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Table 1 medical packaging materials, containers, scope of pharmaceutical packaging materials, containers, in the form of the name preparation notes plastic bottle kalidehydroandrogropholidi = 50ml material with PP, LDPE Infusion bags, kalidehydroandrogropholidi = 50ml material is PVC, polyalkene glass infusion bottle 50ml clorsulon = injection bottle kalidehydroandrogropholidi 50ml, kalidehydroandrogropholidi = 50ml-molded, control of glass bottle kalidehydroandrogropholidi kalidehydroandrogropholidi 50ml kalidehydroandrogropholidi 50ml ampule medical plastic bottle of tablets, capsules, tablets, colour.10pills glass ampoules, pills and capsules, syrup, oral solution, nanosuspensions, immunoembolization, tincture, linimentum, lotio hard PVC medicinal Tablet and capsule-plastic blister packaging PVC/PE/PVDC medicinal compound hard Tablet and capsule-plastic blister packaging Composite PVC/PVDC medicinal Tablet and capsule hard-plastic blister packaging cold metal forming hard medicinal compound tablets, capsules, suppository materials have nylon/aluminium/PVC double aluminum packaging Tablet and capsule PVC/hard LDPE medicinal compound tablets, capsules, suppository glass bottle ciinincal ciinincal ciinincal plastic bottle medicinal ciinincal medicinal eardrops plastic bottle eardrops medicinal nasal drops plastic bottle nose drops for external use liquid medicinal plastic bottle tincture, linimentum, lotio koufuye of medicinal plastic bottle syrup, oral solution, nanosuspensions, immunoembolization glass control oral bottle syrup, oral solution, nanosuspensions, immunoembolization packaging for medicine bag laminating film, puivis bletillae, feian and Tablet foil Tablet and capsule of unguentum Al fighting、smoke aluminium pipe, oculentum, puivis bletillae, Tin aerosolon, nabulization materials have aluminum, plastic valve pyritionate, nabulization stopple kalidehydroandrogropholidi 50ml, 50ml clorsulon = material bromide, CIIR synthesis of oprene 50ml clorsulon = gasket aluminium caps combination Cap koufuye falchion, kalidehydroandrogropholidi 50ml, 50ml prestrain kalidehydroandrogropholidi = potting needle kalidehydroandrogropholidi 50ml desiccant tablets, capsules, pills and aluminium bottles vinpocetione polyethylene film and bag vinpocetione b, package management and standards on the management of the drug packaging mainly has two modes: a mode of government management, such as Singapore, Indonesia adopted a market access system, United States, Canada, the European Union through the implementation of the medicine on the packaging of the strict management, that is, the drug registration, declare to use medical packaging of related materials; Government departments on the packaging manufacturer production system to carry out spot checks.

