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Olivine-type LiFePO4 are recently expected to have a bright future as a potential cathode material of large scale moveable lithium ion batteries for its high theoretical capacity(170 mAh/g)and voltage(about 3.5 V versus Li/Li+),good stability both at room temperature and high temperature,low cost and environmental benignancy.

橄榄石型LiFePO4具有170 mAh/g的理论比容量和约3.5 V的电压、较好的常温和高温稳定性、低廉的价格和优良的环保性能,有望作为大型移动式锂离子电池的正极材料。

The thermodecomposition of Li〓CO〓 charge was experimented and studied in a specially made vacuum furnace. The relationship of decomposition rate with temperature, pressure and time were obtained. The important principle of decomposition rate effected by pressure was acquired and conception of critical decomposition-pressure was presented.

在特制的真空炉内对碳酸锂物料真空分解进行了试验,得到了分解率与温度、压力、时间的关系;得到了分解率受压力影响的重要规律,据此提出了分解临界压力的概念,总结出了分解临界压力与温度的关系。

Cephalotaxine ester of 2-oxo-6-methylheptanoic acid was treated with lithium diisopropylamide and Me O-(1-methoxyisopropyl)glycolate to give a mixture of homoisoharringtonine and its stereoisomers with 56% yield. The four stereoisomers separated by TLC showed identical mass spectra and almost superimposed IR but with different 1H NMR spectra. The configuration of the 2'-C and 3'-C of the four isomers were postulated based upon their 1H NMR spectra as compared with the 1H NMR spectra of isoharringtonine and its stereoisomers.

2-氧代-6-甲基庚酰基三尖杉碱(3)与0-(1-甲氧基异丙基)羟基乙酸甲酯(4)在强碱性试剂二异丙胺锂存在下,起亲核加成反应,反应中间体5在室温用酸性丙酮水解,得到一种新的三尖杉酯类生物碱一一高异三尖杉酯碱(6c)及其立体异构体(6a、6b、6d)的混合物,产率56%、通过制备薄层层析分得这四个立体异构体,它们的1H NMR和异三尖杉酯碱及其立体异构体的1H NMR类似,推定了它们的绝对构型。

Based on the Kirchhoff law, according to the relationships between various technical parameters and main specifications (temperature resolving power, temperature measurement sensitivity, relative temperature measurement sensitivity, and temperature measurement accuracy), an optimal method of the practical real-time temperature measurement system using laser diode and LiTaO3 pyroelectric detector is proposed.

基于Kirchhoff定律,依照测温系统的各主要技术参数与各主要技术指标(温度分辨力、测温灵敏度、相对测温灵敏度及测温准确度)之间的关系,对利用激光并采用钽酸锂热释电探测器作光电转换器件的实用化实时测温系统的工作波长进行了进一步的优化设计。

During the study, many factors, such as: density of H2SO4 solution, reaction ratio of materials, reaction temperature and time, are studied how to effect the extraction yield of Li2O. After these studies, the optimal conditions are summarized: 50% H2SO4 solution and lepidolite powder which has been grounded to a particle size of 80~100microns, react at 2:1ratio,120℃ temp for 8h~10h.

在此过程中主要探索了硫酸水溶液的浓度对氧化锂提取率的影响,以及硫酸溶液与云母粉的反应配比、反应温度、反应时间对提取率的影响;研究了提取液pH值的调节对溶液中金属离子的影响。

The saturated solution can be directly recycled in distillation and turned into renewed solvent which has the same dissolving performance as the untapped one.After disparting from aluminum foil, the mixture of LiCoO_2 and acetylene black was lixiviated to extract cobalt ion. The leaching efficiency of cobalt was shown to be as high as 90% in the lixiviation experiments.

对钴锂膜上与铝箔脱离后的LiCoO_2、乙炔黑混合粉末,通过浸出钴的实验研究,确定了盐酸体系为合适的浸出体系,在盐酸浓度为6.67mol/L,反应温度80℃,反应时间50分钟的最优化浸出条件下,钴金属的浸出率可达90%以上。

Fly ash and LiOH have no significant effect on controlling expansion of concrete microbar with PL limestone.

利用ASR和ACR对粉煤灰等混合材及含锂化合物的不同响应,特别是LiOH的抑制ASR膨胀和引发ACR膨胀的双重效应,在实验室可以快速区别同时合有白云石和石英的灰岩类集料的活性来源。

A preparation method of nickel oxide-base cathode of fused carbonate fuel cell is to select alkali earth metal oxide, transition metal oxide and rare-earth metal oxide, mix with carbonyl nickel powder in the proportion of 0.01-15.00 mol%, add assistant and mix even into a slurry; after the slurry is formed into a biscuit by doctor-blade casting, sinter it into a multi-porous nickel plate; dissolve lithium nitrate and cobaltous nitrate with mole ratio of Li:Co-1:1 and citric acid or PVA in the distilled water to make a solution with Li of 0.00-0.5 mol/L; immerse the multi-porous nickel plate or nickel oxide plate in the solution, keep for 10-60 minutes under vacuum below 200 millibar, then dry in an oven at 75 degrees centigrade further transfer to a crucible electric furnace preheated 650 degrees centigrade for keeping the temp.

要約 熔融碳酸盐燃料电池氧化镍基阴极的制备方法属于燃料电池领域。选取碱土金属氧化物、过渡金属氧化物和稀土金属氧化物,按0.01-15.00mol%的比例与羰基镍粉混合,加入助剂,混合均匀成浆料;混合浆料流延成型为素坯后烧结为多孔金属镍板;将摩尔比为Li∶Co=1∶1的硝酸锂和硝酸钴以及柠檬酸或聚乙烯醇溶于蒸馏水中,制成为0.005-0.5mol/L的溶液;将多孔金属镍板或氧化镍板浸入溶液中,在真空度低于200毫巴下保持10-60分钟;置于75℃的烘箱中烘干,转移至预热到650℃坩埚电炉中保温1-10小时;将此过程重复一次或多次即可。

Through the calculating of doping materials, we can see electrons are easy to transation or transfer, which strengthens the conduction properties of materials. Especially the stability of materials doping with Mn or Al is more strong, and the ionizing energy is more lower. These indicate that the electrons in the outest orbit are easier to lose, that is to say the Li+ ions are easier to imbed into materials. The discharge voltage of material doping with Co decreases, the oxidization of electrolyte is more difficult, and the cycling performance is improved.

通过对掺杂材料的计算可见掺杂后电子更容易跃迁或转移,增强了材料的导电性能,其中掺锰和掺铝的材料稳定性更强,电离能降低,说明失去最外层电子更容易,也就是说锂离子在材料中嵌入和脱出更加容易;掺钴之后材料的放电电压降低,电解液氧化的可能性减小,循环性能得到改善。

The relationship of OEO chain length with crystallization,phase structure and solvency to the Li salt of eopolymers were investigated.A proposal was offered for a rational design of this kind of eopolymers.

通过多种手段考察了不同长度的OEO链段对聚合物的结晶能力、相结构以及其对锂盐溶解能力的影响,并讨论了此类材料的合理结构设计原则。

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With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务,乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐,因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。

Closes the eye, the deep breathing, all no longer are the dreams as if......

关闭眼睛,深呼吸,一切不再是梦想,犹如。。。。。。