锆

2The studies on the appearance typomorphism, physical typomorphism, inner structure typomorphism and chemical typomorphism of the zircon and garnet, and the result of U-Pb isotopic age dating of zircon indicate that the zircons are meta-morphogenic genesis but two or three of them are magmatic genesis and most meta-morphogenic zircons have a basic magmatic zircon core which was generated in Stage of Yanshand and Indo-Chinese epoch. The genesis and origin of the garnet is very complicated. The garnets are main almandine with high Fe and Mg content and were proposed their souce rocks are mostly regional mid-degree-metamorphic rocks.

2研究锆石和石榴石的形貌标型、物性标型、内部结构标型以及成分标型特征和锆石U-Pb同位素测年结果表明，锆石除少数几个为岩浆锆石外，绝大多数是变质锆石，且中间多有形成于燕山-印支期的基性岩岩浆锆石残核；石榴石的成因及来源是比较复杂的，以铁铝榴石为主，且铁铝榴石中Fe、Mg的含量较高，推测其源区母岩主要以中级区域变质岩为主。

Our survey suggested that :(1)the way in which zirconia is added has significant impact to the property of ceramic powders. The flexural strength of the ceramic powders produced by the mix of ZrO2 and leucite crystal is much lower than that of ceramic powders produced by solid phase reaction.

氧化锆-白榴石基烤瓷粉的研究表明：(1)氧化锆的添加方式对瓷粉的性能影响很大，氧化锆与合成的白榴石晶体混合所得的瓷粉的弯曲强度大大低于一次固相反应合成的氧化锆-白榴石烤瓷粉，其弯曲强度甚至还不如没有添加氧化锆的瓷粉。

The influence of different assembled condition such as assembly method, concentration of zirconium source and pH value on the effectiveness of assembly were evaluated via DSC-TG, FT-IR, Uv-vis and SAXRD et al. It showed that the assembly effectivness of uncalcined 3 Si/Zr_10# sample was best.c The optical characteristic, which including light-conduction in infrared band and polarity in visible band, of dip-coating film and membrane assembled zirconia after processing parameters of assembly optimized were observed via FT-IR and Uv-vis. The polarity was characterized by polarizing angle through calculation from light-transmittance, light-reflectance and fresnel coefficient. qualitative analysis showed that the polarity of Si/Zr_10 # dip-coating film assembled was best.d Adopting zirconium oxychloride as zirconium source, CTAB as template, employing different CTAB adding sequence, two mesoporous zirconia samples were prepared. The template effect of two samples was discussed. It showed that the effect of the sample which CTAB adding sequence was same as mesoporous silica film was better. The light-conduction in infrared band of these samples was also studied, which offered comparison to the polarity of zirconium dioxide assembled within mesopore.

结果显示：组装条件优化后的uncalcined 3 Si/Zr_10#厚膜样组装效果最好，其组装液对应的pH值最利于该锆源离子模板交换组装； c选用FT-IR、Uv-vis对组装条件优化后纳米氧化锆/介孔氧化硅厚膜、纳米氧化锆/介孔氧化硅薄膜包括红外导光性、可见光区内的偏光性在内的光学特性进行了分析，其中偏光性以膜层透光性、反光性及菲涅耳系数计算出的偏振角即布儒斯特角表征，定性分析显示，Si/Zr_10#ZrO_2/介孔氧化硅厚膜偏光性最好； d以氧氯化锆ZrOCl_2·8H_2O为锆源，CTAB为模板剂，采用不同的模板剂加入顺序，探索性地制备两介孔氧化锆样，分析了两介孔氧化锆样的模板效果，得出模板剂加入顺序同介孔氧化硅薄膜时介孔氧化锆样的模板效果较好，并分析了所得样品的导光性，为锆氧粒子引起的附加光学特性分析提供了参考和对比。

In the preparation method, zirconium is mixed with benzenephosphonic acid according to the molar ratio of 1:2 to 1:4, and Alpha-zirconium phenyl phosphonate is produced by centrifugal washing after one to five days of crystallization under the temperature of 50 DEG C to 100 DEG C; deionized water is added in order to prepare Alpha-zirconium serosity, the solid content of which is 4 percent to 8 percent; the Alpha-zirconium serosity is granulated and dried by a rotary spray dryer, the feeding speed of the Alpha-zirconium serosity imported into an atomizer is controlled between 20ml/min and 80ml/min, and the temperature of a hot air inlet is controlled between 120 DEG C and 200 DEG C.

本发明涉及一种大比孔容微球α-苯膦酸锆及其制备方法，其颗粒尺寸为10～100μm，比孔容为0.908cc/g，比表面积为125.8m 2 /g；其制备方法是将锆和苯膦酸以摩尔比1∶2～1∶4混合，在50～100℃温度条件下晶化1～5天，离心洗涤得到α-苯膦酸锆；加入去离子水配制α-苯膦酸锆浆液，其固含量为4-8％；将α-苯膦酸锆浆液用旋转式喷雾干燥器进行造粒、干燥，控制α-苯膦酸锆浆液输入雾化器的进料速度为20～80ml/min，控制热风进风口温度为120～200℃；该方法具有操作简单、合成条件温和，对环境污染小等特点，该材料应用于催化、催化剂载体、吸附、离子交换等方面。

The main products are ilmenite, zircon, rutile, xenotime, zircon used for glass screen of color picture tube, and zircon powder used for ceramics and foundry, etc.

