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Current density, anolyte acid and concentration of SO42 in anolyte are notable factors influencing the current efficiency, oxidation rate and cell potential.

通过均匀设计的电解条件试验得出:电流密度、阳极液酸度和阳极液硫酸根浓度为影响电流效率、氧化率和槽电压的显著因素。

It was found that cyclohexanol was oxidized by NiOOH generated with further electrochemical oxidation of nickel hydroxide during the anodic potential sweep.

结果表明,镍电极在阳极扫描过程中产生的Ni_2发生进一步氧化,所产生的NiOOH能够有效的氧化环己醇。

In this process, the discharge process of single point to point contact is transformed to the process of both point to point contact and the overall surrounding contact of sphere Ni through the self redox reaction, thus making a highly efficient electron transfer process. In this dissertation, the catalytic electrolysis mechanism is discussed. The influence of various parameters (e.g. kind and concentration of catalyst, reaction temperature and electrolysis duration) on electrolysis were investigated.

本文首次提出了以KMnO_4为代表的高锰酸盐作为电解过程电子传递的媒介,通过锰盐自身氧化还原反应的参与,在阳极和溶液中的球形Ni_2之间建立起高效的电子转移过程,使球形Ni_2和阳极之间单一的固体之间的点点接触放电,转变为点点接触放电和球镍与溶液全方位包围接触放电过程,大大提高了电解过程的效率。

The main factor affecting the frequency characteristic were given as the following:the coefficient of corrosion of the Al foil surfaces the figure of the hole of scorrosion,and the character of the oxide film on the surface of the anode and cathode;the fabric of the unimpregnated liner in the capacitor,as well as the resistance and steeping of the working electrolyte and the construction of the capacitor.

影响频率特性的主要因素有:阴极和阳极铝箔表面腐蚀系数的大小及腐蚀坑洞的形状;阴极和阳极铝箔表面氧化膜的性质;电容器中衬垫纸的构造;工作电解液的电阻和浸渍情况以及电容器的内外结构尺寸等。

The invention relates to an electrochemical method for preparing ultra-fine tantalum powder, wherein it uses the mixture slat flux with CaCl2 or CaCl2 as electrolyte; composites Ta2O5 powder/block with metal collector as solid cathode; uses graphite or inertia anode as anode; uses reference polar to control the electrolysis level, under inertia gas to electrolyze at 500-1000Deg. C; and the electrolysis time should make electrolysis electricity reach needed amount; reduces Ta2O5 into ultra-fine metal tantalum powder.

本发明涉及一种超细钽粉的电化学制备方法,以CaCl2或者含有CaCl2的混盐熔体为电解质,将Ta2O5粉末或块与金属集流体复合作为固态阴极,以石墨或惰性阳极作为阳极,用参比电极控制电解电位在惰性气氛保护下进行电解,电解温度控制在500-1000℃,控制电解时间使电解电量到达到理论所需电量及以上,将五氧化二钽电化学还原为超细金属钽粉。

Results show that the adoption of stainless steel anode wrapped with anion membrane improves the bath stability and avoids the oxidation of manganous ions.

结果表明:采用不锈钢阳极和阴离子膜可提高镀液稳定性,防止二价锰被氧化,加入氢氧化钡可消除因补充锌锰离子而积累的硫酸根离子。

The anodization utilizes an electrolytic solution which etches out oxidized portion as soon as it is formed as a result of the anodization, to thereby develop a porous layer in a pattern in match with the anode pattern.

阳极化利用了电解液,一旦由于阳极化而形成氧化部分,电解液即蚀刻掉氧化部分,由此以与阳极图案相匹配的图案产生多孔层。

The degradation of aqueous phenol was the combination of direct discharging on anodes and indirect oxidation by active intermediate.

苯酚的降解是苯酚在阳极直接放电氧化和自由基间接氧化两种方式的结合。

Because of the disadvantages in the electrolysis of rare earth metals, a new kind of electrode material called non-carbon anode is studied, and the corrosion mechanism is reseached.

针对稀土金属Nd的氟化物体系熔盐电解中石墨阳极所存在的一系列不足,研制了一种新型的电极材料,称其为非碳阳极;并对其在电解过程中的腐蚀机理进行了较详细的探讨,提出了还原反应、氧化反应、电解质渗透、电极组分溶解、析氧膨胀等几种可能的腐蚀原因。

The sample's metal surface expanded and the thickness of oxide film is 1.72 times of the control samples.

摘要] 目的:分析烤瓷用镍铬合金在上瓷前经过阳极钝化,除气预氧化处理后对其表面氧化膜的形貌、厚度的影响。

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