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Stainless steel 35-42 °Be FeCl 3 35-55 Mild steel 35-42 °Be FeCl 3 35-55 Beryllium copper 30-42 °Be FeCl 3 or 40-55 ammoniacal copper or 33 °Be acidic CuCl 2 Copper and copper 30-42 °Be FeCl 3 or 40-55 alloys ammoniacal copper or 33 °Be acidic CuCl 2 Inconel and other 38-42 °Be FeCl 3 or 45-55 high nickel alloys conc nitric/conc hydrochloric acid/water 1:1:3 Aluminium 20% NaOH 60-90 or conc hydrochloric 20-65 acid/water 1:4 55 or alkaline potassium ferricyanide Brass 30-42 °Be FeCl 3 or 40-55 ammoniacal copper or 33 °Be acidic CuCl 2 Molybdenum Alkaline potassium 55 ferricyanide 40-55 or 40 °Be Fe(NO 3 ) 3 Titanium 10-50% HF 30-50 (optionally with HNO 3 )*The concentration of etchant (column 2) is measured in Degrees Baume where:°Be = 145 (SG - 1/SG); and SG is the specific gravity of the solution.

表美- 00002表2金属共同腐蚀剂*温度° C的不锈钢35-42 °成为氯化铁三 35-55低碳钢35-42 °成为氯化铁三 35-55铍铜30-42 °成为氯化铁3或40-55氨铜或33 °是酸性CuCl的2铜及铜30-42 °成为氯化铁三或40-55合金氨铜或33 °是酸性CuCl的2镍铬铁合金和其他38-42 °成为三氯化铁3或45-55高镍合金浓硝酸/浓盐酸/水1时01分03秒铝20%的NaOH浓盐酸60-90或20-65酸/水1:4 55或氰化钾铜30-42 °碱性钾成为三氯化铁3或40-55氨铜或33 °是酸性CuCl的二钾55钼碱性铁氰化钾40-55或40 °成为铁Fe(NO 3)3钛10-50%的HF 30-50*的浓度对侵蚀剂(栏2)测量波美度其中:°成为= 145(法兴- 1/SG);和SG是比重。

The minerals of Ti are ilmenite and brookite. The forms of Fe and Ti in kaolinite are absorption and structure types. The contents of them are less than 0.234% and 0.020%.

研究区高岭石晶体中铁、钛以吸附型和结构型存在,两种形式铁、钛含量分别小于0.234%和0.020%。

Further,semisteel,V_2O_5 flakes and titanium dioxide are achieved separately according to vanadium recovery from hot metal/vanadium slag and titanium recovery from titanium-beating sl.

通过进一步的铁水提钒、钒渣提钒和硫酸法提钛处理,生产出合格的半钢、片状 V_2O_5和钛白产品,元素回收率分别达到88%、 42%和75%,最终实现了铁、钒、钛的分离和综合回收利用。

When the erosion site inside the 90 degree from the taphole, we suggest that the taphole location should be adjusted away from the erosion site as soon as possible.

3依据碳化钛的浓度分布,加入二氧化钛位置应距离出铁口90度以上较好;当侵蚀处在90度以内,建议可调整出铁口位置。

The invention discloses a synthetic using method of smelting high-furnace dust, which comprises the following steps: grinding the high-furnace dust with 1.5-15% zinc; proceeding magnetic cobbing; reclassifying to obtain the refined ferric ore; disposing ore tail through waste acid of titanium dioxide with 15-30% sulphuric acid; transmitting the zinc oxide in the solution at zinc sulfate pattern; separating solid and liquid solution through lime; obtaining refined zinc ore through S2-, CO32-, HCO3- ion; floating the immersed slag through neutral oil.

一种炼铁高炉炉尘资源综合利用的方法,含锌1.5%~15%的高炉炉尘经磨矿、磁选、重选回收铁矿物获得铁精矿,选矿尾矿用含硫酸15%~30%的钛白废酸处理,使其中的氧化锌以硫酸锌的形式转入溶液中,固液分离得出的溶液用石灰中和除铁后,再用S2-、CO32-、HCO3-离子沉锌获得锌精矿,浸出渣用中性油浮选获得炭精矿。该方法将钛白废酸和高炉炉尘结合在一起,使之成为互为所需的原料和试剂,有效地将两种废弃物变成了有价资源,较好解决了环境污染问题,同时又能产生好的经济效益。

With the starting material intermediate titanyl sulfate and meta-titanic acid of titanium white product by sulfuric acid process,the titanium dioxide and iron content have been determined.

以硫酸法钛白粉生产工艺中间体浓钛液和偏钛酸为原料,分析了浓钛液中二氧化钛和铁的含量。

Keywords Titanyl sulphate;meta-titanic acid;iron content;separation;inorganic ceramic film

硫酸氧钛;偏钛酸;铁含量;铁分离;无机陶瓷膜

MgO-C brick has a good erosion resistance but Al〓O〓-C brick is better. Corrosion mechanism for refractory without carbon is that FeO and oxides of molten slag take place chemical reaction with constituents of refractory and forming low fusing point compounds to be dissolved in molten slag. For those refractory containing graphite carbon is to be decarburized in advance and to form decarburizing layer and metamorphosis layer. The subsequent corrosion is decarburizing and taking chemical reaction to form low fusing point compounds and dissolved in molten slag at the same time.

