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The purity of SAM product was higher than 95%, and the overall recovery of SAM sulfate and SAM double salt of sulfate and p-tosylate were 60% and 50%, respectively.

通过筛选,获得了对SAM有较好选择性离子交换能力、较易洗脱和再生的争光D113弱酸型阳离子树脂,研究了温度、pH等对SAM离子交换的影响,根据SAM在弱酸阳离子树脂D113上的等温交换平衡行为表现出较强的可逆性,考虑到交换基的弱电解质性质以及结合Donan膜平衡理论,建立了考虑pH影响的可逆离子交换平衡模型,该模型可以较好地描述SAM平衡浓度、pH对离子交换平衡的影响;通过对动态离子交换过程的研究,得到了SAM在D113树脂内的有效扩散系数的数量级为1.0E-9cm〓/s~1.0E-8cm〓/s。

It is interesting that (1)hyperconjugation of the solvent's CF3-donor group prefers H4/H5 of BMI cation to H2, which can be explained by the steric hindrance of PF6 anion;(2) the various-temperature 19F spin-lattice relaxation times (T1) of CF3 show phase change, e.g.

藉由分析阳离子和三氟乙醇的扩散速率求得DD值,可以看到改善在乙醇形成大的基团,产生较强的分解,三氟乙醇的性质利用19F、1H化学位移,得到(1)CF3和阳离子H4、H5形成超共轭大於对H2,因为立体效应的关系,而藉由19F迟缓时间的数据,三氟乙醇展现相变化,由一到两各堆叠的离子对,和一个阴离子形成超阴离子的情形,因为溶剂而开始崩解,在继续分解可得到自由的阴阳离子。

However,the removal of soil noncrystalline aluminum with DCB soultioncaused an obvious decrease of soil SSA.3.The hydroxy aluminum in the interlayer of 1.4nm intergrade mineralhad an important negative effect on the cation exchange capacity ofsoil colloids.Its removal would cause a significant increase in CEC valuesof the soil colloids.4.Free aluminum was the major carrier of phosphate adsorption of soilcolloids.Particularly,the active aluminum had a decisive effect on thecapacity of phosphate adsorption of soil colliods.5.Addition to the effects of other soil constituents on soil surfaceproperties,it was thought that the effect of soil free aluminum,especially active aluminum on soil surface properties,deserved closeattention.

焦磷酸钠、草酸铵、DCB、柠檬酸钠和NaOH提取的土壤铝对提高土壤CECv、AEC、PZC和PZNC起重要作用,尤以活性铝的作用较大。2)用草酸铵处理除去铝后,土壤比表面积变化不大或略有增加;用DCB处理除去土壤铝后,土壤SSA明显降低。3)层间羟基铝对土壤胶体的阳离子交换量有显著负贡献,用柠檬酸钠将之除去后,土壤胶体的阳离子交换量明显增加。4)土壤胶体中的游离铝是土壤胶体吸附磷的主要载体,尤其是其中的活性铝,对土壤胶体的磷吸附能力起决定性作用。5)除其它土壤组分对土壤表面性质的影响外,土壤中的游离铝、尤其是活性铝对土壤有关表面性质的影响,值得引起特别的重视。

There are some isoforms of PAPs showing inhibitory ability to virus infection in various organs and at different stages of development. Three different species of the protein can be isolated from leaves of pokeweed (PAP, PAPⅡ and PAPⅢ). Proteins were precipitated with 50-80% ammonium sulfate from leaves in spring, summer and autumn respectively. Proteins were purified on SP cation-exchange then on MQ anion-exchange and finally on MS cation-exchange or on MQ anion-exchange. We found that some new pokeweed antiviral proteins separated from these leaves were different from PAP, PAPⅡ and PAPⅢ.

对美洲商陆春季、夏季、秋季采集的叶片,用50-80%饱和度硫酸铵沉淀出来的蛋白样品,经过SP阳离子柱后,上MQ阴离子柱,然后把活性蛋白峰再上MS阳离子柱或MQ阴离子柱分离,从春季叶片中分离出四个不同的抗病毒蛋白峰;从夏季叶片中分离出二个不同的抗病毒蛋白峰,这两个蛋白峰与春季叶片中分离出的活性蛋白峰都能重叠上;但从秋季叶片中只分离出来一个抗病毒蛋白峰,它和春季、夏季叶片中分离出的活性蛋白峰都重叠不上。

The Mo center of [Mo8](superscript 4)-shows a slight distorted square antiprism coordination environment. The N atoms of cyano groups, acting as acceptors of hydrogen bonds, together with protonate N atoms from organocations and the lattice water, serving as donors of hydrogen bonds, form intricate hydrogen bond interactions, thus generating three-dimensional supramolecular network with the help of π-π interactions of some organocations.

