锆

It was revealed that the film was constituted mainly by Zr-C, C=C (s^2) and C-C(sp^3) bonds; structure of the films was crystalline ZrCN embedded in an amorphous carbon and carbonitride matrix. With increasing flow rate, film Zr content decreased, but C and N contents increased.

实验结果表明薄膜结构是由ZrCN晶粒镶嵌在无定形碳和碳氮化合物基体中；膜中的化合键主要以Zr-C，C=C(sp^2)和C-C(sp^3)形式存在；随着混合气体流量的增加，薄膜的锆原子分数减小，而N和C的原子分数逐渐增大。

This dissertation was focused on the research about the formation and evolution of NQB from the Late Triassic to the early middle Epoch of Jurassic Period, including integrated analyzing the characteristic of the key stratigraphic surfaces, the time of the key stratigraphy, regional rock straigraphy, biostratigraphy and chronostratigraphy, sedimentary system and depositional facies. On basis of these analysis, a tectonic evolution model have been established for NQB during from the Late Triassic to the early middle Epoch of Jurassic Period.1. After the systematic surface analysis about main stratigraphy units, we found that:(1) the bottom of Xiaochaka formation was comformity with the middle Triassic in the basin, and in the north margin it was deposited and overlapped on the different period stratigraphy before Triassic.(2) The top surface of Xiaochaka formation developed regionally karst and paleo-karst breccia, and was uncomformity with Nadigangri Formation, these things suggest that NQB in Xiaochaka depositing stage was developed from middle Triassic basin, and then an extensive regression occurred, the deposition was over and erosion come into being.(3) The lithologic assemblage, geochemistry, mixed fossils, and stratigraphy overlapping characteristic of Quemocuo Formation in early middle Jurassic indicted that the uncomformity surface was an extension-unconformity.2. Integrated analysis about stratigraphy division and correlation indicted that:(1) the paleontologic assemblage of Xiaochaka formation show its time was Carian -Norian stage of late Triassic. According to it was overlapped by late Triassic Nadigangri Formation, so Xiaochaka formation should be Carian - early Norian stage.(2) the SHRIMP Zircon U-Pb age of Nadigangri formation volcanic rocks wear vary form 216 to 205 Ma, so its time should be Norian, but maybe extended into Rhaetian Stage.(3) The age of its bottom volcanic rocks, the fossil assemblages of its middle and upper members and overlapped by lower Jurassic, indicted the age of Riganpeicuo Formation was Norian - Rhaetian stage. And the same time, the volcanic rocks geochemistry of Nadigangri and Riganpeicuo formation both reflected that they wear formed in rift tectonic settings. The lower lithologic and surface characteristic, fossil assemblages and its upper maybe was conformity with lower Jurassic, all reflected that the age of Tumengela Formation in Tumen area should be Norian - Rhaetian stage.

论文对晚三叠世—中侏罗世早期盆地的形成与演化开展了研究，包括关键地层界面特征分析、关键地层时代归属分析、区域岩石地层、生物地层和年代地层的综合对比分析、区域沉积体系与沉积相分析、岩相古地理分析，最终建立晚三叠世—中侏罗世早期羌塘盆沉积—构造动力演化模式。1、系统的对各地层单元的界面分析发现：(1)肖茶卡组底界在盆地内部与中三叠统整合关系，在盆地北缘为沉积超覆于不同时代的前三叠系之上：(2)肖茶卡组顶界面发育古岩溶角砾岩，与上覆那底岗日组为岩溶不整合接触，说明肖茶卡组沉积时期的羌塘盆地是在早中三叠世的盆地基础发展起来的，后期出现了广泛的海退事件，使盆地结束沉积并遭受风化剥蚀作用；(3)中侏罗统雀莫错组的岩性组合特征、岩石化学特征、古生物化石混积和地层的沉积超覆现象均表现出裂陷环境下形成的伸展不整合面的特征。2、综合地层划分与对比分析认为：(1)肖茶卡组古生物化石组合反映其时代为晚三叠世卡尼期—若利期，根据其上被上三叠统那底岗日组不整合覆盖，将其时代厘定为卡尼期—若利期早期；(2)那底岗日组火山岩SHRIMP锆石U-Pb年龄在216～205 Ma之间，其时代主要为若利期，可能包含有瑞替期：(3)日干配错组底部火山岩的年龄、中上部化石组合及其被下侏罗统整合覆盖，综合反映的时代为晚三叠世若利期—瑞替期，而且那底岗日组火山岩和日干配错组火山岩的地球化学成分分析反映两者均为引张构造背景下的产物；土门地区的土门各拉组的下部岩性及界面特征、化石组合和上部可能被下侏罗统整合覆盖，综合反映其时代为若利期—若利期。

Basing on detailed field survey and laboratory researches on lithological features, mineralogical composition, geochemical and zircon SHRIMP U-Pb data, together with the mineralogical study of chromitite and mantle peridotite heavy mineral bulk sample, various proceedings and recognitions have been achieved:(1) The mantle peridotite is the remnants of partial melted MOR mantle altered by SSZ fluids.

通过详细的野外调查和室内岩石薄片的岩相学、矿物成分、岩石地球化学和锆石SHRIMP U-Pb同位素年代学，铬铁矿和地幔橄榄岩的人工重砂大样的矿物学研究，取得以下进展和认识：(1)认为康金拉地幔橄榄岩为部分熔融MOR地幔残余，叠加了SSZ流体的改造。

Zirconium Silicicate also widely obtain further application in the line of television profession chromoscope, emulsified glass.

