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长石

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Through electron probe\'s analysis to the albite jade, union grinding sample thin slice under polarizing microscope observation as well as X powder crystal diffraction data analysis. Discovery like Chen zhenqiang and "System Gemology" said that secondary mineral for actinolite, green mudstone, epidote and quart.

通过对钠长石玉进行电子探针的分析,结合磨制的样品薄片在偏光显微镜下的观察以及X粉晶衍射数据分析,可知钠长石玉中的主要成分为钠长石,次要矿物为硬玉、角闪石、绿辉石、钠铬辉石;并未发现如陈振强等人以及《系统宝石学》中所说的次要矿物为阳起石、绿泥石、绿帘石、石英。

Plagioclase is a continuous solid solution series of albite anorthite, but its crystal structure is in continuous, which can be divided into several feldspar areas with different structure and attachment .

长石是钠长石-钙长石的连续固溶体系列,但在晶体结构上并不连续,可以划分成几种结构和连生不同的长石区。

Using the thin slice observation under the polarized microscopy, we have found that there are two existential ways for albite minerals in emerald: one is the first generation of albite which is earlier than jadeite or grows together with jadeite minerals; the other is albite of vein type which is formed by the hydrothermal fluid effect.

利用偏光显微镜下的薄片观察,发现翡翠中的钠长石矿物有两种存在方式:一种是第一个世代钠长石,其形成的时间早于硬玉或同第一世代的硬玉矿物一起生成,另一种为后期热液作用形成的脉状的钠长石

Slag test indicates that andalusite has no obvious effect on penetration. Slag penetrates along boundaries of bauxite or mullite. Al2O3 from bauxite dissolves into slag to form CA6, anorthite, gehlenite and other low melting phases which precipitate during cooling.

渣蚀试验表明,红柱石时侵蚀无明显影响,熟料液相沿莫来石和矾土骨料晶界向内渗透,氧化铝逐渐浓解与液相、渣中的氧化钙形成CA5和钙长石、黄长石等低熔相,在冷却过程中,钙长石和黄长石从液相中析出。

The author creates the AutomaticallyDiscriminational Model for the Classification of Sandstones System, thatis to say, people can complete the vastly sample s classification of sandstonesaccurately and swiftly, meantime, diminish the possibility of mortal mistake. Based on the study of the basic sandstone component before embedding, the typeof authigenic mineral, and the forming mechanism of porosity in Upper Paleozoicreservoirs in Ordos basin, the author selects the reasonable experiment objects forWater-Rock Interaction modeling study, designs the relatively reactant and resultantduring the diagenesis period, builds the solid-liquid thermodynamics model with theprinciple of thermodynamic phase equilibrium for kinds of primary minerals (potashfeldspar, albite, anorthite, and pyroxene, hornblende) which dissolve in acidic media,and forms the corresponding thermodynamics test database.

在对鄂尔多斯盆地上古生界储层砂岩埋藏前组成、自生矿物类型和孔隙构成研究的基础之上,确定合理的沉积盆地水—岩相互作用模拟研究的实验对象,设计了埋藏成岩过程有关反应的反应物和可能的生成物,并通过热力学相平衡原理,建立了碎屑岩在埋藏成岩过程中各种骨架颗粒(钾长石、钠长石、钙长石以及铁镁暗色矿物中的辉石、角闪石等)在酸性介质条件下发生溶解的固体—流体相化学反应热力学计算模型,并获得了相应的热力学数据库,在此基础上对储层砂岩中主要造岩矿物(钾长石、钠长石、钙长石以及铁镁暗色矿物中的辉石、角闪石等)在埋藏成岩过程的酸性介质条件下发生溶解的热力学习性进行了论述。

As a result, the author discusses the thermodynamics habitus for the minerals either. With the calculation of the thermodynamics modeling, we run the dissolutionmodeling experiments for primary minerals (potash feldspar, albite, anorthite, andpyroxene, hornblende), which is under the conditions of organic acidic and 20 varietytemperature and pressure. The dissolution modeling experiments include 4 anorthitedissolution experiments, 8 pyroxene dissolution experiments, 8 hornblendedissolution experiments. We catch the records on the X ray diffraction, chemistryanalysis, SEMphotos, and the PH parameters. By theway, we discuss the dissolution habitus for the minerals either.