Mo8(上标 4-)离子中,Mo中心处于扭曲的反四棱柱配位环境。8个未配位的氰基氮原子作为氢键的受体,有机阳离子上质子化的氮原子和结晶水作为氢键的给体,形成了丰富的氢键作用,这些氢键作用连同部分有机阳离子间的π-π堆积、阴阳离子间的静电力和Van Der Waals力构筑成三维超分子网络。

Organic and compound cation garrulous coagulates the agent is to use chemical law compound a kind of new-style cation garrulous coagulates agent, belong to domestic and international initiate, with other and groovy drug photograph comparing has 5 big advantages: The photograph such as aluminium of as aggregate as commonly used drug chloridize, aggregate and vitriolic iron, vitriolic aluminium is compared, coagulate with garrulous of polypropylene acyl amine the agent is used jointly, medical dose is little, reduce useless water treatment to expend about 20 % thereby, 30 %; Effect of processing liquid waste is good, garrulous is round settling speed is fast, make liquid waste can second birth is used, managing water natural resources; Its garrulous group is sedimentary filterability can be good, slime can reclaim inside entire plant, namely energy-saving be helpful for protecting an environment again; Corrode to equipment small; Have muti_function, have agglomeration effect already, again garrulous coagulates action and the action that aid filter, can serve as filter aid.内容来自www.ch-water.com

有机复合阳离子絮凝(使液体中悬浮微粒集聚变大或形成絮团,从而加快粒子聚沉,达到固-液分离的过程)剂是利用化学法合成的一种新型阳离子絮凝(使液体中悬浮微粒集聚变大或形成絮团,从而加快粒子聚沉,达到固-液分离的过程)剂,属国内外首创,与其他常规药剂相比具有五大优点:与常用药剂聚合氯化铝、聚合硫酸铁、硫酸铝等相比,与聚丙烯酰胺类絮凝(使液体中悬浮微粒集聚变大或形成絮团,从而加快粒子聚沉,达到固-液分离的过程)剂联合使用,药剂量少,从而降低废水处理(通过物化方法去除水中一些物质的过程)费约20%—30%;处理废水效果好,絮团沉降速度快,使废水能再生利用,节约水资源;其絮团沉渣过滤性能好,煤泥可全部厂内回收,即节能又有利于保护环境;对设备腐蚀小;具有多功能,既有凝聚作用,又有絮凝(使液体中悬浮微粒集聚变大或形成絮团,从而加快粒子聚沉,达到固-液分离的过程)作用和助滤作用,可作为助滤剂。

A chromium free conversion coating at least equivalent in corrosion protective quality to conventional chromate conversion coatings can be formed on metals, particularly cold rolled steel, by a dry-in-place aqueous acidic liquid comprising: a component of anions, each of said anions consisting of at least four fluorine atoms and at least one atom of an element selected from the group consisting of titanium, zirconium, hafnium, silicon, and boron, and, optionally, ionizable hydrogen atoms, and optionally, one or more oxygen atoms; a component of cations of elements selected from the group consisting of cobalt, magnesium, manganese, zinc, nickel, tin, zirconium, iron, and copper; the ratio of the total number of cations of this component to the total number of anions of component being at least 1:5; sufficient free acid to give the composition a pH in the range from 0.5 to 5.0; a component selected from the group consisting of phosphorus-containing inorganic oxyanions and phosphonate anions; and a component selected from the group consisting of water-soluble and water-dispersible organic polymers and polymer-forming resins and, preferably, also including a component selected from the group consisting of tungstate, molybdate, silicotungstate, and silicomolybdate anions.

