阳极极化

Many kinds of modern techniques are used to characterize the obtained K_3Na(FeO_4)_2 sample.The preparation of ferrate by the anodic dissolution of an iron wire gauze at an average current density of 4.8 mA·cm~(-2) is described in the third chapter of this paper. The cyclic voltammogram and SEM are used to characterize the iron electrode polarization.

本文第三章研究了一种在浓NaOH溶液中电解铁丝网阳极快速电合成高铁酸钠的技术，用循环伏安和扫描电镜技术对电极的极化过程进行了表征，同时对电合成高铁酸钠的主要工艺参数之间的关系进行了阐述。

Cerium dioxide ultrafine powder is prepared by electrochemical method using composite coating of In-Ru-Ir as anode,cerous nitrate and ammonium nitrate as electrolyte.

以钛基钌-钇-铑涂层电极作为阳极，硝酸铈和硝酸铵作为电解液，电化学法制备二氧化铈超细粉体，用X射线衍射和透射电镜进行了表征，制备条件用正交实验设计进行优化；通过极化曲线，计算了电极过程动力学参数

In this thesis, the advantages and disadvantages of potentiodynamic polarization curve, electrochemical impedance spectroscope and coulostatic method for studying corrosion inhibitors in acidic mediums were compared. And then the effect of three popular acid corrosion inhibitors such as thiourea, dodecylamine and propargyl alcohol on the corrosion inhibition behaviors of Q235 steel in acidic solutions were investigated by these techniques. The anodic desorption behavior and extreme value phenomenon of concentration were surveyed thoroughly as well.

本文讨论了动电位极化曲线、电化学阻抗谱和恒电量测量方法在酸性介质缓蚀剂研究中的优势和不足，在此基础上，研究了硫脲、十二胺和丙炔醇等三种常见酸性介质缓蚀剂对Q235钢在酸性溶液中的缓蚀行为和机理，并深入探讨了缓蚀剂的阳极脱附和浓度极值现象。

The inhibition effects of di-(2-ethylhexyl)-sebacate on the corrosion behavior of reinforcing steel bar were investigated by electrochemical polarization curves and electrochemical impedance spectroscopy in simulated pore solution.

采用动电位极化曲线和电化学阻抗谱研究了癸二酸二异辛酯在模拟混凝土孔隙液中对钢筋的保护作用。癸二酸二异辛酯的加入导致混凝土钢筋的腐蚀电位正移，对钢筋的阳极电化学过程有抑制作用。

The electrochemistry polarization behavior of the mild steel that take rust makes clear, the corrosion product below dry wet loop accelerates cathode process, control zincous process.

带锈低碳钢的电化学极化行为表明，干湿循环下的腐蚀产物促进阴极过程，抑制阳极过程。

The efficiency of silver recovery and cyanide removal, as well as power consumption was discussed in terms of pulse voltage, pulse duty factor, and pulse frequency.

结果表明，脉冲电源较直流电源能更加有效降低阳极的超电位，减少电极的极化，从而降低槽电压，进而有效地降低电能消耗。

This excellent performance is attributed to the electrolyte's small ohmic resistance, small cathode polarization resistance, and favorable anode microstructure.

优良的电性能主要归功于小的电解质内阻和阴极极化电阻以及良好的阳极微观结构。

The main research work of this dissertation is as follows: Based on the chemical reaction engineering theory and the nitrobenzene electroreduction mechanism, the plate and frame electrolyzer was designed and applied to the process of electroreduction nitrobenzene to p-aminophenol. This dissertation measured the residence time distribution data of the electrolyzer by means of the pulse response method and studied the rule of flow pattern along with the current capacity change. Under different conditions ,this dissertation studied the cyclic voltammetry properties of nitrobenzene on different electrodes by means of the dynamic cyclic voltammetry method and the electrode materials applied to the NB electroreduction have been selected primarily.Baseed on the results of cyclic voltammetry tests, this dissertation used p-electrode systems to measure the steady-state- polarization curves of nitrobenzene on different electrodes in H-type diaphragm cell, and obtained each primary factor s influence rule and the exchange current density value of each electrode.And then on the basis of the conclusions of fundamental researchs upword, the effects of influence factors on the the yield of p-aminophenol and the current efficiency,such as electrode material, current density, quantity of electricity circulated, nitrobenzene concentration . sulpuric acid concentration and so on, have been studied in detail in the systems of hign temperature , strong acidity and oxygen-poorthrough a series of electrolysis experiments in this paper.After all using Pb as anode Monel metal as cathode Dupont Nafion 417 cation-exchange membrane as membrane, this dissertation obtained the optimum technological condition: reaction temperature about 85C, current density 500A m-2, sulphuric acid concentration 20%wt.

论文的主要研究工作为：运用化学反应工程理论，结合硝基苯的电还原机理，设计出用于硝基苯直接电还原合成对氨基苯酚实验的板框式电解槽，并利用脉冲响应法测定了该板框式电解槽的停留时间分布数据，研究了流型随流量变化的规律；通过动态循环伏安法研究了硝基苯在不同电极上、不同条件下的循环伏安特性，初步评选出了用于硝基苯电还原的电极材料；结合循环伏安的测定结果，在H型隔膜电解槽中采用三电极体系测定了硝基苯在不同电极上、不同条件下的稳态极化曲线，得到了各主要因素的影响规律及硝基苯在各个电极上电还原的交换电流密度数值；在基础研究结论指导下，采用板框式电解槽，在高温、强酸、贫氧系统中，进行了一系列的电解实验，分别考察了电极材料、电流密度、通电量、硝基苯浓度、硫酸浓度等因素对收率及电流效率的影响，最终选择以蒙乃尔合金电极作为阴极、铅合金为阳极、Dupont Nofion 417阳离子交换膜为隔膜，得到由硝基苯直接电还原制对氨基苯酚的最佳电解工艺条件：反应温度85℃，电流密度500A·m~(-2)，硫酸浓度20％wt。

Plunder melds and run with this jewel!

掠夺melds和运行与此宝石！

My dream is to be a crazy growing tree and extend at the edge between the city and the forest.

此刻，也许正是在通往天国的路上，我体验着这白色的晕旋。