铁浴中硅和钛的扩散是影响铁浴及熔渣与耐火材料作用的重要因素,耐火材料中添加的TiO〓和SiC受熔渣氧化和侵蚀,将被部分还原形成Si,Ti向铁浴中扩散,Si、Ti在铁浴中的扩散研究结果是: D〓=1.84×10〓exp(-5988.7/T) cm〓/S E〓=49766 J/mol D〓=7.76×10〓exp(-53225.5/T) cm〓/S E〓=442304 J/mol 铁浴式熔融还原熔体对粘土砖,高铝砖,镁砖的侵蚀速度很高,镁碳砖抗侵蚀能力比前几种耐火材料强,但不如铝碳砖;对不含碳耐火材料在熔体中的侵蚀是熔渣中FeO及其它氧化物与耐火材料组分的化学反应形成低熔点物熔蚀进入渣相,产生损毁。

Two series of polyurethane acrylate grafted acrylic resins (Acr-g-TPU-PETA and Acr-gPPU-PETA) self-emulsifying systems are obtained by grafting -NCO group modified polyurethane acrylates with acrylic copolymer prepared from n-butyl acrylate, styrene,βhydroxyethyl methacrylate and acrylic acid The self-emulsifying systems showed Newtonian fluidity with viscosity closed to that of water, the solid contents were around 30% The T〓 of 15~4℃ for dried film before photocuring favored film formation at room temperature DSC and DMA results showed that PU-PETA is compatible with acrylic resin in the grafted resin The TG and dTG curves for Acr-g-PU-PETA samples were substantially different from the corresponding blends, and the brodened dTG peaks for photocured grafted resin suggest that there might be multiple interactions among chain segments The photocued film of the grafted resins self-emulsifying system exhibited good overall properties with polyurethane acrylate grafts ranging from 30% to 50%, and Acr-g-TPU-PETA series showed better properties than Acr-gPPU-PETA series The adhesion of the photocured film was 1~2 grade, impact strength was 50kg-cm and flexibility was 1mm The Shore hardness and the adhesion of the film decreased markedly if PETA was replaced by HEMA as photoactive group due to the lower C=C double bond content in the grafted resin The polyhydroxy amine-linked thioxanthones photoinitiators can be evenly dispersed in self-emulsifying system without color spot appearing in the dried film The films photocured with IV〓~IV〓 generally exhibited higher Shore hardness, gloss and solventresistance than that cured with Irgacure 2959 and did not induce the rusting of the iron substrate Pigmenting with titanium oxide had no effect on the photocuring The polyhydroxy amine-linked thioxanthone IV〓 and IV〓 can be new candidates for the formulation of titanium oxide pigmented photocurable water-borne coatings for their pale-yellow appearance and slight interference with the color of the coatings WB 4759 with high water-solubility coalesced and separated from the dried resin film, and even induced the rusting of iron substrate.

以丙烯酸丁酯,甲基丙烯酸-β-羟乙酯,丙烯酸及苯乙烯合成厂丙烯酸共聚树脂,并与含-NCO端基的聚氨酯丙烯酸酯接枝反应,经水性化后,得到两个系列(Acr-g-TPU-PETA和Acr-g-PPU-PETA)各5个不同配比的丙烯酸树脂接枝聚氨酯丙烯酸酯自乳化体系,粘度与水相近,为牛顿流体,固含量30%左右。光固化前干燥涂膜的玻璃化转变温度在-15℃~4℃之间,有利于室温下成膜。DSC及DMA谱表明两种树脂基本相容。Acr-g-PU-PETA的热失重行为明显不同于共混材料,接枝样dTG峰明显宽化,表明接枝样中链段之间的相互作刚有多重性,丙烯酸树脂与聚氨酯之间有一定的相容性。接枝树脂自乳化体系光固化涂层的综合性能以聚氨酯丙烯酸酯成分为50%~30%者相对较好,且以Acr-g-TPU-PETA系列更理想。光固化膜的附着力为1~2级,冲击强度为50kg·cm,柔软性多为1mm。以HEMA代替PETA作为接枝树脂的活性基团,碳—碳双键密度太低,光固化膜交联点太少,硬度和附着力均较差。多羟基胺连硫杂蒽酮光引发剂能均匀分散于树脂自乳化体系和接枝树脂干膜中,不出现色斑,光固化膜肖氏硬度一般高于以Irgacure 2959为光引发剂的光固化膜,光泽度及耐丁酮溶剂性能均有所提高,不会诱导铁基生锈,钛白着色对光固化结果几乎没有影响。本论文所合成的多羟基胺连硫杂蒽酮光引发剂IV〓与IV〓为浅黄色,对光固化涂层的颜色干扰较小,为配制钛白着色光固化水性涂料提供了新的光引发剂。水溶性太强的WB 4759在干膜中易聚结析出,且对所附着的铁基有诱导锈蚀作用。

In order to study the changing process of Barium strontium titanate Ba(subscript xSr(subscript 1-x) TiO3, BST from cubic phase to the tetragonal phase with Ba doping and the ferroelectric characteristic of BST, the total energy of BST with different mole ratio of Ba/Sr when Ba doped was calculated and the fine structure determined, based on general gradient approximation, by means of ultrasoft pseudopotentials plane wave method.

为了研究钛酸锶(SrTiO3, ST)中随Ba的掺入,其晶体从顺电相到铁电相的变化过程及四方相钛酸锶钡Ba(下标 xSr(下标 1-x)TiO3, BST的铁电性。在广义梯度近似下,利用超软赝势平面波方法计算了不同Ba/Sr摩尔比BST的总能量,确定了BST的精细结构。

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