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The effect of crystallization process from polymers, control laws of particles from the long-chain structure of polymer, as well as the self-assembly regulatory mechanism of nano-particles from polymer are investigated , through the control of its morphology and properties of precursor order to get large aperture, high specific surface area, has good thermal stability and catalytic cerium oxide particles.

研究聚合物对结晶过程的影响、聚合物的长链结构对粒子自组装的控制规律以及聚合物对纳米粒子自组装的调控机理,通过控制其前驱体的形貌和性能,以期得到大孔径、高比表面积、具有良好的热稳定性及催化作用的氧化铈颗粒。

Lanthanides belong to the sixth cycle of the periodic table Ⅲ B family, are all solid metal, they are La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, holmium, erbium, thulium, ytterbium, and lutetium were 15 kinds of metals and their periphery are two layers of electronic 5d16s2, while the peripheral third layer f orbital but never zero to 14, so the external electronic structure of 4f0-145d16s2, and therefore these elements in oxidation number are to 3, very close chemical properties, extraction, when it is difficult to separate them they are mostly multi-element mineral mix, more difficult to increase refining, and their atomic number of 57-71, one by one to increase the number of protons the nucleus, and thus extranuclear electron of gravity is also growing, so that atomic radius decreases with increasing atomic number Z, which makes lanthanides contraction, ionic radius is also reduced, which also makes Zr, Hf, Nb and Ta, Mo and W, the atom and ionic radius very close to each other they also determine a similar nature, resulting in difficult separation, also the tribe Ⅷ of the fifth cycle, ruthenium, rhodium, palladium, and the sixth cycle, osmium, iridium, platinum is very similar in nature, thus The six elements, said platinum group elements.

镧系元素属于周期表第六周期中ⅢB族,全部是固体金属,它们是镧、铈、镨、钕、钷、钐、铕、钆、铽、镝、钬、铒、铥、镱和镥共十五种金属元素,它们的外围两层的电子均是5d16s2,而外围第三层的f轨道电子却从零增加到14个,所以外围电子结构为4f0-145d16s2,而使这些元素氧化数均为+3,化学性质极为接近,提炼时很难分开,它们的矿石又大多是多种元素混在一起的,更增加提纯难度,它们的原子序数为57-71,核内质子数逐个增加,因而对核外电子引力也不断增强,使原子半径随原子序数Z增加而减小,这就使镧系元素收缩、离子半径也缩小,这也使得Zr和Hf,Nb和Ta、Mo和W等原子和离子半径都很接近、也决定了它们彼此性质类似,以致难以分离、也使第Ⅷ族中第五周期的钌、铑、钯和第六周期的锇、铱、铂在性质上极为相似,因而称这六个元素为铂系元素。

In this paper, a new product of Ce/ TiO2 compound antibacterial agent has been made, comparing with naked nano-TiO2, it has better antimicrobial activity against E.coli ,S.aureus and scorch gemmule bacillus in the solar light, increasing the quantity of Ce4+, exhibiting stronger antibacterial property.

制备出稀土铈掺杂锐钛型纳米TiO2复合抗菌功能材料,该抗菌材料与不掺杂的纳米TiO2相比,在可见光下对大肠杆菌、金黄色葡萄球菌、枯草芽孢杆菌的混合菌具有较好的抑菌效果,随着Ce4+的摩尔浓度增加,制备的试样的抗菌能力越强。

The graft polymerization of acrylonitrile on Crosslinked polyvinyl alcohol microspheres CPVA microspheres was performed by using cerium ammonium sulfate as initiator, and grafted microspheres CPVA-g-PAN were prepared. Subsequently, the grafted PAN was converted into poly via amidoximation reaction with hydroxylamine hydrochloride as reagent, resulting in the functional microspheres CPVA-g-PAO. The chemical structure and physicochemistry characters were adequately characterized with infrared spectrum, scanning electron microscope and determining Zeta potential. The effects of main factors on the amidoximation transform reaction of the grafted PAN were researched with emphasis, and the adsorption property of the functional microspheres CPVA-g-PAO for some biomolecules was examined preliminarily with uric acid as a model biomolecule.

以硫酸铈铵为引发剂,实施了丙烯腈在交联聚乙烯醇微球表面的接枝聚合,制备了接枝微球CPVA-g-PAN,然后以盐酸羟胺为试剂,通过偕胺肟化转变,将接枝的PAN转变为聚偕胺肟,制得了接枝有聚偕胺肟的功能微球CPVA-g-PAO,采用红外光谱法、扫描电子显微镜及Zeta电位测定等法,对功能微球CPVA-g-PAO的化学结构及物理化学特性进行了表征,重点考察了各主要因素对接枝PAN的偕胺肟化转变反应的影响,也以脲酸为模型分子,初探了功能微球CPVA-g-PAO对生物分子的吸附性能。

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