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The reclaiming and recycling magnesium alloy were must taken into account and settled with exploiture of magnesium alloy.

本文概述了合金产业的动向和合金技术新进展。7。必须在开发合金的同时考虑和解决合金的回收和再生问题。

Third, most magnesium alcoholates are prepared by alcoholysis.The process is based on the exchange of alkoxide groups of a metal alcoholate in the presence of an alcohol other than the alcohol corresponding to the original alkoxide,i.e.on the alcoholysis of a metal alkoxide with a different alcohol. Primary alcoholates can be prepared by this process,such as magnesium di-n-propanolate,magnesium di-n-butanolate,magnesium di-isobutanolate.

该方法适用于较高沸点的伯醇的醇化合物,例如正丙醇、正丁醇、异丁醇等,但是用醇解法制备出的叔丁醇,其纯度只有80%,这是由于叔丁醇具有较大的空间位阻效应,阻碍了醇交换的进一步进行,并且叔丁醇沸点与甲醇相差不大,使得甲醇难以快速蒸出,只能得到一种混合醇盐产物。

Third, most magnesium alcoholates are prepared by alcoholysis.The process is based on the exchange of alkoxide groups of a metal alcoholate in the presence of an alcohol other than the alcohol corresponding to the original alkoxide,i.e.on the alcoho- lysis of a metal alkoxide with a different alcohol. Primary alcoholates can be prepare- d by this process,such as magnesium di-n-propanolate,magnesium di-n-butanolate,m- agnesium di-isobutanolate.

该方法适用于较高沸点的伯醇的醇化合物,例如正丙醇、正丁醇、异丁醇等,但是用醇解法制备出的叔丁醇,其纯度只有80%,这是由于叔丁醇具有较大的空间位阻效应,阻碍了醇交换的进一步进行,并且叔丁醇沸点与甲醇相差不大,使得甲醇难以快速蒸出,只能得到一种混合醇盐产物。

This paper presents the experimental data of metastable phase equilibrium of Na+, K+, Mg2+∥Cl-, SO2-4-H2O quinary system at 35 ℃, from which the metastable phase diagram is drawn. It consists of nine regions of crystallization saturated with sodium chloride, potassium chloride, glasserite(3K2SO4*Na2SO4), leonite(K2SO4*MgSO4*4H2O), kainite(KCl*MgSO4*2.75H2O), thenardite(Na2SO4), astrankit(MgSO4*Na2SO4*4H2O), carnallite(KCl* MgCl2*6H2O), magnesium sulfate hexahydrite(MgSO4*6H2O) and bischofit(MgCl2*6H2O).

研究得出(Na+, K+, Mg2+∥Cl-, SO2-4-H2O)五元体系35 ℃时的介稳溶解度数据,绘制了该体系35 ℃的介稳相图,共有9个为氯化钠所饱和的结晶区域:氯化钾、钾芒硝(3K2SO4*Na2SO4)、钾矾(K2SO4*MgSO4*4H2O)、钾盐矾(KCl*MgSO4*2.75H2O)、光卤石(KCl*MgCl2*6H2O)、白钠矾(Na2SO4*MgSO4*4H2O)、硫酸钠、六水硫酸(MgSO4*6H2O)和水氯石(MgCl2*6H2O)。

Moreover, the hot compressive deformation behavior of the RS/PM AZ91 magnesium alloy and AZ91 alloy matrix composite were also investigated, the conclusions are drawn as follows:1. The processing parameters of the atomization-twin rolls quenching technology were optimized as follows: the diameter of the nozzle 1mm, the wheel velocity 25m/s, the pressure of atomization gas 0.3MPa and Ar gas for melt injection 0.1MPa. The RS AZ91 alloy flakes exhibited fine and uniform microstructures. When the flakes were extruded at 673K, extruded velocity of 0.1mm/min and extrusion ratio of 25:1,the magnesium alloy rods with clean surface, uniform dimension and excellent mechanical properties were obtained.2. The RS AZ91 magnesium alloy powders prepared by atomization-twin rolls quenched technology exhibited fine equiaxed grains with the grain size of 1-3μm, the phase constituent included supersaturate solid solution phaseα-Mg and miner fineβ-Mg_(17)Al_(12) phase. The as-extruded materials also exhibited equiaxed grains with the size of 5-7μm and a large number of fineβ-Al_(12)Mg_(17) and fewer AlMg_2Zn phases were detected in the alloy.

