锐钛矿

There are three types of TiO2 crystalline: anatase, rutile and brookite.

用作光催化剂的主要是锐钛矿型和金红石型，且其中以锐钛矿型的催化活性最高。

The nanophase anatase of different size (the average is 40 nm) was synthesized with chemical precipitation method.

采用化学沉淀法制备出 40nm的锐钛矿，并用拉曼光谱对纳米和块体锐钛矿到金红石的相转变过程进行了研究。

The titanium dioxide is one kind of important industrial chemicals, mainly has the brookite, Rutile and anatase three crystal seeds.

二氧化钛是一种重要的化工原料，主要有板钛矿、金红石和锐钛矿三种晶型。

Result of photocatalytic degradation of methyl orange showed that the TiO2 photocatalytic activity decreased with the decreasing of anatase ratio in the mixed crystallite of anatase,rutile,and brookite;and photocatalytic activity of pure rutile TiO2 was relatively bad.

光催化降解甲基橙的研究表明，所得锐钛矿、金红石和板钛矿3种混晶中，二氧化钛的光催化活性随着锐钛矿含量的降低而降低；纯金红石型二氧化钛的光催化活性较差。

TiO_2 is a very important wide bandgap semiconductor, which mainly include three crystal structures. Anatase and rutile are tetragonal. Brookite is orthorhombic.

TiO_2是一种重要的宽禁带半导体材料，主要有3种晶型，即金红石、锐钛矿和板钛矿结构，其中金红石和锐钛矿属四方晶系，板钛矿属正交晶系。

Using the aforementioned experimental methods,the author has performedcareful study on the thermoanalytical characteristic of nanocrystalline brookite-basedTiO2,and found that on the DTA curve there exists a small irreversible endothermicpeak,which is related to the dramatic structural phasetransformation from brookite to anatase then to rutile.

利用上述实验手段，作者首次对板钛矿基(brookite-based)纳米TiO2的热分析特性进行了较系统、深入的研究，发现在DTA曲线上存在一较小的不可逆、无失重吸热峰，对应于从板钛矿经锐钛矿到金红石的急剧转变。

It was indicated by UV-Vis spectra characterization that the precursor always contains the tetrahedral Ti species and the octahedral Ti species regardless of the Ti content. Calcination of the precursor resulted in a partial condensation of the octahedral Ti species to form the anatase phase.

UV-Vis 光谱表明，Ti-MWW 合成原粉中含有四面体的钛和八面体的钛，而八面体的钛属于一种骨架外钛，未经酸处理而煅烧会使部分八面体钛缩合形成锐钛矿，而经过酸处理和煅烧后的分子筛则几乎不含有锐钛矿。

The adding of anatase nano-crystalline TiO_2 to the deposition solution accelerates the depositing of TiO_2 articles from the deposition solution on the silica glass fiber. A well-combined and durable TiO_2 thin film on silica glass fibers surface obtained by controlling the deposition temperature, deposition time, deposition cycles, concentration of the deposition solution, relative concentration of the deposition materials, pH value of the deposition solution. The effect of the deposition conditions, the drying conditions and the annealing treatment conditions on the surface morphology, section morphology, growth patterns, thickness of the deposited TiO_2 thin films were investigated. Growth rate and particle size of the thin films were controlled by the deposition conditions.

实验结果表明加入微量的锐钛矿型纳米TiO_2诱导晶可以使沉积液中析出的TiO_2粒子更大程度的以锐钛矿型纳米TiO_2粒子的形式析出；通过对沉积温度、沉积液中组分浓度及相对浓度、沉积溶液的pH值的调节与控制，从而控制沉积溶液中化学反应平衡的移动，研究了以上条件对沉积速率、沉积溶液中[Ti6]2–与—OH、[Ti6]2–之间的脱水聚合反应速率的影响，总结出了获得均匀致密质量较好的TiO_2薄膜的一系列实验参数，并对薄膜的生长模式进行了系统的分析研究；通过对沉积时间及沉积次数的分析，可以有效的控制TiO_2薄膜的厚度及质量；通过对薄膜的干燥条件及热处理条件的控制，可以使利用液相沉积法获得的TiO_2薄膜进一步晶化；并分析了对薄膜引起缺陷的主要原因。

The modification of nanosized TiO_2 with phosphorous acid has been completed by an impregnation process.

结果表明，H_3PO_4修饰显著地提高了纳米锐钛矿相TiO_2热稳定性，甚至经过800℃热处理后仍然具有以锐钛矿相为主的相组成。

The results show that the phosphorous acid modification obviously enhances the thermal stability of nanosized anatase TiO2, a principal anatase phase was maintained even after thermal treatment at 800℃.

结果表明，磷酸修饰显著地提高了纳米锐钛矿相TiO2热稳定性，甚至经过800℃热处理后仍然具有以锐钛矿相为主的相组成。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。