在热力学模拟计算的基础之上,进行20个不同温度和压力条件下,以有机酸作为溶解介质的储层砂岩骨架颗粒(钾长石、钠长石、钙长石以及铁镁暗色矿物中的辉石、角闪石等)的水—岩相互作用的溶解模拟实验,包括:4个钙长石的溶解实验、8个辉石的溶解实验和8个角闪石的溶解实验,获得了溶解模拟实验前后全部参与实验矿物的X射线衍射分析、化学全分析数据、扫描电镜照片,以及介质流体在实验过程中化学参数pH值的检测,在此基础上讨论了铁镁暗色矿物、长石等铝硅酸盐矿物在埋藏成岩过程中酸性介质条件下的溶解习性。

The study shows that almost all the feldspar in the alkali-granite is perthite, the host-crystal is microcline, the chadcrystal could be either albiter or oligoclase. The Alkali-amphibole is either manganese-magnesia-arfvedsonite or arfvedsonite, and all the alkali-pyroxene is aegirine.

结果表明,该区富碱花岗岩几乎所有的长石均为条纹长石,主晶为微斜长石或高微斜长石,客晶为钠长石或更长石,碱性角闪石为含锰镁质钠铁闪石或钠闪石,碱性辉石均为霓石。

The feldspars of topaz-lepidolite granite in Yashan late stage are P-rich albite and Kfeldspar, and the phosphorus goes into feldspar structure in the form of PAlSi〓 substitution. The phosphorus contents of feldspars vary according to their crystal habitus. In general, the feldspars of later generation have the higher average phosphorus content than that of earlier generation, and the albite contains higher phosphorus than the K-feldspar in the same generation. The zircon is highly rich in Hf, U, P and Al. The phosphorus enters the zircon structure mainly by the form of〓P〓〓Si〓, Al〓P〓Si〓 or P〓Al〓Si〓, Zr〓 substitution. The P-rich zircon is the production of the highly evolved magma, and it might be one of the important characteristic minerals of the high-P subtype granite. The manganocolumbite, manganotantalite, wodginite and titanowodginite are the main niobium and tantalum minerals.

雅山晚阶段黄玉锂云母花岗岩的长石矿物是富磷长石,磷以PAlSi〓替换方式进入长石结构中,并且在长石中的分布很不均一,一般是晚结晶的长石比早结晶的长石的磷含量高,同期结晶的钠长石比钾长石的磷含量高;锆石矿物为高度富铪、铀、磷和铝的锆石,磷主要以(Y, HREE, Fe)〓P〓〓〓Si〓〓、Al〓P〓Si〓〓、P〓Al〓Si〓〓Zr〓〓等替换方式进入锆石晶格中,富磷锆石是岩浆高度演化的结果,是高磷花岗岩的特征矿物之一;雅山含有丰富的磷锂铝石,是高磷花岗岩的主要磷酸盐矿物;铌—钽矿物主要有铌锰矿—钽锰矿、锡锰钽矿—钛锰钽矿、细晶石等。

The experimental products include crystal phase quartz, feldspar (alkila-feldspar, albite, K-feldspar), zinnwaldite and topaz, a melt phase and a trace vapour. The solid products were been studied by optics method, electron microprobe and X-ray analysis. The results show that liquidus temperature raises slightly and solidus temperature falls down obviously and that the upper temperature limit raises for the stability field of quartz and topaz, and falls down for the stability field of alkila-feldspar as F contents in crease.

实验淬火产物包括结晶相石英,长石(碱性长石,钠长石、钾长石),铁锂云母和黄玉及玻璃相和微量流体,对固相淬火产物进行了系统和详细的显微观察及电子探针和x射线分析,研究了F对钠长花岗岩液、固相线温度、相关系和相组合的影响和含F钠长花岗岩的结晶序列和熔体演化、F在流体和熔体之间的分配及F对花岗质熔体结构的影响,对含黄玉矿物组合进行了一系列热力学矿物平衡计算,获得如下重要结论

This article mainly divides into three parts, The first part is the albite jade characteristic, uses traditional the gemology method conducts the research to the albite jade physical property as well as the structure, carries on the electron probe analysis to its chemical composition, and the discussion of its mineral component\'s chemical composition change carries on the SPSS statistical software; uses X powder crystal diffraction to determine its lattice parameter, mineral constituent\'s crystal structure conducts the research to the albite jade, carries on the analysis to the feldspar degree of order, and carries on the discussion to the albite jade\'s origin. The above method each other confirms mutually, confirms the data reliability.

本文主要分为三部分,第一部分为钠长石玉的性质,采用常规的宝石学方法对钠长石玉的物理性质以及结构构造进行研究,利用电子探针分析对其化学成分进行分析,并运用SPSS统计软件对其矿物成分的化学成分变化进行探讨;采用X粉晶衍射测定其晶胞参数,对钠长石玉中矿物组成的晶体结构进行研究,对长石的有序度进行分析,并对钠长石玉的成因进行探讨;上述方法彼此相互验证,以证实数据的可靠性。

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