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Nanoscale zero valent iron particles were synthesized by reductive method in aqueous phase. The crystal structure, morphology and size of the particles were characterized using X-ray diffraction and transmission electron microscopy. The influence of temperature, initial acid fuchsine concentration, nanoscale zero valent iron dosage and pH on the removal of acid fuchsine by the particles was studied, and the removal mechanism of acid fuchsine was discussed.

摘 要:采用液相还原法制备零价纳米铁粒子;用X射线衍射和透射电镜表征该样品的晶体结构、颗粒形貌与尺寸;研究温度、酸性品红初始浓度、纳米零价铁加入量及溶液pH值对零价纳米铁粒子脱除酸性品红的影响,并对酸性品红的脱除机理进行讨论。

The results show that the obtained nanoscale zero valent iron particles are mostly in spherical shape with less than 100 nm in size. The acid fuchsine can be removed by nanoscale zero valent iron particles efficiently. The efficiency of removing acid fuchsine from solution is increased with increasing temperature and the dosage of nanoscale zero valent iron particles and decreasing initial concentration of acid fuchsine. The mechanism of removing acid fuchsine by nanoscale zero valent iron particles may include dual functions of absorption and degradation, and the degradation may play a major role in the reaction.

研究结果表明:纳米零价铁颗粒为球形,单个颗粒粒径小于100 nm;纳米零价铁对酸性品红有很好的脱除作用,酸性品红的脱除率随温度的升高、纳米零价铁用量的增加以及酸性品红初始浓度的降低而逐渐增大;纳米零价铁对酸性品红有吸附和降解的双重作用,而以降解作用为主。

Simultaneously, the total extractible myoglobin decreased and the proportion of metmyoglobin increased significantly when the pressure above 400MPa. Beef discoloration after pressure processing may result from oxidation of ferrous myoglobin to ferric metmyoglobin, globin denaturation and structural changes. At 40℃, the changes of beef color was similar to that of room temperature's. When the temperature rise to 60℃, most of muscle proteins denatured, a small quantity of native myoglobin could not affect the color of beef significantly. Therefore, protein denaturation was attributed to the main cause of discoloration in beef muscle after pressurization at 60℃.

压力处理导致色泽变化的直接原因可能是由于二价铁的肌红蛋白氧化成三价铁的高铁肌红蛋白、球蛋白的变性及结构的变化所致。40℃时的压力处理,色泽的变化规律与室温下相似,只是色泽变化的程度更为剧烈,蛋白质变性在色泽变化中起到的作用逐渐加强。60℃下的压力处理,绝大部分蛋白质发生变性,少量未变性的肌红蛋白对色泽不会产生明显的影响,此温度的压力处理,蛋白质变性是造成肌肉失去红色的主要原因。

The experimental results indicates that the optimum pH range was 1.60~2.20, and the optimum H2O2 concentration was 10.0 mmol/L. The degradation ratio increased with the increasing concentration of ammonium ferric oxalate in the range from 0.1 to 1.0 mmol/L, but no significant increase in degradation ratio was observed when the concentration was above 1.0 mmol/L. When the concentration of fuchsin basic increased, the degradation ratio dropped, while the concentration of degraded fuchsin basic rised. When the concentration of fuchsin basic was low, the degradation followed first-order kinetics, but when it was high, the degradation could be fitted by zero-order kinetics. The absorbtion of fuchsin basic at 543 nm disappeared quickly, while the absorbtion of intermediates formed during the course of fuchsin basic dagradation at 298 nm vanished slowly.

试验结果表明:碱性品红降解的最佳初始pH为1.60~2.20,最佳初始H2O2浓度为10.0mmol/L;草酸高铁铵的浓度在0.1~1.0mmol/L时,碱性品红的降解率随浓度的增大而增大;高于1.0mmol/L时,则降解率相差不大;碱性品红的初始浓度增大,降解率减小,而实际降解的浓度则增加;碱性品红的浓度在低和高时,降解动力学过程不一致;随降解的进行,碱性品红在可见光区的吸收峰迅速消失,而降解过程中形成的中间产物吸收峰却消失很慢。

The invention provides a compound for preventing foetus neural tube abnormality and pregnant woman iron deficiency anemia and its manufacturing method, it includes active ingredients and carrier, the active component is mainly made up of 1:25 weight ratio of folacin and hemin, the dosage is: folacin 0.2-0.6mg, hemin 5-15mg, the carrier is 150-300g of mannitol, the product can be produced through following steps and order: the hemin and mannitol are put into the mixer to be mixed for 0.5-1.5 hours according to same-size scale-up method, and they are crashed and filtered with 100 items sift and they are diluted, then they are blended with folacin, and carries pelleting or making capsule, pill and so on, it can prevent the foetus neural tube abnormality and it can prevent the pregnant woman iron deficiency anemia.

本发明提供一种预防胎儿神经管畸形和孕妇缺铁性贫血病的组合物及其制备方法,它包括活性成分和载体,其中活性成分主要由重量比为1∶25的叶酸与氯高铁血红素组成,用量为:叶酸0.2~0.6mg、氯高铁血红素5~15mg,载体为甘露醇150~300g,并按以下步骤和次序配制而成:氯高铁血红素与甘露醇按等量递加法放置在混合机中混合0.5~1.5小时,一起粉碎过100目筛制成稀释散后,再与叶酸混合均匀,直接压片或者制成胶囊、丸剂等剂型,不仅预防胎儿神经管畸形,而且能够同时预防孕妇缺铁性贫血。

In particular, some well-known ceramic production areas, such as iron stores kiln Jinhua, Zhejiang, Jiangxi Jian Ji states kiln, in the Southern Song to the Yuan Dynasty dazzling out of the firing kiln glaze, Jingdezhen firing Copper red glaze Its coloring principle is clearly Song Jun copper red glaze the same strain, and even precious stones Ming and Qing Dynasties to become red, Ji-hong, Lang kiln red beauties drunk marked the beginning of varieties such as glaze.

