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It is easy to prepare TiO〓 nanoparticles with anatase, rutile, brookite and the mixture of anatase and rutile structures respectively through control of temperature and the ratio of /.

控制/比和反应温度可方便地制备锐钛型、金红石型、板钛矿型以及金红石型与锐钛型混合二氧化钛颗粒。

When the is 0.1mol/l, ratio / is 0 or 4, aged at 95250℃ for 24 hours, anatase and rutile TiO〓 particles are formed respectively; when the ratio / is between 0 and 4, mixture of anatase and rutile TiO〓 particles is formed, the high the temperature the more the rutile phase. When the / is 5, aged at below 200℃ for 24 hours, amorphous product is gained, aged at 250℃ for 24 hours, olive-like TiO〓 particles with brookite structure are formed.

Ti〓=0.1mol·L〓时,95~250℃陈化,/比为0时,得到金红石型TiO〓颗粒,/比为4时,得到锐钛型TiO〓颗粒;/比介于0~4,可得到金红石型与锐钛型混合二氧化钛颗粒,温度越高含金红石型成分越多;/比为5,200℃以下陈化,得无定型产物,250℃陈化得橄榄形单分散板钛矿型二氧化钛。

These results indicated that the TiO2 membranes with rutile phase were more propitious to adherent cells growth than that with rutile phase.

对比结果显示金红石型TiO2比锐钛矿型TiO2更有利于神经细胞的生长。

The samples were characterized by XRD、TEM、XPS and UV-VIS diffraction spectrum.

Ce4+掺杂TiO2纳米光催化剂的制备及反应活性研究用简单的水热方法制备了Ce4+掺杂的锐钛矿和金红石相TiO2样品,并对其光催化活性进行了考察。

Light yellow nitrogen-doped nano-TiO2 powders were prepared by directly calcining the mixture of anatase TiO2 powders and guanidine hydrochloride in the muffle furnace at different temperatures.

锐钛矿相纳米TiO2粉体和盐酸胍的混合物为起始反应物,通过在不同温度条件下对反应物直接进行热处理制得了淡黄色的掺氮纳米TiO2粉体。

In other words,under the same reaction conditions,the larger the particle size of theprecursor mixed powder,the higher the temperature at which Zn_2TiO_4 starts to appear.There are structure similarity phenomena in ZnO-TiO_2 system,i.e.,the connectionmanner of TiO6 octahedra in the structure of ZnTiO_3 is similar with the one of rutile,andthe connection manner of TiO6 octahedra in the structure of Zn_2TiO_4 and Zn_2Ti_3O_8 issimilar with the one of anatase.

ZnO-TiO_2系统中存在一种类构现象,即:ZnTiO_3结构中的氧八面体的连接方式和金红石TiO_2的相似,而Zn_2TiO_4和Zn_2Ti_3O_8结构中的氧八面体的连接方式则和锐钛矿TiO_2的相似,并由此衍生出一个类构效应理论,即:ZnO和金红石TiO_2的反应产物中不应该出现Zn_2TiO_4和Zn_2Ti_3O_8当然,反应温度应低于ZnTiO_3的起始分解温度。

The result show that the N elements curbed the transition from anatase phase to rutile phase , Doped-N was in the structure of the TiO2 as the form of Ti-O-N and formed a new bond energy level;N-doped changed the paramagnetic of the characteristics. The paramagnetic resonance spectrum of TiO2 showed anisotropic and showed hyperfine splitting, The Lande factor of Ti3 + combined with the N is 1.956. UV-Vis absorption spectra showed that the photocatalytic ability of photocatalyst TiO2-xNx to expand to the visible region, the sample (3.84wt %) has the highest photo catalytic activity, the adsorption edge extend to 520nm and degradation is 55.54% under the visible light for 1.5h.

研究结果显示,N元素抑制了锐钛矿相向金红石相的转变,阻止了晶粒的长大,掺杂的N元素以O-Ti-N的形式存在于光催化剂结构中,形成了新的能级结构;N掺杂改变了催化剂的顺磁特征,使TiO2的顺磁共振谱线呈现各向异性,发生了超精细分裂,其中g2=1.956,是与N结合的Ti3+的朗德因子;紫外可见光吸收谱表明,催化剂TiO2-xNx的光响应能力拓展到可见光区,光吸收带发生红移;光催化测试结果显示,掺杂量为3.84的TiO2-xNx在可见光区的响应能力最高,吸收波长延伸至520nm,其光催化活性最大,1.5h降解率达到55.54%。

TiO2 nanoparticles synthesized by a sol-hydrothermal process were modified with phosphorous acid by an impregnation method.

通过浸渍过程实现了磷酸对溶胶水热法合成的锐钛矿相TiO2纳米粒子的改性。

Compared with traditional method, the inventive optical catalyst has higher activity and high utilization on ultraviolet light.

光催化材料粒径集中分布于10-12nm之间;晶体晶型多为锐钛矿型;较传统方法制备的光催化材料相比光催化活性明显提高;对紫外光的利用率显著提高,且可部分利用可见光。

The catalyst support contains at least 20% by weight of TiO2 being present mainly in the anatase form. Furthermore, the catalyst support contains diatomaceous earth in an amount of at least 2% and less than 80% by weight of the catalyst support.

催化剂载体含有至少20重量%的主要以锐钛矿型存在的TiO2,而且催化剂载体中含有至少为2重量%,且小于80重量%的硅藻土,以催化剂载体重量计。

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