锆的

2The studies on the appearance typomorphism, physical typomorphism, inner structure typomorphism and chemical typomorphism of the zircon and garnet, and the result of U-Pb isotopic age dating of zircon indicate that the zircons are meta-morphogenic genesis but two or three of them are magmatic genesis and most meta-morphogenic zircons have a basic magmatic zircon core which was generated in Stage of Yanshand and Indo-Chinese epoch. The genesis and origin of the garnet is very complicated. The garnets are main almandine with high Fe and Mg content and were proposed their souce rocks are mostly regional mid-degree-metamorphic rocks.

2研究锆石和石榴石的形貌标型、物性标型、内部结构标型以及成分标型特征和锆石U-Pb同位素测年结果表明，锆石除少数几个为岩浆锆石外，绝大多数是变质锆石，且中间多有形成于燕山-印支期的基性岩岩浆锆石残核；石榴石的成因及来源是比较复杂的，以铁铝榴石为主，且铁铝榴石中Fe、Mg的含量较高，推测其源区母岩主要以中级区域变质岩为主。

The influence of different assembled condition such as assembly method, concentration of zirconium source and pH value on the effectiveness of assembly were evaluated via DSC-TG, FT-IR, Uv-vis and SAXRD et al. It showed that the assembly effectivness of uncalcined 3 Si/Zr_10# sample was best.c The optical characteristic, which including light-conduction in infrared band and polarity in visible band, of dip-coating film and membrane assembled zirconia after processing parameters of assembly optimized were observed via FT-IR and Uv-vis. The polarity was characterized by polarizing angle through calculation from light-transmittance, light-reflectance and fresnel coefficient. qualitative analysis showed that the polarity of Si/Zr_10 # dip-coating film assembled was best.d Adopting zirconium oxychloride as zirconium source, CTAB as template, employing different CTAB adding sequence, two mesoporous zirconia samples were prepared. The template effect of two samples was discussed. It showed that the effect of the sample which CTAB adding sequence was same as mesoporous silica film was better. The light-conduction in infrared band of these samples was also studied, which offered comparison to the polarity of zirconium dioxide assembled within mesopore.

结果显示：组装条件优化后的uncalcined 3 Si/Zr_10#厚膜样组装效果最好，其组装液对应的pH值最利于该锆源离子模板交换组装； c选用FT-IR、Uv-vis对组装条件优化后纳米氧化锆/介孔氧化硅厚膜、纳米氧化锆/介孔氧化硅薄膜包括红外导光性、可见光区内的偏光性在内的光学特性进行了分析，其中偏光性以膜层透光性、反光性及菲涅耳系数计算出的偏振角即布儒斯特角表征，定性分析显示，Si/Zr_10#ZrO_2/介孔氧化硅厚膜偏光性最好； d以氧氯化锆ZrOCl_2·8H_2O为锆源，CTAB为模板剂，采用不同的模板剂加入顺序，探索性地制备两介孔氧化锆样，分析了两介孔氧化锆样的模板效果，得出模板剂加入顺序同介孔氧化硅薄膜时介孔氧化锆样的模板效果较好，并分析了所得样品的导光性，为锆氧粒子引起的附加光学特性分析提供了参考和对比。

In the preparation method, zirconium is mixed with benzenephosphonic acid according to the molar ratio of 1:2 to 1:4, and Alpha-zirconium phenyl phosphonate is produced by centrifugal washing after one to five days of crystallization under the temperature of 50 DEG C to 100 DEG C; deionized water is added in order to prepare Alpha-zirconium serosity, the solid content of which is 4 percent to 8 percent; the Alpha-zirconium serosity is granulated and dried by a rotary spray dryer, the feeding speed of the Alpha-zirconium serosity imported into an atomizer is controlled between 20ml/min and 80ml/min, and the temperature of a hot air inlet is controlled between 120 DEG C and 200 DEG C.

本发明涉及一种大比孔容微球α-苯膦酸锆及其制备方法，其颗粒尺寸为10～100μm，比孔容为0.908cc/g，比表面积为125.8m 2 /g；其制备方法是将锆和苯膦酸以摩尔比1∶2～1∶4混合，在50～100℃温度条件下晶化1～5天，离心洗涤得到α-苯膦酸锆；加入去离子水配制α-苯膦酸锆浆液，其固含量为4-8％；将α-苯膦酸锆浆液用旋转式喷雾干燥器进行造粒、干燥，控制α-苯膦酸锆浆液输入雾化器的进料速度为20～80ml/min，控制热风进风口温度为120～200℃；该方法具有操作简单、合成条件温和，对环境污染小等特点，该材料应用于催化、催化剂载体、吸附、离子交换等方面。

With the same zirconium concentration,the absorbance of zirconyl oxyhalide solution (λ=664nm)prepared in HCl was larger than that from pure zirconyl oxyhalide solution.

