钨酸

Zirconia loaded with tungsten oxide has been reported to be an efficient solid catalyst at relatively low temperatures in the skeletal isomerization of alkane or benzoylation of toluene, which are usually catalyzed by strong acids.

中文摘要文献上钨锆氧化物可以在低温的反应条件之下，对於烷类的异构化反应扮演有效的固体酸的角色。然而，钨锆氧化物其本身的比表面积通常只有50 m2/g。

Then the catalysts of high activities were selected to be used in the preparation of mixed dibasic acid dimethyl esters.Mixed dibasic acids are byproducts of hexanedioic acid. In this article DBE were synthesized.

己二酸生产过程中副产大量的混合二元酸，本文选用DBA和甲醇为原料，分别采用磷钨杂多酸、PW_(12)/C和PW_(12)/SiO_2为催化剂，合成了绿色环保高沸DBE。

The diisoamyl glutarate in catalysis of silicotungsticacid was preparated by esterification of isoamyl alcohol and glutaric anhydride seperated from dicarboxylic acid.

用硅钨杂多酸为催化剂，以从二羧酸中分离出的戊二酸酐和异戊醇为原料合成了戊二酸二异戊酯。

This paper studied the synthesis of isoamyl acetate using silver phosphotungstomolybdate heteroployacid as catalyst.

制备了固体磷钼钨杂多酸银盐，并以此为催化剂，对醋酸异戊酯的合成反应进行了研究，探讨了催化剂用量、醇酸摩尔比、反应时间和催化剂重复使用对酯产率的影响。

Isobutyl butyrate was synthesized from butyric acid and isobutyl alcohol using tungstosilicic acid as catalyst.

以钨硅酸为催化剂，通过桂酸和戊醇酯化反应合成桂酸戊酯，研究了各有关因素对产品酯化率的影响。

Isoamyl isovalerate was synthesized through esterification reaction by using isovaleric acid and isoamyl alcohol as raw materials and nano-H4SiW12O40/SiO2 as catalyst, the influencing factors in the reaction were studied, and the results showed that the esterification rate could reach 98.6 % under the conditions of the ratio of alcohol-acid 1.4∶1, the use level of catalyst 5 %, and the reaction time 1.5 h.

以纳米复合钨硅杂多酸为催化剂，异戊酸和异戊醇为原料，通过酯化反应合成苹果油，对酯化反应的影响因素进行了研究，结果表明，在醇酸物质的量比为1.4∶1，催化剂用量5%，反应时间1.5h的条件下，酯化率可达98.6%。

Dihexyl sebacate was synthesized from sebacic acid and n-hexanol with silicotungstic acid as catalyst.

以硅钨杂多酸为催化剂，癸二酸和正己醇为原料合成了癸二酸二己酯。

Diamyl glutarate ; synthesis ; esterification ; silicotungstic acid ; catalyst

戊二酸二正戊酯；合成；酯化；硅钨杂多酸；催化剂

This dissertation also studied the direct synthesis of H_2O_2 from H_2 and O_2 undernormal pressure over polyoxometalates-supported Pd catalysts in the absence of anyliquid acid or halide additives in the liquid phase.

本学位论文中还针对常压下从氢气和氧气直接合成过氧化氢反应考察了在液相不共存任何酸和卤素助剂的情况下，磷钨杂多酸铯盐负载的金属Pd为催化剂的催化性能。

Complexes 7-12, 16, 22 and 23 are dimeric molybdatesor dimeric tungstates, the central metal with citrate or malate in a molar ratio of 1:1. Theanions of these complexes have two metal atoms and two ligands. Each ligand acts as atridentate fashion via theirα-alkoxy,α-carboxy andβ-carboxy groups coordinated to eachmetal atom. Complex 13 is a monomeric molybdate. The citrate ligand coordinates tomolybdenum with itsα-alkoxy,α-carboxy andβ-carboxy groups in a tridentate mode.

其配阴离子中都含有2个金属原子和2个配体，且配体均以α-烷氧基、α-羧基和β-羧基氧与中心金属三齿配位。13是单核柠檬酸钼配合物，柠檬酸也以α-烷氧基、α-羧基和β-羧基氧与钼三齿配位。17和21分别为苹果酸钼、柠檬酸钨单核配合物，其中苹果酸、柠檬酸配体均以α-烷氧基氧和α-羧基氧与金属双齿配位。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。