链烯

Much olefin of conjugate of discovery short cable length (number of conjugate double key is less than 6) to lengthen and increase quickly of time as degradation, grow catenary conjugate much olefin at the same time (the growth rate that number of conjugate double key is more than or is equal to 6) is far be less than conjugate of short cable length much olefin.

发现短链共轭多烯烃(共轭双键数小于6)随着降解时间的延长而急剧增加，同时长链共轭多烯烃(共轭双键数大于或等于6)的增长速率远小于短链共轭多烯烃。

In this study, main chain of 4,4'-Biphenol combine different side chains to discuss polymer ~ polymer which synthesizes by the difference of structure of 1-Bromobutane、1-Bromoocatane、1-Bromododecane.To examinate luminance property and judge the correction for the structure of polymer ~ polymer by FT-IR、NMR-1H、UV、PL, in the meanwhile,to investigate into radiation wavelength under the condition of different side chains.

中文摘要 1。本实验是利用4，4'-Biphenol为起始物，与Allyl bromide反应，产生丙烯基芳基醚化合物，再利用克莱森重排反应将丙烯基转至邻位，然后在将OH基转变为不同链长的烷基醚合成出聚合物耤I），以FT-IR、NMR-1H、UV、PL测定其发光性质及判断产物结构是否正确，并探讨化合物在不同侧链之条件下，比较其放射波长。

From the femur bone density analysis of protein expression, we can see that light chain lactoferrin, annexin decreased and the expression of enolase, ATP synthase, acetyl-coenzyme A reductase, the expression of troponin, may be related to ovariectomized femoral bone density in osteoporosis-related happened; strong bone of the femoral osteoporosis Po intervention effect may be related to reduced enolase, ATP synthase, troponin, CK-MB, acetyl phosphoglycerate enzyme, the expression of myosin, and the increase in lactoferrin light chain, pyruvate kinase isoenzyme, protein expression crown.

从股骨密质骨蛋白质组表达分析可知，乳铁蛋白轻链、膜联蛋白A3的表达下降及烯醇化酶、ATP合酶、乙酰辅酶A还原酶、肌钙蛋白的表达增强，可能与去卵巢后股骨密质骨骨质疏松的发生相关；强骨宝对股骨骨质疏松的干预效应可能与下调烯醇化酶、ATP合酶、肌钙蛋白、肌酸激酶同工酶、磷酸甘油酸变味酶、肌球蛋白的表达，和上调乳铁蛋白轻链、丙酮酸激酶同工酶、冠蛋白的表达有关。

From the influnce of pH change in water on the copolymerization, the copolymerization mechanism was provided. The copolymerization mechanism is that there is hydrogen bond, which can enhance the copolymerization, between acrylic acid and crotonaldehyde at low pH and there is"Charge Transfer Complex", which gives the more crotonaldehyde in P (acrylic acid-crotonaldehyde), between acrylic acid and crotonaldehyde at high pH.

根据共聚合反应介质pH值变化对丙烯酸-丁烯醛共聚合反应的影响，提出了丙烯酸-丁烯醛共聚合反应机理，即在低pH值时，丙烯酸、丁烯醛之间可形成氢键，从而使共聚合体系具有较高的聚合反应速率和转化率；在较高pH值时，丙烯酸、丁烯醛之间则有电荷转移络合物形成，从而使共聚物中含有更多的丁烯醛链段。

From the experiment discovered for the first time the dimethyl ether may substitute CO to take the chain-carrying agent of the peroxy free radical chemistry amplifier system, and optimized the CH_3OCH_3-NO-HO_2 chemistry amplifying system determination condition, the CH_3OCH_3 best density is 1.876 ppmv, the NO best density is 1.3ppmv, and obtained this method chain length CL=124, 5 parallel determinations densities of HO_2 are the 44.0pptv, the relatively standard deviation is smaller than 4%; Although chemistry box model computed result indicated the dimethyl ether, the ethene, the propene and the ethanol all can take the chain-carrying agent of the peroxy free radical chemistry amplifier system, and their simulation chain length all grows up compared to the CO-NO-HO_2 chemistry amplifying systems, but experiments proved the ethene, the propene and the ethanol have not suit the chain-carrying agents.