硅酸锆也在电视行业的彩色显像管、玻璃行业的乳化玻璃、搪瓷釉料生产中得到了进一步的应用。

Therefore, above-mentioned age dating together with previous chronologic data led us to conclude that the Sulu HP-UHP nappes have two basements: the Early-Middle Protrozoic (≥2400 Ma) basement in the N. Sulu and the Neoprotrozoic (700-800 Ma) basement in the S. Sulu. The basement ages in the N. Sulu together with its western part of the no-UHP metamorphic area (Laiyang-Penglai) are similar and named by the Jiao-Liao-Korea block belong to the NCP. Besides, the boundary between both of the S. Sulu UHP area and JLKB is along north Wulian and south Haiyangsuo.

北苏鲁超高压变质地区的花岗质片麻岩锆石SHRIMP U-Pb定年表明，变质基底的年龄是2400Ma（或＞2400Ma），并经历了1800～1700Ma和～200Ma的变质事件，研究表明苏鲁高压－超高压变质地体由2个不同时代变质基底组成，北苏鲁的变质基底属于北中国板块胶辽朝地块的一部分，形成时代比南苏鲁基底老得多，其与南苏鲁地块之间的界限位于五莲以北到海阳所以南一线。

Zinc acetate, cobaltous Acetate, zirconium oxychloride and manganese acetate are used as typical experimental materials.

实验以乙酸锌、乙酸钴、氧氯化锆和乙酸锰为典型材料，进行了超临界水热合成制备金属氧化物微粒的研究。

Indeed, the Grand Canal was constructed partly utilizing the pre-existing channels connecting these lowland swamps and lakes (3) Several rivers have produced deltaic forms on the western side of the lakes;(4) A series of artificial islands have been constructed upon the natural bars or barriers located in the lakes and wetlands, and are locally termed Duo, Dun or Wei (meaning artificial bars or crossways in Chinese).

钻孔B/M界线之下(4078 m～4530 m)的泛滥平原河湖相沉积物中局部地段富含铁锰鲕粒，其主要矿物组成为蛋白石、铁的氢氧化物(包括纤铁矿、水纤铁矿、针铁矿、水针铁矿，统称褐铁矿)、铁锰氧化物(包括硬锰矿和软锰矿，以硬锰矿为主)及极少量的细小碎屑矿物(钾长石、蚀变黑云母、含铁白云母、锆石、独居石、金红石和含钛磁铁矿)。

This thesis studies the volcanic tectono-petrofacies, petrology, mineralogy, geochemistry, isotopic chronology, stratum and high-precision SHRIMP zircon U-Pb datings of the Mt.Yandangshan volcano-intrusive complex, and concludes that: Yandangshan volcanic rock units belong to high-K calc-alkaline acid rock associations, mainly ryholitic and trachytic dacitic in composition. They have A/CNK values of 0.9-1.2 (i.e., aluminium saturation and supersaturation), enriched LREE and LILEs and depleted HFSE. Their 8Eu values are 0.11-0.32, indicating a evident fractional evolution of plagioclase crystallization. Their ∑REE varied very limitedly,(87~Sr/(86)Sri ratios and eNd values are 0.7086～0.7095 and -10.20～-9.96 for volcanic rocks, and 0.7087~0.7095 and -7.6～6.92 for the central intrusive facies syenite, which means that all the igneous rocks from Mt. Yandangshan are evolutional products of magmas with the same source, and that they derived mainly from crust, but mixed with mantle components.

本文从火山构造岩相学、岩石学、矿物学、地球化学、同位素年代学、地层学等方面出发，同时结合高精度SHRIMP锆石U-Pb定年，对雁荡山火山岩进行了系统的研究，确定雁荡山火山岩为一套以流纹质和粗面英安质为主体的高钾钙碱性酸性岩石组合，A/CNK值集中在0.9～1.2之间，为铝饱和或铝过饱和类型；富轻稀土元素和大阳离子亲石元素、相对亏损高场强元素：负铕异常明显，δEu值为0.11～0.32，表明岩浆经历了以斜长石为主的强烈结晶分异作用：岩石样品的∑REE变化有限，火山岩样品的~(87Sr/~(86)Sr_i为0.7086～0.7095，εNd为-10.20～-9.96，中央侵入体石英正长岩~(87Sr/~(86)Sr_i为0.7087～0.7095，εNd为-7.6～-6.92，表明它们是同源岩浆分异演化的产物，物质来源主要为陆壳，但有地幔物质参与。

And the iron supported samples prepared by the new method show good activity in the dehydrogenation of ethylbenzene.

新方法制备的负载氧化铁的硅柱磷酸锆在乙苯脱氢反应中亦比传统方法制备的样品表现出更高的催化活性。

In this sea area, the main origin of the detrital minerals is Hainan island, and the characteristics of genetic mineralogy of the zicon and garnet indicate that the detrital minerals mainly come from regional mid-degree-metamorphic area.

3研究区碎屑矿物主要物源是海南岛，锆石和石榴石的成因矿物学特征指示研究区的碎屑矿物可能主要来自中级区域变质物源区。

It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发，分析对称连杆曲线上鲍尔点的产生条件，提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品，年生产总值3000万美元，产品价廉物美、选料上乘、质量保证，深受国内外客户的青睐