特别是一些著名的产瓷区,如浙江金华铁店窑、江西吉安吉州窑,在南宋至元代就烧制出了光彩夺目的窑变釉,江西景德镇烧制的铜红釉,其呈色原理显然与宋钧铜红釉一脉相承,甚至成为明清时期宝石红、霁红、郎窑红、美人醉等釉色品种的滥觞。

Our grab nickel production, nickel is mainly used to crawl Hard fine powder , red clay minerals such as highly viscous due to the recent nickel Hard fine powder , red clay and other minerals to be widely used, so Many major ports on the existence of such a problem, in which the ore handling when loading and unloading there is a low efficiency, has been a lot of ore grab adhesive wall, our company in order to solve this dilemma has been studied and produced by such a professional crawl very sticky ore grab, the principle is: grab the lowbeam calculated to increase the adoption of two pieces of solder, including the specific location of board and grab the bucket to create a circular flap, so Open grab discharging, the fight is on board, including the body wall from the top down (no contact with body panels Doo), to stick the body in fighting the viscous wall down, including mine, so, which greatly improved the handling grab the efficiency of ports and factories to solve the problem, which is purpuratus grab a patent, other manufacturers can not be produced.

我公司生产的镍矿抓斗,主要用来抓取镍矿、铁精粉、红粘土等粘性很强的矿石,由于近来镍矿、铁精粉、红粘土等矿石在被人们广泛使用,因此,许多大港口就存在着这样一个问题,在装卸这此矿石的时候,存在着装卸效率低,抓斗内壁被很多矿石粘着,我公司为了解决这一难题,现已研究并生产出来这种专业抓取很粘的矿石抓斗,原理是:在抓斗的下承梁上通过计算得出要加焊俩块括板的具体位置,并要把抓斗的斗瓣做成圆形,这样在抓斗打开卸料时,括板就在斗体内壁从上而下,把粘在斗体内壁的粘矿括了下来,所以,这就大大提高了抓斗的装卸效率,为港口和工厂解决了这一难题,这种抓斗是紫石的一项专利,其它厂家是无法生产出来的。

Our grab nickel production, nickel is mainly used to crawl Hard fine powder, red clay minerals such as highly viscous due to the recent nickel Hard fine powder, red clay and other minerals to be widely used, so Many major ports on the existence of such a problem, in which the ore handling when loading and unloading there is a low efficiency, has been a lot of ore grab adhesive wall, our company in order to solve this dilemma has been studied and produced by such a professional crawl very sticky ore grab, the principle is: grab the lowbeam calculated to increase the adoption of two pieces of solder, including the specific location of board and grab the bucket to create a circular flap, so Open grab discharging, the fight is on board, including the body wall from the top down (no contact with body panels Doo), to stick the body in fighting the viscous wall down, including mine, so, which greatly improved the handling grab the efficiency of ports and factories to solve the problem, which is purpuratus grab a patent, other manufacturers can not be produced.

搜索关键字:镍矿抓斗,矿石抓斗,红粘土抓斗,砂石料抓斗我公司生产的镍矿抓斗,主要用来抓取镍矿、铁精粉、红粘土等粘性很强的矿石,由于近来镍矿、铁精粉、红粘土等矿石在被人们广泛使用,因此,许多大港口就存在着这样一个问题,在装卸这此矿石的时候,存在着装卸效率低,抓斗内壁被很多矿石粘着,我公司为了解决这一难题,现已研究并生产出来这种专业抓取很粘的矿石抓斗,原理是:在抓斗的下承梁上通过计算得出要加焊俩块括板的具体位置,并要把抓斗的斗瓣做成圆形,这样在抓斗打开卸料时,括板就在斗体内壁从上而下,把粘在斗体内壁的粘矿括了下来,所以,这就大大提高了抓斗的装卸效率,为港口和工厂解决了这一难题,这种抓斗是紫石的一项专利,其它厂家是无法生产出来的。

Then in each hole by adding 35 grams bean paste, sugar, 5 grams of pig small leaf lard, and then taking 15 grams of sugar evenly spread in the hole, after slurry surface will be used to fill holes, sprinkled about 15 grams of red and green silk, Canada Cover burned two minutes, re-openings evenly sprinkled 15 grams of sugar, covered with burn铁盖again three minutes that is cooked.

接着在每个孔内加入豆沙35克、糖猪板油丁5克,再取白砂糖15克均匀撒在各孔内,此后用面浆将孔填满,撒上红绿丝约15克,加盖烧2分钟,开盖再均匀撒上白砂糖15克,盖上铁盖再烧3分钟即熟。

"5C■","TST Star Ferry Pier","Tsz Wan Shan","$4.7#","4 -12min","06:20 - 00:30","Salisbury Rd, Chatham Rd South, Ma Tau Wai Rd, To Kwa Wan Rd, Prince Edward Rd West / East",The HK Polytechnic University, HK Science Museum, HK Museum of History, East Rail Hung Hom Station, Ko Shan Theatre, Factory

&尖沙咀天星码头&,&慈云山&,,&4 -12分钟&,,&梳士巴利道漆咸道南马头围道土瓜湾道太子道西/东&,&香港理工大学香港科学馆香港历史博物馆东铁红磡站高山剧场民裕街之出口成衣制造厂&

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