表1 药品包装材料、容器适用的范围药用包装材料、容器名称制剂形式备注塑料输液瓶注射剂≥50ml 材料有PP、LDPE 输液膜、袋注射剂≥50ml 材料有PVC、聚烯烃玻璃输液瓶注射剂≥50ml 冻干注射剂瓶注射剂0ml、注射剂≥50ml 模制、管制玻璃注射剂瓶注射剂0ml 安瓿注射剂0ml 口服固体药用塑料瓶片剂、胶囊、丸剂玻璃药瓶片剂、胶囊、丸剂、糖浆剂、口服溶液剂、混悬剂、乳剂、酊剂、搽剂、洗剂 PVC药用硬片片剂、胶囊铝塑泡罩包装 PVC/PE/PVDC药用复合硬片片剂、胶囊铝塑泡罩包装 PVC/PVDC药用复合硬片片剂、胶囊铝塑泡罩包装冷冲压成型药用复合硬片片剂、胶囊、栓剂材料有尼龙/铝/聚氯乙烯双铝包装片剂、胶囊 PVC/LDPE药用复合硬片片剂、胶囊、栓剂玻璃滴眼剂瓶滴眼剂药用滴眼剂塑料瓶滴眼剂药用滴耳剂塑料瓶滴耳剂药用滴鼻剂塑料瓶滴鼻剂外用液体药用塑料瓶酊剂、搽剂、洗剂口服液体药用塑料瓶糖浆剂、口服溶液剂、混悬剂、乳剂玻璃管制口服液瓶糖浆剂、口服溶液剂、混悬剂、乳剂药品包装用复合膜、袋散剂、颗粒剂、片剂药品包装用铝箔片剂、胶囊铝管、铝塑管软膏、眼膏剂、散剂、罐气雾剂、喷雾剂材料有铝、塑料阀门气雾剂、喷雾剂胶塞注射剂0ml、注射剂≥50ml 材料有溴化、氯化丁基橡胶合成聚异戊二烯垫片注射剂≥50ml 铝盖、铝塑组合盖口服液、注射剂0ml、注射剂≥50ml 预灌封注射针注射剂0ml 干燥剂片剂、胶囊、丸剂铝瓶原料药聚乙烯膜、袋原料药二、包装管理及标准各国对药品包装的管理主要有两种模式:一种模式是政府管理,如新加坡、印度尼西亚采取市场准入制的方式,美国、加拿大、欧盟通过对药品的管理实施对药品包装的严格管理即在药品注册时,申报所使用药品包装的相关材料;政府部门对药品包装生产企业的生产体系进行现场检查。

AlN MSM devices were fabricated on AlN epitaxial thin film deposited on GaN/Sapphire substrates using helicon sputtering system at the low temperature of 300°C. The device characteristic was found to be improved by in situ metallization of Al electrodes. The extremely low dark current (1.39pA at 20V), the ideal factor (1.0125) and the Schottky barrier height (0.916eV) are superior compared to those of AlN MSM in the literature. When the device was illuminated by the 150W D2 lamp, the ratio of the induced photocurrent to dark current is more than 2 orders of magnitude. The illumination effect also shows the linear relationship between the radiation power and the photo current for the MSM devices, indicating the potential applicability for deep UV sensors.

氮化铝金属-半导体-金属光侦测器则是用In situ metallization制程,利用低温回旋溅镀法在氮化镓/蓝宝石基板上沉积之氮化铝,再直接溅镀金属铝作为指叉电极,比较目前文献制作出来的氮化铝MSM元件,可得到很好的元件金半接面之理想因子1.0125,算出萧特基能障高度为0.916eV,并有很低的暗电流为1.39 pA,提升了元件的特性,使用150 W氘灯入射,光暗电流差距可到两个order,且元件之光电流与入射光功率呈线性,显示所制作之氮化铝MSM元件,很适合针对深紫外光波段侦测。

The main products are: calcium sulfate / calcium nitrate / calcium carbonate / copper sulfate / chloride, copper / zinc sulfate / nitric acid zinc / zinc chloride / potassium sulfate / potassium chloride / potassium bromide / potassium aluminum sulfate / potassium dihydrogen phosphate / 2 of potassium hydrogen phosphate / sodium bromide / sodium chloride / sodium nitrate / sodium fluoride / trisodium phosphate / sodium dihydrogen phosphate / disodium hydrogen phosphate / crystallization of sodium carbonate / anhydrous sodium carbonate / aluminum sulfate / nitrate aluminum / crystallization of aluminum chloride / aluminum hydroxide / nitrate Fe / hydrobromide / oxalic acid / boric acid / citric acid / barium chloride / Azone / magnesium sulfate / magnesium nitrate / magnesium chloride / ammonium chloride / ammonium sulfate / Bifluoride ammonium / ammonium aluminum sulfate / ferrous ammonium sulfate / ammonium dihydrogen phosphate / diammonium hydrogen phosphate / bromide / tetrabutylammonium bromide / chloride, nickel / nickel nitrate / sulfate nickel / cadmium chloride / cadmium sulfate / nitrate Cadmium / Cadmium Carbonate / Strontium / strontium nitrate / sulfuric acid manganese / manganese chloride / 50% manganese nitrate solution / stannous chloride / zinc chloride, such as crystallization of the four largest packing of chemical reagents AR and CP level.