本文还研究了快速凝固/粉末冶金AZ91合金热压缩变形流变应力行为,快速凝固/粉末冶金法原位生成Mg_2Si增强AZ91基复合材料,经过系统的研究,获得如下结论:1、雾化-双辊急冷法在下列工艺参数组合下:双辊线速度25m/s;喷嘴直径1mm;熔体压射压力0.1MPa;雾化气体压力0.3MPa。,可获得宏观尺寸细小、微观组织均匀细小、综合性能优良的的快速凝固AZ91合金细碎箔带,快速凝固箔带在挤压温度为673K、挤压速度为0.1mm/min,挤压比为25:1时,可获得的外表光洁、尺寸均匀、组织性能优异的合金棒材。2、雾化-双辊急冷法制备的AZ91合金粉末态为细小等轴晶组织,晶粒尺寸1-3μm,组织为α-Mg过饱和固溶体和微量的细小β-Mg_(17)Al_(12)相组成;粉末挤压棒材为等轴晶组织,晶粒尺寸5-7μm,组织中含有大量细小的β-Al_(12)Mg_(17)以及AlMg_2Zn析出相,室温力学性能,抗拉强度383MPa,屈服强度275MPa,断后伸长率7.5%。

The results of magnesium and calcium ions tolerance test indicated that the modified SPS, synthesized from the above two methods,has good chelation with magnesium and calcium ions for the crablike carboxyl and ester group and increase the reaction weight with magnesium and calcium ions for addition of hydrophilic group.Both of the two modified petroleum sulfonates could produce ultra-low interfacial tension at calcium and magnesium ions concentration lower than 600 mg/L,whereas the general petroleum sulfonates could only produce ultra-low value below 300 mg/L.

耐钙离子能力测试结果,以大庆炼化公司两种渣油为原料,采用上述两种合成方法制备的改性石油磺酸钠,由于产物中引入蟹爪状羧酯基,对钙离子有较强的螯合作用,同时增加了亲水基,增大了表面活性剂分子与钙离子的反应量,因而在600mg/L的钙离子溶液中获得10-3级的超低界面张力;而普通石油磺酸钠仅能在300mg/L的钙离子溶液中获得超低界面张力。

The melting point of the pure periclase magnesia is 2,800℃, some impurities may reduce the melting point of the magnesia , borides influence is extremely remarkable.

纯净的方石型氧化的熔点为2800℃,一些杂质可使氧化的熔点降低,其中硼化物的影响极为显著,即使是少量的硼化物(0.01%-0.02%)的存在就将导致氧化的抗蠕变性能明显降低,而B2O3在高温时的气化能够造成氧化材料的气孔率增大,严重影响其高温强度,故砂降硼是非常重要的。

The paper elaborateds the methods for the magnesium salt whisker synthesis which contains magnesium pyroborate whisker、basic magnesium sulfate whisker、magnesia whisker ect.

详细阐述了硼酸、碱式硫酸晶须和氧化晶须等盐晶须的合成方法,着重介绍了盐晶须作为增强材料在金属铸造、复合材料、塑料等行业的应用。

The main products are: the indirect method zinc oxide Zno99.7, Zno99.5, special rubber zinc oxide, light magnesium oxide, activated magnesium oxide, magnesium oxide wire and cable, adhesives dedicated magnesia, light magnesium carbonate, basic zinc carbonate, rubber accelerator TMTD, rubber Antioxidant: RD, DFC-34, SP-C, 4010,4010 NA of the Company to " With faith in order to survive, rely on technology and development, quality-oriented "approach, the vast numbers of users at home and abroad to win the trust and support, established a good cooperative relationship.

主要产品有:间接法氧化锌Zno99.7、Zno99.5、橡胶专用氧化锌、轻质氧化、活性氧化、电线电缆专用氧化、胶粘剂专用氧化、轻质碳酸、碱式碳酸锌、橡胶促进剂TMTD、橡胶防老剂:RD、DFC-34、SP-C、4010、4010NA 本公司以&凭诚信求生存,靠技术求发展,质量为本&的方针,赢得国内外广大用户的信赖与支持,建立了良好的合作关系。

The results showed that Mg application considerably alleviated Mg-deficient symptom and increased magnesium nutrition on leaf of shatian pumelo; while soil in the orchard contained medium K and lack of Mg, yield and plantation income of shatian pumelo comparatively increased by 1.2% 18.7% and 0.4%~24.7% at the level of the amount of potassium oxide 340.2 kg/hm^2 applying Mg 22.5 kg/hm^2 and 45.0 kg/hm^2 while yield and plantation income of shatian pumulo comparatively increased by 11.2% 31.7% and 11.7%~39.4% at the level of the amount of potassium oxide 453.6 kg/hm^2 applying Mg 45.0 kg/hm^2, 81.0 kg/hm^2 and 117.0 kg/hm^2, and fruits quality was improved as well.

结果表明,施可明显减轻沙田柚叶片的缺症状,提高叶片素营养;在土壤有效钾含量中等,有效含量缺乏的情况下,施用钾肥(K2O) 340.2 kg/hm^2基础上配施肥 22.5及45.0 kg/hm^2,果实产量提高1.2%~18.7%,种植效益提高0.4%~24.7%;施用钾肥(K2O) 453.6 kg/hm^2基础上配施肥 45.0、81.0及117.0 kg/hm^2,果实产量提高11.2%~31.7%,种植效益提高11.7%~39.4%,同时柚果品质得到改善。

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