主要业务是从事稀有金属海滨砂矿采、选、深加工、行业技术开发和国际贸易等，主要产品有钛铁矿、锆英石矿、金红石矿、独居石矿、磷钇矿、彩色显像管玻屏用锆英石粉、陶瓷和铸造用系列锆英石粉、低熔点玻璃用锆英石粉和高白度、高纯度超细锆英石粉等。

With the same zirconium concentration,the absorbance of zirconyl oxyhalide solution (λ=664nm)prepared in HCl was larger than that from pure zirconyl oxyhalide solution.

发现对于相同锆浓度的溶液，高酸度的锆贮备溶液中的锆与偶氮胂Ⅲ形成的化合物的吸光度(λ=664nm)要大干仅由氧氯化锆配制的锆贮备溶液中的锆与偶氮胂Ⅲ形成的化合物的吸光度。

According to crystal shape and color, 4 types of zircon in metarhyolite have been identified: inherited, magmatic, metamophic and mixed zircon.

1根据锆石的晶形和颜色，将本区流纹岩中的锆石分为继承锆石、岩浆结晶锆石、变生锆石以及它们之间的混合锆石。

According to the metamorphic fluid involved, metamorphic zircon can be divided into five subtypes: metamorphic recrystallization via solid-state transformation, replacement alteration or dissolution reprecipitation, and metamorphic growth corresponds to chemical precipitation from aqueous fluid or hydrous melt.

根据参与锆石改造的变质流体性质，进一步可将变质锆石区分为五种不同类型，即固态重结晶锆石、交代重结晶锆石、溶解重结晶锆石，以及富水流体和含水熔体中的生长锆石。

The mian works are as follows:(1)By coprecipitation technique and coprecipitation- gel technique the nano zirconia powder was produced, factors affecting the properties of nano zirconia powder such as pH and the content of stabilizator are analyzed;(2)By the new pressless sintering process, the nano zirconia ceramic was produced, factors which can affecting the properties of nano zirconia sinter body such as moulding press and the sinter temperature are analyzed;(3)By the microtherm pressless sintering process, the nano copper added functional zirconia ceramic composite was produced, microscopic dimensionality and electric properties of such sinter body and the factors affecting such sinter body are analyzed;(4)By the self-invented "external albumen coating" technique the zirconia powder was successfully coated by carbon in the corresponding sinter body, which can help solve the traditional aggregation problem to some degree;(5)Based on analyze the characteristics in the nano powder sinter process, the "three-ball sinter model" was proposed, for the relationship between the relative density and porosity of sinter body, by mathematical fitting, such model was successfully verified.

本研究比较系统地研究了纳米氧化锆陶瓷的合成与成型机理，特别是讨论了纳米氧化锆陶瓷的稳定性，为防止纳米颗粒在外场作用下的团聚和长大提供了理论基础和实验数据，具体工作有以下几方面：(1)采用共沉淀法和共沉淀-凝胶法制备了纳米氧化锆粉体，并分析了pH值和稳定剂含量对粉体性能的影响；(2)采用新型无压烧结工艺制备了纳米氧化锆陶瓷，并分析了成型压力和烧结温度对烧结体性能的影响；(3)采用低温无压烧结工艺制备出添加纳米铜的功能性纳米氧化锆复合陶瓷，并分析了烧结体的微观尺度和电学性能的变化以及影响因素；(4)通过自创的&鸡蛋清外敷法&在真空镀膜台上对纳米氧化锆粉体进行包敷碳颗粒的表面处理，并采用真空烧结工艺制得相应烧结体，初步开始解决陶瓷烧结过程中团聚长大这一传统难题；(5)通过分析纳米颗粒在制备烧结体过程中的实际特点，提出了&三球烧结数学模型&，通过引入坯体相对密度和孔隙率的相对关系分析并通过自行编写的数学拟合软件，验证了这一数学模型。

All the ligands and complexes have been characterized with ~1H-NMR, MS and EA.X-Ray single crystal diffraction reveals that zirconium complex containing the tert-butyl substituted N_2O_2 ligand is an oxo- and hydroxyl-bridged dinuclear structure, which is possibly formed by partial hydrolysis of chlorides at one of the zirconium centers. A tetranuclear zirconium complex has been obtained and chacaterized, which is formed by complete hydrolysis of the chlorides at the zirconium centers.

通过研究配合物的单晶结构，我们发现叔丁基取代的不对称N_2O_2配体与ZrCl_4反应生成的锆配合物为氧桥和羟基桥连接的双核锆配合物，中间过程涉及单核锆配合物中氯原子部分水解，并得到氯原子部分水解的双核锆配合物和全部水(来源：8e6eAB67C论文网www.abclunwen.com)解的四核锆配合物的晶体结构，在晶体培养过程中发现双核锆配合物能够以手性自发拆分结晶析出。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。