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The invention relates to a method for making oligomeric isocyanates by reacting diisocyanates in the presence of a catalyst, wherein the catalyst comprises a saline compound prepared from an anion selected from 1,2,3- or 1,2,4-triazole, a substituted species of 1,2,3- or 1,2,4-triazole and carbocyclically and/or heterocyclically annellated species of 1,2,3- or 1,2,4-triazole and the cation selected from an alkali metal, alkaline-earth metal and/or monovalent ammonium cation and/or phosphonium cation of formula (5), wherein the E, R1, R2, R3, R4 are as defined in the descriotion.

本发明涉及一种制备低聚异氰酸酯的方法,包括二异氰酸酯在催化剂的存在下进行反应,其中所述催化剂由盐化合物组成,该盐化合物由选自1,2,3-或1,2,4-三唑、1,2,3-或1,2,4-三唑的取代系列者、1,2,4-三唑的碳环稠合系列者、1,2,3-或1,2,4-三唑的杂环稠合系列者的化合物及其混合物的阴离子和选自碱金属、碱土金属和/或通式(5)的一价铵阳离子和/或磷友衾胱拥难衾胱又票福其中E、R 1 、R 2 、R 3 和R 4 如说明书中所定义。

Each starch reagent has its own mode of action on mineral surface, such as primary starch mainly by hydrogen bond, cationic starch by the co-action of hydrogen bond and electrostatic force (for minerals with negative charge on its surface), while carboxymethyl starch, hydroxamic acid starch and dialdehyde starch principally by chemical force accompanied with hydrogen bond and electrostatic force in part. Such chemical forces ensure the close adsorption of reagent on diaspore surface and enforces the hydrophilic of mineral surface. Also the branched chain enable the starch to cover the collector adsorbed on mineral surface, so as to depress diaspore furthermore.

不同淀粉药剂在矿物表面表现不同作用,原淀粉主要是氢键的作用,阳离子淀粉是氢键和静电力的共同作用,羧甲基淀粉、羟肟酸淀粉和双醛淀粉离子性药剂与矿物间的作用除了氢键、静电力外,更重要的是与矿物表面金属离子间产生的化学作用,使药剂能牢固地吸附在一水硬铝石矿物表面,增加矿物表面的亲水性,同时,淀粉支链结构的存在,使它能够掩盖吸附的捕收剂,达到抑制一水硬铝石的目的。

The present work solves the ELD problem with Lineflow constraints through effective appli- cation of GA, considering the system transmission losses, power balance equation as the equality constraint, limits on the active power generations of the units and limits on currents in different lines as the inequality constraints. Two test systems, i.e.

目前的工作,解决了在ELD 问题lineflow的限制,通过有效的应用-阳离子遗传算法,考虑到该系统的传输损耗,权力的平衡方程作为等式约束,限制,有源电力几代人的单位和限制电流在不同的线路( lineflow限制)作为不等式约束。

Results showed that casein could be completely removed of by adjusting pH 4.6 and centrifuging at 1100g.β-lactoglobulin was absorbed by the cation-exchange resin eluented by phosphate buffer. Through limiting the quantity of acid whey, the purity concentration percent of immunoglobulin was above 80% determined by SDS-PAGE. The ratio of activity of immunoglobulin losing decreased in simulated pepsin and the residual immunoglobulin content percentage was about 80% in 60 minutes.

实验结果表明:调节脱脂牛初乳pH=4.6采用1100g低速离心即可达到完全去除酪蛋白的良好效果;利用含有磷酸根基团的缓冲液处理阳离子树脂柱会专一吸附酸性乳清中的β—乳球蛋白,达到分离乳清中免疫球蛋白与β—乳球蛋白的良好效果,控制乳清样品处理量可使免疫球蛋白纯度达到80%以上;微胶囊化的免疫球蛋白可以延缓胃液对免疫球蛋白的消化分解,减缓免疫球蛋白活性损失速率,在60分钟内仍可保留80%的活性。

In every group, rabbits were subdivided into experimental and control subgroups. 2 Rabbits were bullets injected followed by continuous injected with 13C labeled leucine, glucose, and lactic acid; 3 Blood were drewed before and 150, 160, 170, and 180 min after the initiation of isotopes injection for material analysis; 4 Exhale gas were collected every 5 min in the first 30 min followed by every 30 min there after for material analysis; 5 After centrifuge in low temp the supernatant of the blood samples were collected and went through axon and anon exchange column treatment; 6 Treated blood sample was used for 13C labeled leucine, glucose lactic acid examination through mass spectrograph; 7 The exhale gas was collected for 13CO2 exam through gas-phase mass spectrograph; 8 CO2 total production rate (V13CO2), body various substances production, oxidation speed, and substances metabolic percentage all can be calculated through equations provided by references below; 9 Data was processed through student t test.

