锆的

The reactions and transformation have resulted in a great volume increase and thus destroyed the structure,weakened the strength and corrosion resistance of the materials.

这一系列反应使试样产生很大的体积膨胀，从而破坏了制品结构。因此，与镁炭砖不同，Al和Si不但不能增强镁锆炭砖，而且使其结构破坏和耐侵蚀性降低。

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Of the five stages deformation, the exact ages of the (2) and (3) were determined by 40Ar/39Ar method as 290 and 259 Ma respectively.2. New results on the metamorphic belts and associated metamorphism of the Xiaopu metamorphic rocksBased on detailed microtextural observations and occurrence of typical metamorphic minerals, five metamorphic belts in the Xiaopu metamorphic rocks are identified. From the north to the south, they are biotite belt, garnet belt, staurolite belt, andalusite belt, and sillimanite belt. I suggested that the metamorphic belts occurred in the Xiaopu area belongs to the high temperature/low pressure series, may have resulted from the later Permian crust extension at ca. 290 Ma.3. I suggest that there may have been a Carboniferous backarc basin along the southern slope of the Harlik Mountain.Detrital Zircon SHRIMP U-Pb dating indicated that the sedimentary age of the Julideneng formation lithic sandstone must be later than late Devonian, most likely is Carboniferous rather than previously thought Precambrian. Analyses on its geologic setting, location of provenance, and sedimentary environment suggest the Carboniferous strata may form in a lagged backarc basin bounded by backarc uplifts.5. Reconstruction of the post-Paleozoic tectonic evolution history of the Harlik MountainThe tectonic evolution of Harlik mountains since the Paleozoic were reconstructed as followings:(1) arc-affinity magmative activities occurred during the middle-Ordovician to early-Silurian;(2) the middle-Silurian to late-Devonian was a back-arc uplift stage;(3) back-arc extension featured the Carboniferous period;(4) post-collisional extension and/then compression during Permian;(5) at the Mesozoic, differential uplift developed; and (6) the late Cenozoic is the intra-continental re-orogen stage.6. Primary estimation of the crust shortening is madeThe folded pre-Mesozoic strata were used to estimate crust shortening along the Harliknanshankou-Koumenzi, Shichengzi-Baishitou, and Qincheng-Xiaopu sections. Their shortening ratios are 16.2%, 19.8%, and 20.1% respectively corresponding crust shortening are 4.3, 9, and 11.3 km.

根据Ar-Ar热年代学研究，精确测定了早二叠世伸展变形和晚二叠世挤压变形的峰期时代分别为290Ma和259Ma.2、提出了关于哈尔里克山南麓小铺一带变质带和变质作用的新认识根据显微观察资料和特征变质矿物的出现，把小铺一带的变质岩由SW向NE方向依次划分为黑云母带、石榴石带、十字石带、红柱石带和矽线石带等变质带；初步确定该区的变质作用属于中温-低压型，变质作用发生的时代为290Ma左右，是该区早二叠世地壳伸展的产物。3、首次提出哈尔里克山南麓在石炭纪可能发育弧后盆地的新观点根据哈尔里克山南麓原"居里得能组"岩屑砂岩的碎屑锆石SHRIMP U-Pb定年，确认这套地层的沉积不早于晚泥盆世，很可能是石炭纪，而不是前人所说的前寒武纪；结合对其区域地质背景、源区位置和沉积环境分析，推测该区石炭纪可能为滞后弧后盆地和弧后隆起区构造背景。4、进一步证明哈尔里克山不发育与岛弧演化相关的泥盆纪岩浆活动根据对代表性闪长岩和花岗岩的锆石SHRIMP年代学研究获得的新资料，结合该区已有相关资料的综合研究，确定哈尔里克山岩浆岩分别形成于奥陶纪-志留纪和石炭纪晚期-二叠纪，不存在泥盆纪的岩浆岩，进而认为该区泥盆纪不属于岛弧环境。5、重建了哈尔里克山古生代以来的地质演化过程根据区域资料以及本次研究所获得的资料，把哈尔里克山古生代以来的构造演化划分中奥陶世-早志留世为岛弧、中志留世-晚泥盆世为弧后区、石炭纪弧后伸展、二叠纪为后碰撞伸展与挤压、中生代差异隆升和晚新生代陆内再造山过程等构造阶段。6、初步估算了哈尔里克山地壳缩短率和缩短量根据前中生代地层褶皱估算的哈尔里克山南山口-口门子、石城子-白石头和沁城-小铺三条剖面的地壳缩短率分别为16.2%、19.8%和20.1%，相应的地壳缩短量分别为4.3km、9km和11.3km。

The U-Pb and Pb-Pb isotopic dating of zircons provided the ages of 447-462Ma representing the ages of peak granulitic metamorphism. The U-Pb dating of detrital zircons from aluminum-rich gneisses yielded older upper intercept ages which reflect the times of older materials derived from sourse rocks of the gneiss protoliths.

