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Accordingly, the polymorph of antimony white is determined by the growth units in solution.

相应地,湿法锑白的晶型结构由液相中的可溶性生长基元结构决定。

The antimony doped tin oxide nanoparticles were synthesized at 240℃for 17 h by the complexing hydrothermal oxidation method using stannate, antimony white and sulphuric acid as the starting materials, sodium hydrotartrate as the complexing agent and hydrogen peroxide as the oxidant. The resulting powders were characterized by means of differential thermal analysis, infrared spectrometry, X-ray diffraction and transmission electron microscope. The mechanism of the preparation of ATO powder was investigated as well.

摘 要:以锡酸钠、锑白和硫酸为原料,酒石酸氢钠为配合剂,双氧水为氧化剂,采用配合水热氧化法在水热氧化温度为240℃和水热保温时间为17 h时,合成单分散性的蓝色锑掺杂二氧化锡粉末,用差热分析、红外光谱、X射线衍射和透射电镜对所制得的粉末进行表征,并对ATO纳米粉体的配合水热氧化合成机理进行探讨。

The antimony-doped tin oxide nanoparticles were synthesized at 240℃ for 17h by the complexing-hydrothermal oxidation method using stannate, antimony white and sulphuric acid as the starting materials, sodium hydrotartrate as the complexing agent and hydrogen peroxide as the oxidant. The resulting powders were characterized by means of differential thermal analysis, infrared spectrometry, X-ray diffraction and transmission electron microscope. The mechanism of the preparation of ATO powder was investigated as well.

以锡酸钠、锑白和硫酸为原料,酒石酸氢钠为配合剂,双氧水为氧化剂,采用配合-水热氧化法在水热氧化温度为240℃和水热保温时间为17h时,合成单分散性的蓝色锑掺杂二氧化锡粉末,用差热分析、红外光谱、X射线衍射和透射电镜对所制得的粉末进行表征,并对ATO纳米粉体的配合-水热氧化合成机理进行探讨。

The antimonydoped tin oxide nanoparticles were synthesized at 240 ℃ for(17 h) by the complexinghydrothermal oxidation method using stannate,antimony white and sulphuric acid as the starting materials,sodium hydrotartrate as the complexing agent and hydrogen peroxide as the oxidant.

以锡酸钠、锑白和硫酸为原料,酒石酸氢钠为配合剂,双氧水为氧化剂,采用配合水热氧化法在水热氧化温度为240℃和水热保温时间为17 h时,合成单分散性的蓝色锑掺杂二氧化锡粉末,用差热分析、红外光谱、X射线衍射和透射电镜对所制得的粉末进行表征,并对ATO纳米粉体的配合水热氧化合成机理进行探讨。

The antimonydoped tin oxide nanoparticles were synthesized at 240 ℃ for(17 h) by the complexing hydrothermal oxidation method using stannate,antimony white and sulphuric acid as the starting materials,sodium hydrotartrate as the complexing agent and hydrogen peroxide as the oxidant.

以锡酸钠、锑白和硫酸为原料,酒石酸氢钠为配合剂,双氧水为氧化剂,采用配合水热氧化法在水热氧化温度为240℃和水热保温时间为17 h时,合成单分散性的蓝色锑掺杂二氧化锡粉末,用差热分析、红外光谱、X射线衍射和透射电镜对所制得的粉末进行表征,并对ATO纳米粉体的配合水热氧化合成机理进行探讨。

This paper introduces the principal,technical process and product properties of which yield superfine powder whith plasma technical in the classical antimony white furnace.

介绍在传统的锑白炉上采用等离子体技术,生产Sb2O3超细粉末的原理、工艺过程以及产品性能,是一项老工艺赋与新内容的技术创新。

This paper describes the fundamentals, main technical conditions, product quality, economic-technical indicators and actual application of the autogenous top-blowing process for producing antimony white and its co- mparison with other antimony white production processe

介绍了自热式顶吹法生产锑白的工艺原理、主要技术条件、产品质量、经济技术指标以及实际应用情况,并与其它锑白生产方法进行了比较。

The initial products of neutralization-conversion contain oxychloride, cubic and orthorhombic antimony white. The final products turned into single cubic antimony white.

在酒石酸根离子存在的情况下,氯氧锑中和转化初期产物物相含有氯氧锑、立方晶型和斜方晶型锑白,随着时间的延长,完全转化为单一的立方晶型锑白

On the 1st fine antimony, antimony, special white won both countries editor. april 1991, in the second session of beijing international expo, the "flash-card" fine antimony, antimony trioxide won the gold medal. march 2004, tin mines by the state administration for industry and commerce awarded the "shou-credit business contracts."

一号精锑、特号锑白均荣获国家银质奖。1991年4月,在第二届北京国际博览会上,&闪星牌&精锑、三氧化二锑荣获金奖。2004年3月,锡矿山被国家工商行政管理总局授予&守合同重信用企业&。

In the neutralization transforming process of antimony oxychloride, it will be more convement to form the metastable phase in theory, orth. Sb〓O〓, which stably exist all along in fact.

论文首先通过理论分析与实验研究,揭示了锑白湿法生产工艺中粉末结构形貌控制机理:(1)斜方晶型锑白的单位晶胞内所含分子数比立方晶型锑白少,结构与单斜晶型氯氧锑相似。

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