通过对包含以下成分的含水酸性液体进行干燥,可以在金属上形成无铬的转换涂层,该涂层与普通铬酸盐转换涂层相比,至少在抗腐蚀质量上等效:$_一种阴离子成分,所述各个阴离子包括至少4个氟原子,至少选自钛、锆、铪、硅与硼元素中的1个原子。任选地可离解的氢原子,任选地1个或多个氧原子;$_一种选自钴、镁、锰、锌、镍、锡、锆、铁与铜元素的阳离子成分,上述成分的阳离子总数与成分内的阴离子总数之比至少为1∶5;$_足够的游离酸以使该组合物的pH值在0.5~5.0的范围内;$_一种选自含磷的无机含氧阴离子与膦酸盐阴离子的成分;$一种选自水溶性与水可分散性有机聚合物与聚合物形成的树脂的成分,优选还包括一种选自钨酸盐、钼酸盐、钨硅酸盐与钼硅酸盐阴离子的成分。

Viral vector mainly contain adenovirus, retrovirus,adeno-associated virus and so on, but it has potential danger of safety; it isrepeled by immune system when it is injected to organism for a greatimmunogenicity. An injection with adenovirus vector with highconcentration, it leads to serious inflammatory reaction of liver. Viralvector such as liposome and polycation are commonly used lately. But,liposome and polycation have low specificness and targetness of genetransfer tissue, have lower transfection efficiency and short period ofgene expression, for they can be phagocytized by endothelial system.

许多的载体,病毒载体和非病毒载体以前已广泛应用,病毒载体主要包括腺病毒,逆转录病毒,腺相关病毒等;但病毒载体在安全性方面存在潜在的危险;免疫原性比较强,注射到机体后很快会被机体的免疫系统排斥,当静脉注射高浓度的腺病毒载体会使肝脏发生严重的炎症反应;非病毒载体目前常用的有脂质体及多聚阳离子聚合物;但脂质体和阳离子聚合物介导基因转移缺乏组织的特异性和靶向性,转染效率较低且易被网状内皮系统吞噬,基因表达时间短;因此研制新型的非病毒载体已成为研究的热点,纳米颗粒具有小尺寸效应,表面效应,随着颗粒直径变小,比表面积将会显著增大,故具有很高的化学活性,因而纳米成为了最有应用前景的非病毒载体。

The humidity resistance and the sensitivity to chemical warfare agents simulants of the tuned films were also investigated.Self-assembled LBL polyaniline films were prepared from aniline monomers by in situ polymerization and the mechanism of film formation was discussed. It was proposed that the self-assembly of polyaniline occurred through the quick absorption of aniline monomer cations or aniline monomer cation radicals on the glass surfaces by electrostatic attractions to form homogeneous polymerization centers, then increased gradually by the way of upright to the glass supports for extensity, leading to the polyaniline chain growth. The polyaniline was doped under acidic condition to absorb anionic polyelectrolyte, such as sodium polystyrene sulfonate based on the electrostatic force, or to adsorb polymer based on hydrogen-bonding interactions, for example Polyvinyl Alcohol, and then recycled to fabricate_n or_n self-assembled multilayer films.

跟踪了原位聚合的具有纳米结构的聚苯胺多层自组装膜的成膜过程,提出了该自组装膜的成膜机理:聚合反应初始阶段的苯胺阳离子或苯胺阳离子自由基通过静电作用快速吸附到带负电荷的基片表面,形成均匀的聚合中心,然后以垂直于基片的方式进行链增长生成PANI;PANI在酸性条件下经现场掺杂后带正电荷,再通过静电作用吸附带负电荷的聚电解质如聚苯乙烯磺酸钠,或通过氢键作用吸附聚合物如聚乙烯醇,这样循环LBL-SA即得到_n或_n等原位聚合聚苯胺自组装膜。

Based on these results, it is reasonable to assume that cationic surfactant could form well-stabilized films on the surface of partially hydrated polyacrylamide solution, as a result a kind of surface active complex was formed between cationic surfactant and HPAM.

总之,本论文系统研究了阳离子表面活性剂和不同水解度的聚丙烯酰胺之间的相互作用,发现阳离子表面活性剂能在HPAM水溶液表面成膜,这和表面活性剂的HLB值有关,还与HPAM的水解度以及溶液的pH值有关;两者之间的静电引力是主要驱动力,这一过程又被表面活性剂链之间的疏水相互作用所增强。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。