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钾盐镁矾

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A light soft silver-white metallic element of the alkali metal group; oxidizes rapidly in air and reacts violently with water; is abundant in nature in combined forms occurring in sea water and in carnallite and kainite and sylvite.

轻而软的银白色碱金属元素,空气中能迅速氧化,能与水发生剧烈反应,以天然化合物状态大量存在于海水、光卤石、钾盐镁矾和钾盐中。

Also there is much difference between the obtained metastable phase diagram at 35 ℃ and the metastable phase diagram at 25 ℃. The crystallization regions of schoenite(K2SO4*MgSO4*6H2O) and epsomite disappear and arise the crystallization regions of leonite and kainite.

所得35 ℃介稳相图与25 ℃介稳相图区别很大:软钾镁矾和七水硫酸镁结晶区域消失,同时出现了钾镁矾和钾盐镁矾的结晶区域。

A large difference is found between the obtained metastable phase diagram at 35 ℃ and Vant Hoffs stable phase diagram at 25 ℃. The crystallization regions of schoenite(K2SO4*MgSO4*6H2O), epsomite(MgSO4*7H2O), magnesium sulfate pentahydrite(MgSO4*5H2O) and starkeyite(MgSO4*4H2O) disappear and the crystallization regions of leonit and astrankit are greatly incresed.

所得35 ℃介稳相图与Vant Hoff 25 ℃稳定相图比较有较大区别:软钾镁矾(K2SO4*MgSO4*6H2O)、七水硫酸镁、五水硫酸镁及四水硫酸镁结晶区域消失,钾镁矾和钾盐镁矾结晶区域显著扩大。

This paper presents the experimental data of metastable phase equilibrium of Na+, K+, Mg2+∥Cl-, SO2-4-H2O quinary system at 35 ℃, from which the metastable phase diagram is drawn. It consists of nine regions of crystallization saturated with sodium chloride, potassium chloride, glasserite(3K2SO4*Na2SO4), leonite(K2SO4*MgSO4*4H2O), kainite(KCl*MgSO4*2.75H2O), thenardite(Na2SO4), astrankit(MgSO4*Na2SO4*4H2O), carnallite(KCl* MgCl2*6H2O), magnesium sulfate hexahydrite(MgSO4*6H2O) and bischofit(MgCl2*6H2O).

研究得出(Na+, K+, Mg2+∥Cl-, SO2-4-H2O)五元体系35 ℃时的介稳溶解度数据,绘制了该体系35 ℃的介稳相图,共有9个为氯化钠所饱和的结晶区域:氯化钾、钾芒硝(3K2SO4*Na2SO4)、钾镁矾(K2SO4*MgSO4*4H2O)、钾盐镁矾(KCl*MgSO4*2.75H2O)、光卤石(KCl*MgCl2*6H2O)、白钠镁矾(Na2SO4*MgSO4*4H2O)、硫酸钠、六水硫酸镁(MgSO4*6H2O)和水氯镁石(MgCl2*6H2O)。

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