发现对于相同锆浓度的溶液，高酸度的锆贮备溶液中的锆与偶氮胂Ⅲ形成的化合物的吸光度(λ=664nm)要大干仅由氧氯化锆配制的锆贮备溶液中的锆与偶氮胂Ⅲ形成的化合物的吸光度。

Lithium complexes 1b,1d and Zirconium complexes 1c,1e,lf were prepared using the benzylamine ligand. X-ray crystal structures of these complexes were determined.

合成了一种新型的硅桥联的多齿胺类配体[PhNHSi(NMe_2)NHPh]，在此基础上研究了其对应的碱金属化合物和过渡金属锆的络合物的制备，并进行它们的X-射线晶体结构的分析。

The original Seluohe Group contains at least four parts: Late Archean metamorphic rocks (zircon SHRIMP protolith ages 2517~2534 Ma), Late Paleozoic metamorphosed volcanic-sedimentary strata (zircon SHRIMP 252 Ma), Permian gneissic granitic complex (zircon SHRIMP 260 Ma), and Jurassic mylonitized granites (zircon SHRIMP 168 Ma).

原划分的色洛河群至少由4部分组成：新太古代变质火山－沉积地层（锆石SHRIMP年龄为2517~2534 Ma）、晚古生代变质火山－沉积地层（英安岩锆石SHRIMP年龄为252 Ma）、二叠纪片麻状杂岩体（锆石SHRIMP年龄为260 Ma）和侏罗纪糜棱岩化花岗岩（锆石SHRIMP年龄为168 Ma）。

According to crystal shape and color, 4 types of zircon in metarhyolite have been identified: inherited, magmatic, metamophic and mixed zircon.

1根据锆石的晶形和颜色，将本区流纹岩中的锆石分为继承锆石、岩浆结晶锆石、变生锆石以及它们之间的混合锆石。

The coarse needle-like or nubby Al9FeNi phase existed in the cast microstructure of high content Fe and Ni alloy 2618(2#). After hot extrusion, it was broken into coarse multi-angle Al9FeNi particles. The contents of Fe and Ni have no effect on aging characteristic and the hardness of the alloy after aging.

含锆的高铁、镍2618合金经熔体高温过热处理后(4#)，在合金铸态组织中获得均匀细小的针片状Al_9FeNi相，热挤压后获得均匀细小的颗粒Al_9FeNi相；弥散Al_3Zr粒子的存在可使2618合金得到细小的再结晶晶粒组织，该合金既可获得较高的高温强度，还可获得较高的延伸率。

According to the metamorphic fluid involved, metamorphic zircon can be divided into five subtypes: metamorphic recrystallization via solid-state transformation, replacement alteration or dissolution reprecipitation, and metamorphic growth corresponds to chemical precipitation from aqueous fluid or hydrous melt.

根据参与锆石改造的变质流体性质，进一步可将变质锆石区分为五种不同类型，即固态重结晶锆石、交代重结晶锆石、溶解重结晶锆石，以及富水流体和含水熔体中的生长锆石。

All the ligands and complexes have been characterized with ~1H-NMR, MS and EA.X-Ray single crystal diffraction reveals that zirconium complex containing the tert-butyl substituted N_2O_2 ligand is an oxo- and hydroxyl-bridged dinuclear structure, which is possibly formed by partial hydrolysis of chlorides at one of the zirconium centers. A tetranuclear zirconium complex has been obtained and chacaterized, which is formed by complete hydrolysis of the chlorides at the zirconium centers.

通过研究配合物的单晶结构，我们发现叔丁基取代的不对称N_2O_2配体与ZrCl_4反应生成的锆配合物为氧桥和羟基桥连接的双核锆配合物，中间过程涉及单核锆配合物中氯原子部分水解，并得到氯原子部分水解的双核锆配合物和全部水(来源：8e6eAB67C论文网www.abclunwen.com)解的四核锆配合物的晶体结构，在晶体培养过程中发现双核锆配合物能够以手性自发拆分结晶析出。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。