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Compared with the conventional catalyst, the complex catalyst improved methanol anodic oxidation activity by 46 percent. The reason that it deceases the activation energy for the methanol and its ramification electro-oxidation reaction was estimated to be its special complex Keggin structure.

测试表明该添加剂降低了甲醇及其电氧化中间产物转化的活化能,改善了电极内部的质子传输状况,对甲醇的电化学氧化过程具有明显的促进作用,该复合催化剂与常规的Pt-Ru/C催化剂相比,甲醇的阳极氧化电流提高了46%。

The study aims at the performance of a proton exchange membrane fuel cell with interdigitated flow field ,its influencing factors and feasible ways to improve it.

为研究交指流场质子交换膜燃料电池的输出性能,分析影响其性能的因素,寻找改善其性能的可行措施,探讨了使用交指流场流道的必要性和优越性,建立了包括质子交换膜燃料电池阴极/阳极侧流道、扩散层和催化层以及质子交换膜在内的完整的稳态、三维、两相数学模型。

The study aims at the performance of a proton exchange membrane fuel cell with interdigitated flow field, its influencing factors and feasible ways to improve it. The necessity and advantages of using interdigitated flow field were introduced. A three-dimensional, two-phase and steady-state numerical model was developed. The computational domain of the model consists of the flow channels, gas diffusion layers and catalyst layers in both anode and cathode sides and the PEM in PEM fuel cell.

为研究交指流场质子交换膜燃料电池的输出性能,分析影响其性能的因素,寻找改善其性能的可行措施,探讨了使用交指流场流道的必要性和优越性,建立了包括质子交换膜燃料电池阴极/阳极侧流道、扩散层和催化层以及质子交换膜在内的完整的稳态、三维、两相数学模型。

The dynamical processes of the nucleation and propagation of stress corrosion cracking of four low alloy steels with a wide range of tensile strengths in aqueous media with various polarization conditions, in a K_2Cr_2O_7 inhibitor solution and in some organic solvent such as acetone and alcohol were traced with an optical microscope.

用抛光的恒位移试样跟踪观察了具有广泛拉伸强度范围的四种低合金钢在各种水溶液中(高纯水、阳极极化和阴极极化下的水溶液,0.1NK_2Cr_2O_7水溶液)以及含痕量水的有机溶剂中应力腐蚀裂纹产生和扩展的动态过程。

The results showed that the two kinds of Ni-P electroless deposits are both amorphous. The phosphorus content in the deposit using lactic acid as complexing agent is 10.04%, and in the deposit using citric acid as complexing agent is 11.93%. As the Na2S content increases, the polarizability increases, and the corrosion current and corrosion potential decrease while the Na2S content is between 1.0%~2.5%. The corrosion resistance of Ni-P electroless deposit using lactic acid as complexing agent is better than that of another kind.

结果表明,利用两种络合剂形成的Ni-P镀层均为非晶态,其中以乳酸为络合剂的镀层中P含量为l0.04mass%,以柠檬酸为络合剂的镀层中P含量为11.93mass%,在1.0%~2.5% Na2S多介质中,随着Na2S多含量的增加,阳极极化曲线的极化率增大,自腐蚀电位和自腐蚀电流降低。

Experimental and practical researches of impurity distribution activities and common effect, and analysis on the removing and distribution activity of the impurities in the Guixi Smelter anode copper like As Sb and Bi and the forming structure and conditions of the flotating anode slime have been done.

很久以来,许多从事冶金或相关专业的研究人员,对As、Sb、Bi、Pb等杂质在铜电解精炼过程中的行为进行了多项研究,如对存在形态和行为、阳极泥的形成机理,以及对阴极铜质量的影响进行了一系列的探索研究,并取得了可喜的科研成果。

Anodising reaction proceeds in the sequence of growth of porous anodic alumina when the aluminum layer is consumed up to the underlying metal, and the growth of metal oxide under the bottoms of the alumina pores occurred simultaneously.

以电化学的方式在阳极产生氧化铝孔洞的同时,底层的金属同时被氧化而在孔洞底端成长出奈米点。以草酸、硫酸和磷酸不同的电解液和不同施加电压下观察奈米点的阵列。

The formation of the striations was affected by the combination effect with the distribution of spatial potential and surface charge on the anode surface, especially the distribution of electron charge on the anode surface would greatly influence the structure of striations.

条纹现象的形成是由阳极表面附近的空间电势分布和表面电荷分布共同作用产生的,特别是表面的电子电荷分布对条纹现象的影响很大。

The different deposition behaviors were dependent onpH of solution, mixed potential of redox couple, dissolution rate of silicon, complexformation and equilibrium potential of metal ion.

不同的沉积行为取决于溶液的pH值、体系的混合电位、硅的阳极溶解速率、金属离子的络合状态和还原电位。

Contents of Zn, Cu, Cd and Pb in Shell of oyster and offshore water from Dalian gulf, Laohu beach, Fujia Zhuang beach, Lingshui bay, Lvshun and Jinzhou are studied by Anodic Stripping Voltammetry in order to establish a relationship between offshore seawater and heavy metal content in shells. Through monitoring the seawater and shells we researched whether the shells could replace the soft tissue of oyster shells as an indicator of marine environment changes in hope of finding a more convenient and accurate carrier for monitoring marine heavy metal.

本论文以大连湾、老虎滩、付家庄、凌水湾、旅顺及金州六个区域的近岸海水及牡蛎贝壳为研究对象,应用阳极溶出伏安法对其锌、镉、铅、铜的含量进行分析,旨在通过监测大连近海水域及贝壳重金属含量来研究二者的相关性,探索是否可以利用贝壳替代贝类软组织来指示海域环境的变化情况,从而找到一种更为简便、更为可靠的监测海洋重金属的载体。

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