分亮氨酸、葡萄糖和乳酸三组各取健康新西兰兔16只,每组再分为高代谢脓毒症组和对照组两部分,建模方法同第一部分;2)三组分别先静脉弹丸式推注再持续灌注13C标记的亮氨酸、葡萄糖和乳酸;3)灌注前抽取动脉血作为背景值,灌注达150,160,170和180min分别抽取动脉血2ml用于质谱分析;4)实验开始后前30min中每5min收集呼出气一次,随后每30min收集呼出气一次,用于气相质谱分析;5)血样经过低温离心取上清液,过阳离子及阴离子交换树脂,再经衍生化处理;6)处理过的血样进入气相色谱-质谱仪,测量其13C标记的亮氨酸、葡萄糖和乳酸丰度;7)实验兔的呼出气通过13CO2气相质谱分析仪测定其中的13CO2丰度(E13CO2);8)利用文献提供的公式算出CO2总生成率(V13CO2)以及机体各物质的通量、氧化速率以及物质代谢百分比等;9)数据分析处理采用t检验。

In this paper,the geographical distribution,profile shape and char- acteristics of major soil types such as the young brown earth,brown earth and meadow brown earth in the eastern low-mountain and hilly region and the meadow soil,saline meadow soil and paddy soil in the western plain region in Haicheng county of Liaoning Province are diseribed;the primary physico-chemical properties,organic matter,total nitrogen,total phosphorus,total potassium,total exchange of positive ions,the content of.01 physical cl...

本文叙述了海城县东部低山丘陵区的棕壤性土、棕壤、潮棕壤和西部平原区的草甸土、盐化草甸土及水稻土等主要土壤类型的地理分布、特性、剖面性态;论述了这些土壤类型的主要理化性质,有机质、全氮、全硷、全钾、阳离子代换量、。01物理性粘粒含量等及微量元素的含量、丰缺程度。根据主要土壤类型的性质和特点,作者提出了棕壤、草甸土两大土类的合理利用意见及其改良措施。

The acidic composition can be prepared by mixing a monovalent or polyvalent cation and an organic acid in the presence of a strong oxyacid, wherein the resultant acidic composition is less corrosive to a ferrous metal than a solution of a mineral acid having the same acidic pH value as that of the acidic composition, and where in the acid composition is more biocidal than a mixture of the organic acid and a metal salt of the organic acid which mixture has the same acid normality value as that of the acidic composition.

所述酸性组合物可以在一种强羟基酸存在时,通过混合单价或多价阳离子和有机酸来制备,其中与具有相同的酸性pH值的无机酸溶液相比,所形成的酸性组合物对含铁金属的腐蚀性更小,并且与具有相同酸当量值的有机酸与有机酸金属盐的混合物相比,所述的酸组合物具有更强的杀生物作用。

And the mechanism of ATRP is discussed from the view of complex-catalytic reaction. It is deduced that the active center in ATRP is not pure radical but complex active center, which maybe a complex with radical and complex ion. The structure of active center may have a "bridge"structure formed through propaganating radical and transition metal ion, and the active center exists in a"cage"generated by ligand-transition metal ion-organic halide and monomer or solvent.

论文运用基团贡献理论对一些实验现象和结果进行了讨论和分析,并结合研究结果对络合催化引发原子转移自由基聚合反应的机理进行了初步的探讨,认为:过渡金属化合物与有机配体参与的络合催化引发原子转移自由基聚合反应中,聚合反应的活性中心不是纯粹的自由基活性中心,而是与过渡金属相结合的、有着某种"笼"结构存在的复合式活性中心,同时该活性中心以自由基特性为主,同时兼具某种程度的其它活性中心特征(如阳离子和络合聚合活性中心)。

At the heavy metal concentration of 3-4ppm, our study on adsorption capacity, adsorption selectivity of montmorillonite, illite and kaolinite to Cu〓、 Pb〓、 Zn〓、 Cd〓、 Cr〓 shows that the adsorption capacity is mainly determined by the capacity of exchangeable cations and the adsorption capacity of the three clay minerals decreases in this sequence: montmorillonite >> illite>kaolinite. It is found that clay minerals have obvious adsorption selectivity to various heavy metals. Montmorillonite exhibits a stronger affinity to Cr〓 and Cu〓 while kaolinite and illite sorb Cr〓 and Pb〓 more effectively. At the same heavy metal concentration, adsorption amount of clay minerals to heavy metals increase with increasing pH value of the solution.

在痕量浓度下,研究了蒙脱石、伊利石、高岭石三种粘土矿物对Cu〓、Pb〓、Zn〓、Cd〓、Cr〓五种重金属离子的吸附容量、吸附选择性及其介质条件对吸附量的影响,结果表明,粘土矿物的阳离子交换容量越大,对重金属离子的吸附容量也越大,其大小顺序为蒙脱石>>伊利石>高岭石;同时,不同粘土矿物对重金属离子具有明显的吸附选择性,蒙脱石对Cr〓和Cu〓有较好的选择性,伊利石和高岭石则对Cr〓和Pb〓有较好的选择性;随着吸附溶液pH值的增大,其吸附量有增加的趋势。

We study the phase-separation and microstructure of the pure binary and trinary mixed LB and LS films of Dimyristoyl phosphatidyicholine cholesteroland sphingomylin deposited from pure water subphase by π-A isotherms and tapping mode Atomic Force Microscopy.

在本章中我们用这种极易溶于水的阳离子型聚合物PEI为一软垫,研究以此软垫为基底的不同生物分子和它们不同种二元及三元混合单分子膜体系在含PEI亚相上的相结构情况,初步的讨论了它们以云母为基底的IS膜和LB膜的微结构或者说是该软垫对单分子膜微结构的影响。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。