岩石中变质锆石的U-Pb及Pb-Pb同位素测定获得447-462Ma的年龄值，代表其麻粒岩相的变质作用时代，富铝片麻岩中含继承组分的锆石还获得较老的上交点年龄，它可能代表其沉积岩原岩源区的年龄。

A chromium free conversion coating at least equivalent in corrosion protective quality to conventional chromate conversion coatings can be formed on metals, particularly cold rolled steel, by a dry-in-place aqueous acidic liquid comprising: a component of anions, each of said anions consisting of at least four fluorine atoms and at least one atom of an element selected from the group consisting of titanium, zirconium, hafnium, silicon, and boron, and, optionally, ionizable hydrogen atoms, and optionally, one or more oxygen atoms; a component of cations of elements selected from the group consisting of cobalt, magnesium, manganese, zinc, nickel, tin, zirconium, iron, and copper; the ratio of the total number of cations of this component to the total number of anions of component being at least 1:5; sufficient free acid to give the composition a pH in the range from 0.5 to 5.0; a component selected from the group consisting of phosphorus-containing inorganic oxyanions and phosphonate anions; and a component selected from the group consisting of water-soluble and water-dispersible organic polymers and polymer-forming resins and, preferably, also including a component selected from the group consisting of tungstate, molybdate, silicotungstate, and silicomolybdate anions.

通过对包含以下成分的含水酸性液体进行干燥，可以在金属上形成无铬的转换涂层，该涂层与普通铬酸盐转换涂层相比，至少在抗腐蚀质量上等效：$_一种阴离子成分，所述各个阴离子包括至少4个氟原子，至少选自钛、锆、铪、硅与硼元素中的1个原子。任选地可离解的氢原子，任选地1个或多个氧原子；$_一种选自钴、镁、锰、锌、镍、锡、锆、铁与铜元素的阳离子成分，上述成分的阳离子总数与成分内的阴离子总数之比至少为1∶5；$_足够的游离酸以使该组合物的pH值在0.5～5.0的范围内；$_一种选自含磷的无机含氧阴离子与膦酸盐阴离子的成分；$一种选自水溶性与水可分散性有机聚合物与聚合物形成的树脂的成分，优选还包括一种选自钨酸盐、钼酸盐、钨硅酸盐与钼硅酸盐阴离子的成分。

Theoretical study on the change of HOMOs and LUMOs gaps illustrates that cubic-like structures are more favorable than others growth modes, namely the cubic zirconia nucleates favorable, this fact accords well with previous experimental results.

对各种生长模式的最高占据轨道能和最低空轨道的能量的差值与团簇的尺寸变化可以发现，氧化锆团簇最容易以类立方结构的生长模式生长，即立方相氧化锆团簇结构容易形核生长，这是符合先前的实验结果的。

This implies a major stage of crustal growth in Proterozoic time and remelting of the crustal material in Early Jurassic time;(5) The Oligocene-Miocene adakites contain magmatic zircons that show similar Hf isotope compositions to the Cretaceous-Paleogene Gangdese batholiths, providing a key constraint that allows evaluation of the nature and timing of crustal thickening in southern Tibet owing to the India-Asia collision; and (6) As a whole, the Hf isotope information observed in zircons from the above Transhimalayan rocks demonstrates a temporal variation in εHf values, and thus TDMC ages, that suggests multiple stages of orogenic or crustal formation events.

五、渐新世、中新世的埃达克岩，其岩浆锆石的铪同位素特徵与白垩纪、古第三纪冈底斯岩浆相似，因而为藏南在印亚碰撞以后，地壳增厚的时间与机制提供了关键性的制约；六、综观上述藏南火成岩中的锆石，它们与时变化的铪同位素初始值及其对应的模式年龄记录了拉萨地块多阶段的造山与地壳形成历史。

For example, alkaline elements can affect diffusion velocity of Zr, Si and O ions although these alkaline elements cannot exist in crystal structure of zircon. However, K rich media and Na rich media exert different effects on the growth of crystal form: in the K rich media, growth speed of prism faces in the vertical direction is much higher than that of pyramid faces, and {111} growth speed in the vertical direction is higher than {311},which decides the formation of bipyramids dominated by {311} pyramids; in the Na rich media, both prism and pyramid grow to a certain extent, but the former is smaller than the latter.{100} growth speed in the vertical direction is lower than {110}, while {111} growth velocity in the vertical diredtion is lower than that of {311},resulting in the growth of the crystal form characterized by {100} short prism and {111} pyramid.

例如，尽管碱性元素并不进入锆石晶格，但它们可以影响Zr、Si、O离子的扩散速度，但是富钾和富钠的介质对锆石晶形发育的影响是有差别的，表现为：在富钾的介质中，将导致柱面的法向生长速度较锥面快得多，而锥面中，｛111｝的法向生长又较｛311｝快，由此决定了形成以｛311｝锥为主的双锥状晶体；在富钠的介质中，柱面和锥面都有一定程度的发育，但前者弱于后者，而柱面中，｛100｝的法向生长较｛110｝慢，由此决定了形成以｛100｝柱和｛111｝锥为主的短柱锥状晶体。

Therefore, the formation of the first episode of metamorphic zircons is correlated with fluid activity during the progressive high-pressure eclogite-faeies metamorphism.