主要产品有:硫酸钙/硝酸钙/碳酸钙/硫酸铜/氯化铜/硫酸锌/硝酸锌/氯化锌/硫酸钾/氯化钾/溴化钾/硫酸铝钾/磷酸二氢钾/磷酸氢二钾/溴化钠/氯化钠/硝酸钠/氟化钠/磷酸三钠/磷酸二氢钠/磷酸氢二钠/结晶碳酸钠/无水碳酸钠/硫酸铝/硝酸铝/结晶三氯化铝/氢氧化铝/硝酸铁/氢溴酸/草酸/硼酸/柠檬酸/氯化钡/氮酮/硫酸镁/硝酸镁/氯化镁/氯化铵/硫酸铵/氟化氢铵/硫酸铝铵/硫酸亚铁铵/磷酸二氢铵/磷酸氢二铵/溴化铵/四丁基溴化铵/氯化镍/硝酸镍/硫酸镍/氯化镉/硫酸镉/硝酸镉/碳酸镉/碳酸锶/硝酸锶/硫酸锰/氯化锰/50%硝酸锰溶液/氯化亚锡/结晶四氯化锌等大包装化学试剂的AR和CP级别。

The Si/Al ratio of NaY molecular sieve was determined by an empirical formula of lattice constant obtained by extension function method of X-ray diffraction and framework Si/Al ratio of NaY molecular sieve determined by solid nuclear magnetic resonant spectrum method.

前言晶胞参数是决定晶体结构的重要参数之一,Na Y超稳分子筛属立方晶系,由于 Na Y超稳分子筛骨架硅铝比受许多条件的影响,如投料比、晶化温度、晶化压力和晶化时间等。通过研究发现分子筛骨架的硅铝比与其晶胞参数相关,而分子筛的硅铝比可作为合成分子筛产品质量的控制指标 [1] 。

Then, the application of MCM-22 in OATS process was investigated. It was found out that with SAR increasing, thiophen conversion first increased and reached maximum at SAR of 75 (98.3%), and then reduced. A postulation was raised that the alkylation reaction mainly occurred at the external surface of MCM-22 zeoltie. The application of MCM-22 in ABLPG process was also investigated.

考察了MCM-22在模拟FCC汽油烷基化脱硫方面的应用,研究表明,随着硅铝比的增加,其噻吩烷基化活性在硅铝比为75时达到最大(98.3%),硅铝比继续增加,活性则不断降低,提出了噻吩烷基化过程主要发生在分子筛外表面的观点。

The main steps include as follows: CO2 is led into the mother liquor of sodium meta-aluminate to carry out carbon content decomposing; the primary separation between the aluminum and the gallium is realized by primary carbonatation to filter out sodium hydroxide; secondary carbonatation is carried out on the filtrate to obtain the deposit of the complex salt of gallium and aluminum; a sodium carbonate crystal is obtained after the filtered filtrate is condensed and vaporized; the deposit of the complex salt of gallium and aluminum is dissolved in the mother liquor of sodium meta-aluminate; the processes are repeated until the proportion of gallium and aluminum in the complex salt of gallium and aluminum is larger than 1/340; then the complex salt of gallium and aluminum is added into the NaOH liquor and electrolyzed, thus obtaining the metal gallium with a purity larger than 99.9 percent which reaches the level of 3; simultaneously, the byproducts of the aluminum hydroxide and the sodium carbonate during the process of carbonatation by steps are obtained.

