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钼酸盐

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Effects of the components of chromating solution and influence of technological parameter on the chromate conversion coating are discussed.

研究了一种以钼酸盐为促进剂的铬酸盐转化处理工艺的配方和成膜机理,讨论了铬酸盐转化处理液中各组分的作用和工艺参数对铬酸盐转化膜层的影响,并对铝合金型材涂装前处理工艺流程和主要工序进行了说明。

Owing to the good stability in light, heat and chemical characteristics, the rare earth-doped molybdate is a good kind of luminescent material, but there are few reports on it.

稀土钼酸盐发光材料由于具有良好的光热稳定性和化学稳定性,是一种很好的发光基质材料,但关于稀土钼酸盐发光材料的研究却少有报道。

The results indicated that the inhibition efficiency increased with increasing molybdate concentration, but single molybdate inhibitor had low inhibition efficiency.

实验结果表明:单一钼酸盐对海水中碳钢的缓蚀率随着钼酸盐使用浓度的增加而增加,但低浓度使用缓蚀率较低。

Based on analyses of the present applications of corrosion inhibitors for recirculated cooling water, a new-type of complex corrosion inhibitor containg molybdate, zincate, organic acid and gluconate was proposed.

为解决某水样的腐蚀问题,提出了一种由钼酸盐、锌盐、有机酸、葡萄糖酸盐等组分的复合缓蚀剂配方,设计了正交实验,并采用旋转挂片测定了其腐蚀速度。

Molybdates were reduced to adsorbed hydrogen molybdenum bronzes on platinum electrode in H 2SO 4 solution during potential sweep cathodically.

钼酸盐在铂电极上硫酸溶液中还原形成钼青铜,吸附在电极表面,铂电极因钼酸盐的还原和钼青铜的氧化而得到修饰。

A chromium free conversion coating at least equivalent in corrosion protective quality to conventional chromate conversion coatings can be formed on metals, particularly cold rolled steel, by a dry-in-place aqueous acidic liquid comprising: a component of anions, each of said anions consisting of at least four fluorine atoms and at least one atom of an element selected from the group consisting of titanium, zirconium, hafnium, silicon, and boron, and, optionally, ionizable hydrogen atoms, and optionally, one or more oxygen atoms; a component of cations of elements selected from the group consisting of cobalt, magnesium, manganese, zinc, nickel, tin, zirconium, iron, and copper; the ratio of the total number of cations of this component to the total number of anions of component being at least 1:5; sufficient free acid to give the composition a pH in the range from 0.5 to 5.0; a component selected from the group consisting of phosphorus-containing inorganic oxyanions and phosphonate anions; and a component selected from the group consisting of water-soluble and water-dispersible organic polymers and polymer-forming resins and, preferably, also including a component selected from the group consisting of tungstate, molybdate, silicotungstate, and silicomolybdate anions.

通过对包含以下成分的含水酸性液体进行干燥,可以在金属上形成无铬的转换涂层,该涂层与普通铬酸盐转换涂层相比,至少在抗腐蚀质量上等效:$_一种阴离子成分,所述各个阴离子包括至少4个氟原子,至少选自钛、锆、铪、硅与硼元素中的1个原子。任选地可离解的氢原子,任选地1个或多个氧原子;$_一种选自钴、镁、锰、锌、镍、锡、锆、铁与铜元素的阳离子成分,上述成分的阳离子总数与成分内的阴离子总数之比至少为1∶5;$_足够的游离酸以使该组合物的pH值在0.5~5.0的范围内;$_一种选自含磷的无机含氧阴离子与膦酸盐阴离子的成分;$一种选自水溶性与水可分散性有机聚合物与聚合物形成的树脂的成分,优选还包括一种选自钨酸盐、钼酸盐、钨硅酸盐与钼硅酸盐阴离子的成分。

Under the excitations of Ultraviolet, X-ray, cathodic ray, etc. tungstates can produce blue emission, and molybdates can generate green light. Hence, scheelite-structured tungstates and molybdates are used in the fields of detections for high energy particles, scintillant arithmometers, X-ray gain screen, luminescence and displays.

在紫外、X射线、阴极射线等的激发下,钨酸盐能发射出蓝光,钼酸盐能发射出绿光,因而白钨矿结构的钨—钼酸盐在高能粒子探测、闪烁计数器、X射线增感屏、发光与显示技术等领域具有重要的应用。

Pit corrosion is a main kind of localized corrosion. The process of forming pit corrosion includes three stages-formation of pit source, development of pit cave and forming occluded corrosion cell. Molybdate series inhibitors can be inhibitive, for it can control three stages of pit development. First, there is apparent synergistic effect between molybdate and phosphate, which can suppress formation of pit source. Second, there is apparent passivation of molybdate inhibitor according to electrochemistry analysis, which let oxidation film in unoccluded cave repassivate.

首先,钼酸盐与磷酸盐或硅酸盐复配的缓蚀剂具有较理想的缓蚀性能,并且有明显的协同作用,从而能抑制部分点蚀核的产生;其次,钼酸盐复配缓蚀剂的使用,从电化学的角度分析,具有明显的钝化性能,且钝化区间较宽、维钝电流密度较小,从而能使未封闭的蚀孔或点蚀核附近的氧化膜再钝化,得到有效的修复;最后,对于还有部分蚀孔发展成为闭塞腐蚀电池的情况,钼酸盐、磷酸盐能进入蚀孔内部并且在酸性条件下生成铁钼磷酸盐,从而有效地减缓了点蚀的恶化,抑制了腐蚀的发展。

The mechanism of vanadium removal from ammonium molybdate solution by ion-exchange was studied. It is found that V and Mo existing in ammonium molybdate solution are in the forms of V3O(superscript 2- subscript 9) and MoO4(superscript 2-), respectively, when V2O5 concentration is about 0.5g/L and the p!

钼酸盐溶液离子交换钼钒分离机理进行研究研究结果表明,在钼酸盐溶液中V2O5含量约为0.5g/L,钒与钼在pH值为6.5~8.5的范围内分别以V3O(上标 3-下标 9)和MoO(上标 2-下标 4)的形态存在。

However, chromates have caused increasingly environmental concern. The need to find low toxicity alternatives to hexavalent chromium-based passivation treatment is of prime importance. Molybdate passivation can be used to replace chromate in a wide range of applications.

但由于铬酸盐钝化对环境的污染,寻找一种低毒的代替铬酸盐钝化的处理工艺是十分必要的,钼酸盐钝化是最有前途的一种。

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