年龄为240.9 4.8～245.1 3.1Ma的变质锆石的生长对应于板块俯冲过程中高压榴辉岩相变质作用期间的流体活动，而223.7 4.2-226.0 3.9Ma的变质锆石的生长可能对应了板块折返早期的流体活动。

Of the five stages deformation, the exact ages of the (2) and (3) were determined by 40Ar/39Ar method as 290 and 259 Ma respectively.2. New results on the metamorphic belts and associated metamorphism of the Xiaopu metamorphic rocksBased on detailed microtextural observations and occurrence of typical metamorphic minerals, five metamorphic belts in the Xiaopu metamorphic rocks are identified. From the north to the south, they are biotite belt, garnet belt, staurolite belt, andalusite belt, and sillimanite belt. I suggested that the metamorphic belts occurred in the Xiaopu area belongs to the high temperature/low pressure series, may have resulted from the later Permian crust extension at ca. 290 Ma.3. I suggest that there may have been a Carboniferous backarc basin along the southern slope of the Harlik Mountain.Detrital Zircon SHRIMP U-Pb dating indicated that the sedimentary age of the Julideneng formation lithic sandstone must be later than late Devonian, most likely is Carboniferous rather than previously thought Precambrian. Analyses on its geologic setting, location of provenance, and sedimentary environment suggest the Carboniferous strata may form in a lagged backarc basin bounded by backarc uplifts.5. Reconstruction of the post-Paleozoic tectonic evolution history of the Harlik MountainThe tectonic evolution of Harlik mountains since the Paleozoic were reconstructed as followings:(1) arc-affinity magmative activities occurred during the middle-Ordovician to early-Silurian;(2) the middle-Silurian to late-Devonian was a back-arc uplift stage;(3) back-arc extension featured the Carboniferous period;(4) post-collisional extension and/then compression during Permian;(5) at the Mesozoic, differential uplift developed; and (6) the late Cenozoic is the intra-continental re-orogen stage.6. Primary estimation of the crust shortening is madeThe folded pre-Mesozoic strata were used to estimate crust shortening along the Harliknanshankou-Koumenzi, Shichengzi-Baishitou, and Qincheng-Xiaopu sections. Their shortening ratios are 16.2%, 19.8%, and 20.1% respectively corresponding crust shortening are 4.3, 9, and 11.3 km.

根据Ar-Ar热年代学研究，精确测定了早二叠世伸展变形和晚二叠世挤压变形的峰期时代分别为290Ma和259Ma.2、提出了关于哈尔里克山南麓小铺一带变质带和变质作用的新认识根据显微观察资料和特征变质矿物的出现，把小铺一带的变质岩由SW向NE方向依次划分为黑云母带、石榴石带、十字石带、红柱石带和矽线石带等变质带；初步确定该区的变质作用属于中温-低压型，变质作用发生的时代为290Ma左右，是该区早二叠世地壳伸展的产物。3、首次提出哈尔里克山南麓在石炭纪可能发育弧后盆地的新观点根据哈尔里克山南麓原&居里得能组&岩屑砂岩的碎屑锆石SHRIMP U-Pb定年，确认这套地层的沉积不早于晚泥盆世，很可能是石炭纪，而不是前人所说的前寒武纪；结合对其区域地质背景、源区位置和沉积环境分析，推测该区石炭纪可能为滞后弧后盆地和弧后隆起区构造背景。4、进一步证明哈尔里克山不发育与岛弧演化相关的泥盆纪岩浆活动根据对代表性闪长岩和花岗岩的锆石SHRIMP年代学研究获得的新资料，结合该区已有相关资料的综合研究，确定哈尔里克山岩浆岩分别形成于奥陶纪-志留纪和石炭纪晚期-二叠纪，不存在泥盆纪的岩浆岩，进而认为该区泥盆纪不属于岛弧环境。5、重建了哈尔里克山古生代以来的地质演化过程根据区域资料以及本次研究所获得的资料，把哈尔里克山古生代以来的构造演化划分中奥陶世-早志留世为岛弧、中志留世-晚泥盆世为弧后区、石炭纪弧后伸展、二叠纪为后碰撞伸展与挤压、中生代差异隆升和晚新生代陆内再造山过程等构造阶段。6、初步估算了哈尔里克山地壳缩短率和缩短量根据前中生代地层褶皱估算的哈尔里克山南山口-口门子、石城子-白石头和沁城-小铺三条剖面的地壳缩短率分别为16.2%、19.8%和20.1%，相应的地壳缩短量分别为4.3km、9km和11.3km。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。