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Linear alkyl benzenes and linear alkyl dimethyl benzenes, prepared by the alkylate reaction of linear alpha olefin with benzene or dimethyl benzene which were sulfonated by chlorosulfonic acid and then neutralized to produce linear alkyl benzene sulfonates and linear alkyl dimethyl benzene sulfonates.

本文以一定链长的直链α-烯烃分别与苯和混合二甲苯为原料制备了直链烷基苯和烷基二甲苯,经氯磺酸磺化,中和可得到具有一定链长的直链烷基苯磺酸盐和直链烷基二甲苯磺酸盐。

The formed long and linear chain alkyl benzene changes into benzene methyl and alkene through β-scission and monomolecular homolysis, and then benzene methyl shifts to the position of α-Carbon in the long chain alkyl benzene through H-transfers.

已形成的长直链烷基苯通过β分裂、单分子均裂形成苯甲基、烯烃,苯甲基通过氢转移到长链烷基苯的α碳上,烯烃再与α碳结合形成带支链的烷基苯。

The biosynthesis of the quinoid nucleus are the same in all coenzyme Qs. The biosynthesis of the isoprenoid side chain determine the kind of coenzyme Q.

芳香环的合成在所有的辅酶Q族物质中都是相同的,异戊烯基侧链的长度则决定了辅酶Q的种类,这里存在一个关键酶,即异戊烯焦磷酸合成酶。

The alkaloids were studied by gas chromatography coupled to mass spectrometry. Six major venom alkaloids were detected in worker venom which are all trans 2-methyl-6-alkyl or alkenyl pepdine according to mass spectral data and relative report on S.invicta.

通过保留时间和质谱离子碎片数据,并与国外相关报道比较分析得出:入红火蚁毒液中主要成分为2-甲基-6-烷基或烯基哌啶生物碱,仅有6位取代烃基碳链长短和烯键有无及顺反异构的差异。

With the aim of enhancing the nonlinear optical property of poly, poly[(thiophene-2,5-diyl)p-(N,N-dimethylamino) azobenzylidene] is prepared from 4-aldehyde-4'-dimethylamino azobenzene and thiophene through condensation polymerization reaction.

为了提高聚噻吩甲烯的非线性光学性能,通过4-醛基-4'-二甲胺基偶氮苯和噻吩的缩聚反应,合成了聚噻吩对二甲氨基偶氮苯甲烷,再用PTDMAAB与四氯苯醌发生脱氢反应合成了侧链含偶氮的聚噻吩甲烯。

The copolymer of N isopropylacrylamide and acrylamido azobenzene was synthesized for the study of the effect of the photoisomerization of a water soluble copolymer containing azobenzene groups on the photocontrolled release behavior of liposomes.

为了研究侧链含有偶氮苯基的水溶性共聚物的光异构化对脂质体内包容物的光控释放的影响,设计合成了N-异丙基丙烯酰胺和丙烯酰胺基偶氮苯的共聚物。

The catalyst combined with MAO or Al(i-Bu_3, AlEt_3 to form copolymerization active species, which was responsible for copolymerizing the ethylene andα-olefins to prepare branched polyethylene.

二酮锆/MAO Al(i-Bu_3、AlEt_3可以形成乙烯与α-烯烃的共聚活性中心,催化乙烯与特定链长的α-烯烃共聚得到了支化聚乙烯。

A novel polymeric organic thermal stabilizer for PVC was designed and synthesized by acryloylthiourea grafting on polystyrene which was nitrified by HNO3 and then reducted by Sn powder to amine.

以经部分硝化和还原的低分子量聚苯乙烯为母链,利用其胺基和丙烯酰基异硫氰酸酯加成,合成了一种新型有机高分子型PVC 热稳定剂——丙烯酰基硫脲接枝聚苯乙烯,其结构经IR和元素分析表征。

To improve the effect of CDCA on dissolving cholesterol gallstone, the water-soluble copolymers as polycarboxylic acid of comb-like copolymers and C_(60)-PCC were synthesized, which being used for modification of CDCA and strengthening effects of CDCA on dissolving the cholesterol gallstones by their entropy-repelled properties of comb-shaped side chains in buffers of phosphate and in model bile.The design theory of polymer was mainly employed to synthesis the conjugate of PCC-CDCA and C_(60)-PCC-CDCA by C_(60), polyoxyalkylene allylalkyldiether and maleic anhydride, which were copolymerized with AIBN as initiator, and then PCC or C_(60)-PCC were reacted with CDCA. The structures of the copolymers and the conjugates of PCC-CDCA and C_(60)-PCC-CDCA were confirmed with IR, TLC and TEM. The dissolving effects and the dissolution kinetics mechanism of cholesterol gallstone was inverstigated in PBS and in model bile of different cholesterol saturated index at pH7.4, including PCC-CDCA or C_(60)-PCC-CDCA.

利用高分子设计理论,以烯丙基聚氧乙烯基醚、顺丁烯二酸酐、C_(60)和CDCA为原料,以偶氮二异丁腈为引发剂,合成具有梳状侧链结构的梳状共聚物-CDCA结合物和C_(60)-梳状共聚物-CDCA结合物,以IR、TLC和TEM法表征共聚物的结构,并在pH7.4的PBS液和不同胆固醇饱和指数的模拟胆汁中进行溶石效果的研究,探讨在PBS液和不同CSI的模拟胆汁中结合物溶解胆固醇结石的效果和溶解动力学机制。

The result of potassium malonyloxyborohydride as a new hydroboration reagent reacts with terminal alkenes and alkynes is described.

介绍新的硼氢化试剂丙二酰氧基硼氢化钾与链端烯炔烃的作用,烯烃的硼氢化物在PTC条件下,插入∶CCl2 ,可得饱和羧酸;炔烃则难以与之硼氢化。

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