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The results showed that (1) The grain size of nanometer YiO_2 was40~80nm.The wavelength corresponding to the maximum absorbency values were observedin the 200~320nm range.The crystal structure of carbon doped TiO_2 photocatalyst is primarilyanatase(22.43% rutile), and the content of carbon is about 4.6%.(2) The relative humidityvaring from 8% to 80%, the photocatalytic degradation degree of benzene increased withincreasing relative humidity; and to toluene, degradation rate was hanced by relative humidityup to 60%, and more or less inhibited above 60%.(3) Scheme and results of orthogonal testswere used by evaluating the photocatalytic performance of the gas phase methanol, acetoneand 1-heptane.The results revealed that their degradation degree reached 84.5%, 93.39% and93.45%, respectively.(4) The 254nm UV lamp showed higher photocatalytic degradation rate.For methanol, acetone and 1-heptane, it was found that photocatalytic degradation reactionoccurs with the light strength of daylight lamp.(5) Under the the same conditions, 15%degradation degree has been obtained for benzene, whilst about 10% degradation degree wasattained by Degussa P25; During the initial phases, the toluene revealed higher photocatalyticactivity, comparing with Degussa P25, the degradation degree of methanol, acetone and1-heptane were slightly lower.

结果表明:(1)CVD法制备的纳米TiO_2光催化剂,颗粒球形度好、粒径在40~80nm之间;最大吸光度值所对应的波长为200~320nm;含碳量约为4.6%;晶型组成主要为锐钛矿型,金红石的含量约为22.43%;(2)在相对湿度为8%~80%范围内,苯的光催化降解率随着相对湿度的增大而增大;甲苯在相对湿度为60%时达到最好降解效果,当相对湿度增大到80%时光催化效果降低;(3)将正交实验设计及实验方案应用于气相甲醇、丙酮和正庚烷光催化降解研究,实验结果表明:三者最高降解率分别为84.5%、93.39%和93.45%;(4)有254nm紫外灯参与的光催化实验可以大大提高有机气体的光催化降解率;在日光灯的照射下,掺碳纳米TiO_2对气相甲醇、丙酮和正庚烷具有一定的光催化氧化能力;(5)较P25粉,在相同的光催化操作条件下:气相苯的平均降解率达15%,高于P25粉10%的降解率;气相甲苯在初始阶段具有较高的反应速率;气相甲醇、丙酮和正庚烷的降解率略低于P25粉。

As confirmed by XRD and XPS determinations, the crystalline pattern of immobilized TiO2 was still anatase-form after calcination, and the micrographic structure and surface properties of ACF have not been damaged by the deposition process and calcination at different temperatures.

从XRD 以及XPS图可以看出;煅烧后的TiO2仍保持了锐钛矿相;而且经过负载以及不同温度下的煅烧后; ACF的形貌以及特性并没有被破坏。

After annealing at higher temperatures (higher than 900 ℃),the structure of TiO 2 thin film changed into rutile completely;the TiO 2 grain changed from column to nubbly.

锐钛矿相TiO2 薄膜,在紫外线作用下可以实现有机物的光催化降解,在环境保护污染治理等方面有着广阔

The results show photoactivity is related to structure of TiO2, that is the anatase phase plays beneficial role in photoactivity.

结果表明,光催化活性与晶体结构有关,锐钛矿型有利于光催化活性的提高。

The particle diameter, per-surface area of the prepared catalyst particles will enhance photoactivity in the degradation of phenol.

Ce4+可显著提高TiO_2的活性,主要归因于锐钛矿结晶度、比表面积、孔径和孔容的提高,特别是表面缺陷的增加。

Due to its large surface area, mesoporous structure, pure anatase structure and high adsorption capacity, the photoactivity of 31%TiO〓/SiO〓 was much higher than that of the pure titanium dioxide.

多孔硅胶抑制了高温时TiO〓晶型由锐钛矿向金红石型的转变,并且对TiO〓具有很好的分散能力。

The autoclaved sol was synthesized by using titanyl sulfate (TiOSO4), ammonia as raw materials and peroxide (H2O2) as complexing agent, the AS sol was neutral or alkalescent .

以无机盐TiOSO4、氨水、H2O2为原料制备了含有针状锐钛矿晶粒的AS(autoclaved sol简写为AS)溶胶,AS溶胶呈中性或弱碱性。

Anatase of unaged gel powder owned faster crystalline growth rate and worse aggregation during calcination than that of aged gel powder due to the existence of much more amounts of OH- in unaged powder.

未经过陈化处理的胶体粉末在煆烧过程中其锐钛矿晶粒成长较为快速且造成较为严重的凝聚,可能为粉末中含有较多的氢氧基所造成。

The dielectric function and complex refractive, reflectivity, and absorption coefficients of anatase TiO2 dominated by electron interband transitions are analyzed in terms of the precisely calculated band structure and density of states.

利用精确计算的能带结构和态密度分析了电子带间跃迁占主导地位的锐钛矿相TiO2的介电函数、复折射率、反射率和吸收系数,理论计算得到的结果与实验测量结果基本一致。

The CoFe2O4/TiO2 magnetic nano-photocatalysts has fairly good magnetic property. The X-ray diffraction, transmission electron microscopy and ultraviolet-visible technique were used to analyze the phase structure, size and spectrum response scope of the samples. The XRD indicated the anatase TiO2 was formed when TCF modified by plasma. The size of CoFe2O4 particles was about 20 nm. The diameter of CoFe2O4/TiO2 particles is in the range of 30~40 nm. So the shell of TiO2 enwraps closely around the core and the thickness is in the range of 10~20 nm.

运用VSM技术对样品磁性能进行研究,结果表明:等离子体修饰后的复合材料仍具有较高的饱和磁化强度,可在外加磁场作用下实现催化剂在水中的分离与回收;样品的XRD、TEM和UV-Vis分析测试结果表明:等离子体修饰后的复合材料有锐钛矿型TiO2存在;TEM谱图显示磁核CoFe2O4的平均粒径约为20 nm,TCF复合粒子的粒径约为30~40 nm,TiO2包覆层的厚度为10~20 nm。

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