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After detail analysis of current several iron removal methods, it was proved that the jarosite could not only be used for iron deep purification, but also release the accumulation of sulfate, which was due to the oxidation of pyrite.

在对现行诸多除铁方案进行分析后,指出了黄钠铁矾法不仅可以从锰结核浸出氯化物溶液中深度净化除铁,而且可以同时除去黄铁矿氧化生成的大部分硫酸根,这样无疑避免了硫酸根在氯化物体系中的积累。

Aiming at some defects and shortages existing in conventional deferrization processes,such as jarosite,goethite and spray processes,in zinc hydrometallurgy process and using new movements abroad for reference,the study on new technology for removing iron by phosphate has been carried out and satisfactory results have been achieved.

针对湿法炼锌过程中,常规的铁矾法、喷淋法等除铁工艺存在渣量大、周期长、能耗高以及渣二次污染等缺陷和不足,并借鉴国外除铁新动向,进行了磷酸盐除铁法的试验研究,获得了较满意的结果。

The decomposition of ammonium jarosite bearing indium in NaOH medium were studied. The effects of NaOH addition, liquid-solid ratio, decomposition temperature and time on the decomposition ratio of ammonium jarosite were investigated, respectively, and the behavior of impurity elements, such as Zn, In, Cu, Cd, Pb, As, Sb, Sn and Ag in jarosite residues was also discussed.

摘 要:提出NaOH分解含铟铁矾渣新工艺,考察NaOH用量、液固比、温度和时间对铁矾渣分解率的影响,并讨论铁矾渣中杂质金属,如Zn、In、Cu、Cd、Pb、As、Sb、Sn和Ag等在NaOH分解过程中的行为。

The effect of the addition of the crystal seed in the jarosite preciptation was investigated and the results showed that the crystal seed would accelerate the crystallizing rate of jarosite formation, which convert the reaction mechanism from the crystallization kinetic rate control into the chemical reaction kinetic control.

阐述了晶种加入对沉矾影响的过程机理,认为晶种的加入加快了沉矾反应的结晶速度,使反应由结晶的动力学控制过渡到化学反应动力学控制,足量晶种加入情形下沉矾过程的活化能为94.66KJ/mol,表明了氯化物体系铁矾沉淀较硫酸盐体系中更易进行。

This paper studies the neutralize agent for zinc hydrometallurgy of jarosite process,analyses advantage and disadvantage of NH_4HCO_3 and calcine as jarosite precipitation neutralize agent,points out if used calcine removed zinc ferrite as neutralize agent,than can cut the cost and reduce zinc content in slag.

研究了湿法炼锌黄钾铁矾渣除铁工艺的中和剂,分析了碳酸氢铵和焙砂作为沉矾中和剂的优缺点,指出用除去铁酸锌的焙砂作中和剂,可降低成本,减少渣含锌。

Jarosite process can obtain high recovery rate of zinc,simultaneously,most of indium remains in the jarosite residues and a little part of indium remains in the high acidities leaching residues.

某锌精矿中铟含量很高,采用黄钾铁矾法处理该高铟锌精矿,在得到较高锌回收率的同时,大部分的铟进入矾渣,少部分进入高浸渣,从矾渣和高浸渣中可回收得到电铟。

The results indicate that both the precipitates produced by Leptospirillum ferriphium strain DY and Acidirhiobacillus ferrooxidans strain GF are composed of jarosite and ammonium jarosite. However, the content of jarosite in the precipitates synthesized by strain GF is 5.53% higher than that synthesized by strain DY, but the content of ammonium jarosite in the precipitates synthesized by strain DY is 15.24% higher than that synthesized by strain GF.

结果表明:无论是嗜铁钩端螺旋菌DY菌株,还是嗜酸氧化亚铁硫杆菌GF菌株合成的沉淀都是黄钾铁矾和黄铵铁矾的混合物;其中,GF合成的沉淀混合物中黄钾铁矾的含量比DY合成的黄钾铁矾约高出5.53%;而DY合成的沉淀中,黄铵铁矾的含量比GF合成的沉淀中的黄铵铁矾的含量约高出15.24%。

The potassium ammonium jarosite with zinc and indium is obtained by Fe3+ ion removal from the iron,zinc and indium coexisted sulphate system by potassium ammonium jarosite process.

在铁、锌、铟共存的硫酸盐体系中采用黄钾铵铁矾法除铁,得到了含锌、铟的黄钾铵铁矾,通过TG/DTA和XRD对黄钾铵铁矾及其热分解产物进行表征。

The strong acidity, Fe(superscript 2+) and rather lower concentration of alkalis ions are responsible for voltaite, not jarosite, crystallizing from the acidic iron-bearing water.

分析认为,废液呈强酸性、溶液中存在大量Fe(上标 2+)、碱金属离子含量偏低是蒸发结晶过程中形成绿钾铁矾而不是黄钾铁矾的主要原因。

The experiment result shows that if Iron in the pickle of copper-smelting smoke ash is removed by Oxygen or oxidation combined with Hydrogen peroxide, Iron removing rate is 90%.

常用除铁方法主要有 [1 ,2 ] :(1 )直接鼓风氧化生成针铁矿的形式除铁;(2 )用生成磷酸盐沉淀的方法除铁;(3 )用黄钾铁矾法除铁;(4)用过氧化氢氧化除铁;(5 )采用溶剂萃取法分离铁。

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从鲍尔点的形成原理出发,分析对称连杆曲线上鲍尔点的产生条件,提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

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