRNA can be determined by semi-quantitative reverse transcription PCRRT-PCR. 3、To the most effective siRNA, after transfected into human RPEs with different concentration, the cellular proliferate activities were messured by MTT colorimetry ; the percentages of RPE in different cell circle phase was assayed by FCM; the changes of phenotypical properities were observed with SCM; the protein expression of cx43 was studied through immunocytochemistry stain and Weston blot; the communication intercellular was calculated with FRAP; and the ability of recovery was assessed by using an in vitro wound healing model.4、The total proteins of siRNA1 and RPE were seperated by two-dimensional gel electrophoresis and visualized by silver staining. Proteins with significant expression alterations were selected and their peptide mass fingerprints (PMFs were obtained by matrix-assisted laser desorption/ionization time of flying mass spectrometry (MALDI-TOF-MS).The PMFs were used to search NCBInr database by Auto MS-Fit software.

实验方法：1、培养原代的人RPE细胞，经过细胞角蛋白、S-100和神经胶质原纤维酸性蛋白免疫细胞化学鉴定后，通过AO/PI染色技术确定培养细胞的存活率，描记其生长曲线，第3-5代用于以下细胞实验2、生物合成针对人cx43基因的三条小干扰RNA和一条阴性RNA通过脂质体转染RPE细胞后，通过RT-PCR的方法确定抑制效率最高的干扰片断3、将该片段以不同浓度通过阳离子脂质体转染培养的人RPE细胞后，采用MTT法观察其对细胞的增殖力的作用；通过流式细胞仪观察其对细胞周期的影响；通过扫描电镜观察其对细胞形态的影响；通过免疫细胞化学和Weston blot观察其对cx43蛋白表达的作用；采用激光共聚焦和荧光淬灭恢复技术观察荧光恢复速率平均百分率，评价其对细胞间通讯功能的影响；通过制作RPE细胞损伤模型，观察其对损伤修复能力的作用4、分离纯化转染siRNA的RPE组和正常对照组RPE细胞的全部蛋白质，应用等电聚焦电泳和SDS-PAGE双向电泳技术，银染显示分离出的蛋白质斑点，经凝胶图像分析软件对两个样本进行胶图分析，寻找差异蛋白点。

Correlation coefficient: 0.9962 . Positively charged'free'complex ions should be readily quenched by 〓, but when it is bound to DNA, it can be protected from the quencher because the highly negatively charged 〓 would be repelled by the negative DNA phosphated backbone, hindering quenching of the emission of the bound complex.

从理论上讲，带正电的配合物的阳离子应该可以被大阴离子淬灭，但是在DNA存在下，金属配合物插入到DNA的碱基对中，而〓被带负电荷的DNA磷酸骨架强烈排斥，从而避免了〓的淬灭，因此大的Stern-Volmer曲线斜率相应于对配合物较弱的保护形式。D。

In the results of the optical properties, these molecular monomers have different HOMO and LUMO energy gap such that there are dual-emission and energy transfer mechanism in solution fluorescence spectrum. In the study of the electrochemical properties, various of triphenylamine derivaties have different oxygen binding site and they make elecropolymerization happen or not. In the applications of the hole-transport materials, the performance of compound 21 is better than other compounds. The electropolymerized-film may have residual cation molecules so they can increase the concentration of hole-transport. Due to this reason , compound 21 is suitable to become hole-transport materials.

在光学研究方面，由於目标化合物内单体的HOMO及LUMO能阶差异，使得在溶液萤光放射上有双发射及能量转移的情形发生；在电化学研究方面，不同的三苯胺衍生物由於氧基的位置不同，使得取代基在间位的化合物有不错的电聚合效果；而元件的应用上，具有咔唑基团的化合物21由於在形成电聚薄膜后，可能有残余的阳离子态化合物，使得电聚薄膜内的电洞数浓度较高，因此与其他元件相比之下，有较低的启动电压和不错的元件效率。

The synergistic effect of Cu and Mn is listed as follows:(1) On improving the structure of rust layer, addition of Cu and Mn can reduce cracks and pores in rust layer;(2) On altering the composition of rust, it can increase the amount of Fe3O4 and γ-FeOOH, while decrease that of β-FeOOH;(3) On the chemical state of alloying elements and selectivity of rust layer, it mainly convert the anion selectivity to canoed selectivity;(4) On the electrochemical aspect, it can decrease the anode current density and increase the corrosion potential of steel.

Cu、Mn的协同作用主要体现在以下几个方面：在改善锈层结构方面，主要是减少锈层中的裂纹与孔洞，提高锈层与基体的结合强度；在改变锈层组成方面，增加Fe3O4和γ-FeOOH的含量，降低β-FeOOH的含量；在元素化学状态与离子选择性方面，促使锈层由阴离子选择性转变为阳离子选择性，抑制Cl-的渗透；在电化学方面，大幅度降低阳极电流密度，提高钢基体的自腐蚀电位。

Results show that acid value of carboxylic wood powder from alkaline hydrolysis is higher,but its yield is lower than that from acid hydrolysis. The adsorption capacity of carboxylic wood powder for basic pink dye increased with increase of the initial concentration of the adsorbate,and could be kept over 500mg/g after repeated use and regeneration for 4 times.

实验结果表明：（1）在适量引发剂（FeSO4 * 7H2O=1g）和适当温度（60℃）作用下，可得到较高接枝增量和接枝率的PANW；（2）在PANW的水解反应中，在碱性催化剂作用下，可得到羧基含量高的产物，但收率较低；而在酸性催化剂作用下，则得到羧基含量低的产物，但收率较高；（3）羧基木粉对阳离子型染料--碱性桃红的吸附容量与起始浓度有关，本实验中，羧基木粉对碱性桃红的吸附容量最高可达500mg/g，对Cu2+的吸附容量最高可达39mg/g；（4）经0.3mol/LHCl再生4次后，羧基木粉对碱性桃红的吸附容量保持在440mg/g以上，在含有多种金属离子的溶液中，羧基木粉优先吸附Fe3+等硬酸型离子。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。