首次从实验上发现二甲醚可以替代CO作为过氧自由基化学放大系统的链传递试剂，并优化了CH_3OCH_3-NO-HO_2化学放大系统的测定条件，CH_3OCH_3的最佳浓度是1876ppmv，NO的最佳浓度为1.3ppmv，并得到了这一方法的链反应长度(CL=124)，5次平行测定浓度为44.0pptv的HO_2自由基，相对标准偏差＜4％；虽然化学盒子模式计算结果表明二甲醚、乙烯、丙烯和乙醇都能作为过氧自由基化学放大系统的链传递试剂，并且它们的模拟链长都比CO-NO-HO_2化学放大体系的链长大，但是实验证明乙烯、丙烯和乙醇不适合作为过氧自由基化学放大系统的链传递试剂。

Finally confirmed that,The thighbone and the osteoporosis morbidity is possibly connected protein 6, respectively are: The lactoferrin light chain, membrane association protein A3, the enolase, ATP gather the enzyme, the acetyl coenzyme A reductases, the myo calcium protein; The lumbar vertebra and the osteoporosis morbidity is possibly connected protein 5, respectively are: The actin, the keratin, the enolase, ATP gather the enzyme, the myosin; The thighbone and the strong bone valuable curative effect is possibly connected protein 9, respectively are: The enolase, ATP gather the enzyme, the myo-calcium protein, the creatine activating enzyme isozyme, the phosphoglyceric acid change flavor the enzyme, the myosin, the lactoferrin light chain, the pyruvic acid activating enzyme isozyme, the crown protein; The lumbar vertebra and the strong bone valuable curative effect are possibly connected protein 8, respectively are: The carbonic anhydrase, the actin, the αB-crystal protein, 3-phospho-glycerol aldehyde oxidase, the serum albumin, ATP gather the enzyme, the myosin, the enolase.

最后确认：股骨与骨质疏松发病可能相关的蛋白6个，分别为：乳铁蛋白轻链、膜联蛋白A3、烯醇化酶、ATP合酶、乙酰辅酶A还原酶、肌钙蛋白；腰椎与骨质疏松发病可能相关的蛋白5个，分别为：肌动蛋白、角蛋白、烯醇化酶、ATP合酶、肌球蛋白；股骨与强骨宝疗效可能相关的蛋白9个，分别为：烯醇化酶、ATP合酶、肌钙蛋白、肌酸激酶同工酶、磷酸甘油酸变味酶、肌球蛋白、乳铁蛋白轻链、丙酮酸激酶同工酶、冠蛋白；腰椎与强骨宝疗效可能相关的蛋白8个，分别为：碳酸酐酶、肌动蛋白、αB-晶体蛋白、3-磷酸甘油醛脱氢酶、血清白蛋白、ATP合酶、肌球蛋白、烯醇化酶。

The results show that both norbornenic and cyclopentenic double bonds are involved in the polymerization. The propagation on the NB double bond generates structural unit I by direct addition and unit II by carbocation rearrangement, respectively. Similarly, the propagation on the CP double bond produces structural unit III by direct addition and unit IV by transannular rearrangement, respectively.

结果表明， DCPD分子的降冰片烯双键和环戊烯双键均参与了聚合反应并根据不同链增长机理产生四种链结构单元：通过NB双键的链增长反应可生成直接加成结构单元I和重排结构单元II，通过CP双键的链增长反应生成直接加成结构单元III和跨环重排单元IV。

Alkenes have one or more double bonds between carbon atoms, where two pairs of electrons are shared.

链烯有一个或多个共价键，即碳原子分享两对电子。

The progress in alkylation reaction of benzene with long chain alkenes was introduced from the two aspects of catalyst research and reaction technology.

从催化剂研究和反应技术两方面介绍了苯与长链烯烃烷基化反应技术的研究开发进展。

When the reaction was finished, the ligand was extracted with CH2Cl2 and precipitated upon addition of diethyl ether followed by filtration.

2配体2在丙酮/水体系中催化/又种烯烃的AD反应，非链端烯烃的立体选择性(80一99%ee)明显优于链端烯烃(51一62%ee)。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新