主要步骤包括:向铝酸钠母液中通入CO 2 进行碳分分解,一次碳酸化实现铝镓的初次分离;过滤出氢氧化钠,滤液进行二次碳酸化获得镓铝复盐沉淀,过滤后滤液经浓缩蒸发获得碳酸钠晶体,铝镓复盐沉淀溶解在偏铝酸钠母液中,重复上述过程直至铝镓复盐中的镓铝比例大于1/340,将其加入到NaOH溶液中,电解可获得纯度>99.9%的金属镓,达到3N级水平同时在分步碳酸化的过程中获得氢氧化铝和碳酸钠副产品。

The main products are inorganic fluoride, with the integrated capacity of 150 thousand tons per year, our main products are: synthetic cryolite, aluminium fluoride, sodium fluoride, silica white, hydrofluoride, potassium fluoroborate, potassium fluotitanate, potassium aluminium fluoride, magnesium fluoride, barium fluoride, lithium fluoride ,potassium fluoride, magnesium fluorosilicate, potassium fluorosilicate, potassium fluorosilicate etc.

多氟多公司生产区多氟多化工股份有限公司,公司注册资本8000万元,为河南省高新技术企业,是中国最大的无机氟化盐生产基地之一。综合产能15万吨/年,主要产品有冰晶石、氟化铝氟化钠、白炭黑、氢氟酸、氟硼酸钾、氟钛酸钾、氟铝酸钾、氟化镁、氟化钡、氟锆酸钾、氟化氢铵、氟化铵、氟化钾、氟化锂、氟硅酸钠、氟硅酸钾、氟硅酸镁等。

This paper, aimed at the problem of drying aluminum fluoride trihydrate, studied the most possible binding format of crystal water, and hereby deduced the process of crystal water dehydration.

本论文针对三水氟化铝的干燥脱水问题,应用晶体结构理论、价键理论以及各种相关化学原理推测了三水氟化铝可能的结晶水结合形式,并据此推断了其结晶水的脱除过程:对氟化铝干燥特性进行了实验研究,研究了温度和升温速率对氟化铝干燥效果的影响:采用非等温TG-DTG法,对三水氟化铝进行了热分解行为和热分解动力学分析,进一步验证了三水氟化铝的脱水过程,并得出了其脱水和水解过程的动力学参数及方程。

The research shows that In has activation to Al, making its corrosive potential decrease, and increasing the rate of H2-evolutive simultaneously. The affiliating of Zn leads In and Al to alloying, reducing the rate of H2-evolutive, and passivating aluminum. The adhibiting of Bi helps to activate Al electrode, but gets up the rate of H2-evolutive. The existent of Pb passivates Al anode, restraining the H2-evolutive availably. After compounding these elements, the general performances of complex alloys are advanced by their conjunct functions farther.

结果表明,铟对铝阳极有活化作用,使铝的腐蚀电位发生负移,但同时也会加大析氢副反应的速度;锌的加入促进了铟的合金化,减少富铟偏析相的形成,而且能极大地降低铝阳极的析氢反应速率,使其钝化;铋的引入有助铝阳极活化,但同时又会导致析氢速率的提高;铅的存在使铝阳极钝化,有效地抑制了析氢反应,但加大了阳极极化。

The mechanism of carbonization process of aluminate solution was analyzed thermodynamically. The results show that the internal reason of precipitation of Al3 in the process is its spontaneous nucleation caused by supersaturation of aluminate solution. The behaviors of SiO2 in the process are in accordance with that from published experiment, which implies that the content of product SiO2 from carbonization depends on its solubility but is not the result of absorption. The thermodynamic calculation for forming Na2O·Al2O3·2CO2· n H2O was achieved.

摘 要:为对高浓度铝酸钠溶液碳酸化分解过程中产品杂质含量的控制提供理论依据,分析了铝酸钠溶液碳酸化分解过程的热力学,认为该过程中Al3析出的真正机理是过饱和铝酸钠溶液的自发结晶;而基于分解过程中平衡浓度的热力学计算表明,在碳酸化分解过程中SiO2的变化规律与公认的三段变化规律一致,说明该过程产品中SiO2的含量取决于它在溶液中的平衡浓度,而非吸附所致;同时还分析了丝钠铝石的形成热力学。

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