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铁氰化钾

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After being extracted and purified, thiamine which has no fluorescence was oxidized to fluorescent thiochrome, then, it was extracted by n-butanol, the thiochrome in n-butanol were measured with spectrofluophotometer, and the thiamine was determined.

样品经提取、净化后,再利用碱性铁氰化钾K3Fe(N6将没有荧光的硫胺素氧化成能够发射荧光的硫色素,经正丁醇萃取后测定萃取液中硫色素的含量,从而实现对维生素B1含量的测定。

With potassium ferricyanide used as catalyst, LCVL dissolved in sodium hydroxide was oxidized to CVL by inpouring the air for 18h. The yield of CVL is 90.50%.

把LCVL溶解在碱性溶液中,以铁氰化钾为催化剂,通入空气反应18h,得结晶紫内酯,收率为90.50%。

It was based on the reaction between thiamine and hexacyanoferrate in sodium hydroxide medium to give CL signal,which was enhanced by cetyltrimethyl ammonium bromide.

基于在N aOH碱性中,铁氰化钾可以直接氧化维生素B1产生化学发光,而十六烷基三甲基溴化铵的存在可以大大增强这一化学发光强度,结合流动注射分析技术,在研究并优化化学发光条件的基础上,建立了测定维生素B1的化学发光分析方法。

The SinoChrom ODS-BP column(4.6mm×200mm i.d 5um) was used with the mobile phase of phospioricacid salt buffer solution.The recovery of benzoic acid was 93.2%.

此种方法用醋酸锌和亚铁氰化钾溶液作为沉淀剂,以磷酸盐缓冲溶液作为流动相,用SinoChrom ODS-BP柱(4.6mm×200mm i.d 5um)液相色谱柱分离,用伊利特UV-230+紫外可见检测器进行检测。

Using free radical 4-hydroxy-2,2,6,6-tetramethyl-1-piperidinyloxyl as catalyst, the phase transfer catalyzed method of oxidation of anilines to 15 symmetrical azobenzenes with a saturated solution of potassium ferricyanide in 2N aqueous potassium hydroxide and dichloromethane was described for the first time.

用2,2,6,6-四甲基-4-羟基-1-哌啶氮氧自由基为催化剂,芳胺类化合物在饱和铁氰化钾的氢氧化钾溶液和二氯甲烷的两相转移催化下合成了15 个对称取代偶氮苯。

The structures were identified by IR, UV,〓 NMR and element analyses. 2. Free radical 4-hydroxy-2,2,6,6-tetramethyl-1-piperidinyloxyl as catalyst, the phase transfer catalyzed method of oxidation eighteen semicarbazides to N-Aryl-2-Phenyl diazenecarboxamide with a solution of potassium ferricyanide in 2N aqueous sodium hydroxide and dichloromethane is described for the first time.

利用2,2,6,6-四甲基-4-羟基-1-哌啶氮氧自由基为相转移催化剂,在饱和铁氰化钾的2N氢氧化钠溶液与二氯甲烷的两相反应液中,催化氧化十八个取代氨基脲得到十八个相应的新型偶氮化合物N,2-二芳基二氮亚烯甲酰胺,均获得了较高的产率。

In weak alkaline medium, the ECL intensity of luminol could be sensitized by potassium ferricyanide. The mechanism of the sensitization is revealed as the oxidation of the luminol by potassium ferricyanide concomitant with the ECL reaction.

在弱碱性介质中,铁氰化钾对鲁米诺具有氧化作用,因而对鲁米诺的电化学发光产生增敏,提高了鲁米诺电化学发光检测的灵敏度,讨论了这一增敏作用的机理。

Methods Sea sand were added into samples-distill by water in the condition of alkalescence vibratedly-add potassium ferrocyanide and zinc acetate (to deposit protein, faecula,fat.)-determination by HPLC after filtration.

样品加入海砂分散黏稠成块的样品,在碱性条件下用水振荡提取,加入亚铁氰化钾和乙酸锌沉淀蛋白质、淀粉和脂肪等,滤膜过滤进行液相色谱分析。

The high potassium ferrocyanide solution was added to CAM homogenates and the absorbance was detected by ultraviolet spectrophotometer. The hemoglobin content of CAM homogenates was obtained by reference standards.

分离发育期鸡胚尿囊膜并将其匀浆,加入高铁氰化钾溶液,用紫外分光光度计测量A值,通过标准品计算样品中血红蛋白的含量。

The protein and the fatty compounds in the sample are precipitated by zinc acetate and potassium ferrocyanide, then the chromogenic reaction of acetylacetone with formaldehyde released from the sample in weak-acid medium and boiling bath takes place immediately.

提出了一种用於现场测定水发食品中甲醛含量的样品快速前处理新方法,采用乙酸锌和亚铁氰化钾沉淀样品中的蛋白质和脂肪,在弱酸性介质和沸水浴条件下提取了样品中的甲醛,并与乙酰丙酮立即发生显色反应。

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